Synthesis and Structural Characterization of Zn(II) Coordination Polymer Material
2011 ◽
Vol 282-283
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pp. 100-103
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Keyword(s):
In order to synthesize a new catalysis material, the title complex, [Zn(2,2’-bipyridine)(H2O)2(SO4)]n, was prepared and determined by X-ray diffraction. The results shows that the compound was crystallized in the monoclinic system, space groupC2/c, witha= 15.4304(14) Å,b= 12.7150(11) Å,c= 6.7068(5) Å,β= 102.103(10)º,V= 1286.61(19) Å3,Z= 4. The geometry of Zn(II) is a distortedcis-ZnN2O4octahedron. In the structure of the title complex, a one-dimensional chain structure is formed by hydrogen-bond.
2011 ◽
Vol 204-210
◽
pp. 144-147
2005 ◽
Vol 70
(2)
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pp. 237-246