scholarly journals catena-Poly[[diaquabis[1,4-bis(pyridin-4-yl)buta-1,3-diyne-κN]iron(II)]-μ-cyanido-κ2N:C-[dicyanido-κ2C-platinum(II)]-μ-cyanido-κ2C:N]

IUCrData ◽  
2017 ◽  
Vol 2 (10) ◽  
Author(s):  
Lucia Piñeiro-López ◽  
Francisco Javier Valverde-Muñoz ◽  
Maksym Seredyuk ◽  
Kateryna Znovjyak
Keyword(s):  
Molecular Structure ◽  
Hydrogen Bonds ◽  
Bond Length ◽  
Title Compound ◽  
Three Dimensional ◽  
Water Molecules ◽  
Stacking Interactions ◽  
One Dimensional ◽  
Polymeric Chains ◽  
The One

The molecular structure of the title compound, [FePt(CN)4(C14H8N2)2(H2O)2]n, consists of one-dimensional polymeric [–Fe–NC–Pt(CN)2–CN–]∞chains. Two water molecules and two monodentate 1,4-bis(pyridin-4-yl)buta-1,3-diyne (bpb) ligand molecules complete the octahedral coordination sphere of the FeIIatoms. The Fe—N(py) bond length (py is pyridine) is 2.2700 (15) Å, Fe—N(cyanide) is 2.1185 (16) Å and the Fe—O distance is 2.1275 (14) Å. The water molecules are hydrogen bonded to either bpb ligands or cyanide groups of the planar [Pt(CN)4]2−anion of adjacent polymeric chains. These O—H...N hydrogen bonds, in conjunction with offset and tilted π–π stacking interactions between bpb ligands and cyanide groups, extend the one-dimensional chains into a three-dimensional assembly.

Ethylenediammonium dichloride bis(1,10-phenanthroline) tetrahydrate

2006 ◽  
Vol 62 (7) ◽  
pp. o2797-o2799
Author(s):  
Zi-Lu Chen ◽  
Yu-Zhen Zhang ◽  
Fu-Pei Liang
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Three Dimensional ◽  
Water Molecules ◽  
Supramolecular Network ◽  
Stacking Interactions ◽  
Two Dimensional ◽  
One Dimensional ◽  
Compound C ◽  
Π Stacking

The title compound, C2H10N2 2+·2Cl−·2C12H8N2·4H2O, has an inversion centre located midway between the two C atoms of the ethylenediammonium cation. The 1,10-phenanthroline molecules stack along the a axis, and are linked by π–π stacking interactions to form one-dimensional chains. These are bridged by ethylenediammonium cations, via hydrogen bonds, forming two-dimensional supramolecular sheets parallel to the ac plane. Hydrogen bonds to chloride anions and water molecules connect these two-dimensional sheets, resulting in the formation of a three-dimensional supramolecular network.

scholarly journals Synthesis and crystal structure of a 6-chloronicotinate salt of a one-dimensional cationic nickel(II) coordination polymer with 4,4′-bipyridine

2020 ◽  
Vol 76 (5) ◽  
pp. 599-604
Author(s):  
Nives Politeo ◽  
Mateja Pisačić ◽  
Marijana Đaković ◽  
Vesna Sokol ◽  
Boris-Marko Kukovec
Keyword(s):  
Molecular Structure ◽  
Coordination Polymer ◽  
Three Dimensional ◽  
Polymeric Chain ◽  
Water Molecules ◽  
Sulfate Heptahydrate ◽  
Synthesis And Crystal Structure ◽  
One Dimensional ◽  
Polymeric Chains ◽  
Hydrogen Bonded

A 6-chloronicotinate (6-Clnic) salt of a one-dimensional cationic nickel(II) coordination polymer with 4,4′-bipyridine (4,4′-bpy), namely, catena-poly[[[tetraaquanickel(II)]-μ-4,4′-bipyridine-κ2 N:N′] bis(6-chloronicotinate) tetrahydrate], {[Ni(C10H8N2)(H2O)4](C6H3ClNO2)2·4H2O} n or {[Ni(4,4′-bpy)(H2O)4](6-Clnic)2·4H2O} n , (1), was prepared by the reaction of nickel(II) sulfate heptahydrate, 6-chloronicotinic acid and 4,4′-bipyridine in a mixture of water and ethanol. The molecular structure of 1 comprises a one-dimensional polymeric {[Ni(4,4′-bpy)(H2O)4]2+} n cation, two 6-chloronicotinate anions and four water molecules of crystallization per repeating polymeric unit. The nickel(II) ion in the polymeric cation is octahedrally coordinated by four water molecule O atoms and by two 4,4′-bipyridine N atoms in the trans position. The 4,4′-bipyridine ligands act as bridges and, thus, connect the symmetry-related nickel(II) ions into an infinite one-dimensional polymeric chain extending along the b-axis direction. In the extended structure of 1, the polymeric chains of {[Ni(4,4′-bpy)(H2O)4]2+} n , the 6-chloronicotinate anions and the water molecules of crystallization are assembled into an infinite three-dimensional hydrogen-bonded network via strong O—H...O and O—H...N hydrogen bonds, leading to the formation of the representative hydrogen-bonded ring motifs: tetrameric R 2 4(8) and R 4 4(10) loops, a dimeric R 2 2(8) loop and a pentameric R 4 5(16) loop.

