A three-dimensional PbIIcoordination framework: poly[[μ4-(E)-2,2′-(diazene-1,2-diyl)dibenzoato]dimethanollead(II)]
2014 ◽
Vol 70
(7)
◽
pp. 650-653
Keyword(s):
In the title coordination polymer, [Pb(C14H8N2O4)(CH3OH)2]n, the asymmetric unit contains half of a PbIIcation, half of a 2,2′-(diazene-1,2-diyl)dibenzoate dianionic ligand (denotedL2−) and one methanol ligand. Each PbIIcentre is eight-coordinated by six O atoms of chelating/bridging carboxylate groups from fourL2−ligands and two O atoms from two terminal methanol ligands, forming a distorted dodecahedron. The [PbL2(MeOH)2] subunits are interlinkedviathe sharing of two carboxylate O atoms to form a one-dimensional [PbL2(MeOH)2]nchain. Adjacent chains are further connected byL2−ligands, giving rise to a two-dimensional layer, and these layers are bridged byL2−linkers to afford a three-dimensional framework with a 41263topology.
2014 ◽
Vol 70
(5)
◽
pp. 517-521
2014 ◽
Vol 70
(7)
◽
pp. 715-717
Keyword(s):
2014 ◽
Vol 70
(7)
◽
pp. 693-696
2015 ◽
Vol 71
(4)
◽
pp. 306-310
◽
2014 ◽
Vol 70
(3)
◽
pp. 277-280
◽
2014 ◽
Vol 70
(11)
◽
pp. 1057-1063
◽
2017 ◽
Vol 73
(11)
◽
pp. 1599-1602
◽
2009 ◽
Vol 65
(3)
◽
pp. m118-m120
2012 ◽
Vol 68
(2)
◽
pp. m41-m44
◽
2019 ◽
Vol 75
(10)
◽
pp. 1432-1435