A one-dimensional heterometallic coordination polymer with a three-dimensional supramolecular framework: poly[μ2-aqua-diaqua(2,2′-bipyridyl)(μ5-2-sulfonatobutanedioato)copper(II)sodium(I)]

2012 ◽  
Vol 68 (8) ◽  
pp. m209-m212 ◽  
Author(s):  
Jiang-Hong Fu ◽  
Yu-Ling Wang ◽  
Ying Chen ◽  
Chang-Hui Hu ◽  
Li Tang
Keyword(s):  
Title Compound ◽  
Three Dimensional ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Stacking Interactions ◽  
Supramolecular Framework ◽  
One Dimensional ◽  
Distorted Octahedral ◽  
Coordinated Water ◽  
Thermal Stability Of

The title compound, [CuNa(C4H3O7S)(C10H8N2)(H2O)3]n, consists of one CuIIcation, one NaIcation, one 2-sulfonatobutanedioate trianion (SSC3−), one 2,2′-bipyridyl (bpy) ligand and three coordinated water molecules as the building unit. The coordination of the CuIIcation is composed of two pyridyl N atoms, one water O atom and two carboxylate O atoms in a distorted square-pyramidal coordination geometry with an axial elongation. The NaIcation is six-coordinated by three water molecules and three carboxylate O atoms from three SSC3−ligands in a distorted octahedral geometry. Two SSC3−ligands link two CuIIcations to form a Cu2(SSC)2(bpy)2macrocyclic unit lying across an inversion centre, which is further linked by NaIcationsviaNa—O bonds to give a one-dimensional chain. Interchain hydrogen bonds link these chains to form a two-dimensional layer, which is further extended into a three-dimensional supramolecular framework through π–π stacking interactions. The thermal stability of the title compound has also been investigated.

A novel dinuclear bismuth(III) coordination compound: bis(μ-pyridine-2,6-dicarboxylato)-κ4O2,N,O6:O6′;κ4O2:O2′,N,O6-bis[(azido-κN)(1,10-phenanthroline-κ2N,N′)bismuth(III)] tetrahydrate

2014 ◽  
Vol 70 (6) ◽  
pp. 562-565 ◽  
Author(s):  
Wei Zhang ◽  
Yu-Quan Feng
Keyword(s):  
Molecular Structure ◽  
Hydrogen Bonds ◽  
Coordination Compound ◽  
Photoelectron Spectroscopy ◽  
Three Dimensional ◽  
Water Molecules ◽  
Stacking Interactions ◽  
Coordination Geometry ◽  
X Ray Diffraction ◽  
X Ray

A novel dinuclear bismuth(III) coordination compound, [Bi2(C7H3NO4)2(N3)2(C12H8N2)2]·4H2O, has been synthesized by an ionothermal method and characterized by elemental analysis, energy-dispersive X-ray spectroscopy, IR, X-ray photoelectron spectroscopy and single-crystal X-ray diffraction. The molecular structure consists of one centrosymmetric dinuclear neutral fragment and four water molecules. Within the dinuclear fragment, each BiIIIcentre is seven-coordinated by three O atoms and four N atoms. The coordination geometry of each BiIIIatom is distorted pentagonal–bipyramidal (BiO3N4), with one azide N atom and one bridging carboxylate O atom located in axial positions. The carboxylate O atoms and water molecules are assembledviaO—H...O hydrogen bonds, resulting in the formation of a three-dimensional supramolecular structure. Two types of π–π stacking interactions are found, with centroid-to-centroid distances of 3.461 (4) and 3.641 (4) Å.

scholarly journals Dichlorido(4,4′-di-tert-butyl-2,2′-bipyridine-κ2N,N′)palladium(II) dimethyl sulfoxide monosolvate monohydrate

2014 ◽  
Vol 70 (6) ◽  
pp. m200-m201 ◽  
Author(s):  
Ricardo A. Gutiérrez-Márquez ◽  
Carmela Crisóstomo-Lucas ◽  
Reyna Reyes-Martínez ◽  
Simón Hernández-Ortega ◽  
David Morales-Morales
Keyword(s):  
Hydrogen Bonds ◽  
Dimethyl Sulfoxide ◽  
Title Compound ◽  
Three Dimensional ◽  
Planar Geometry ◽  
Water Molecules ◽  
Stacking Interactions ◽  
Bite Angle ◽  
Linear Chains ◽  
Square Planar

The title compound, [PdCl2(C18H24N2)]·(CH3)2SO·H2O, the PdIIion is in a distorted square-planar geometry. The Pd—N bond distances are 2.022 (2) and 2.027 (2) Å, the Pd—Cl bond distances are 2.2880 (7) and 2.2833 (7) Å, and the ligand bite angle is 80.07 (9)°. The dimethyl sulfoxide and water molecules form linear chains along [100] by O—H...O and O—H...S hydrogen bonds, generating eight- and 12-membered rings. C—H...Cl interactions link the chains, forming a three-dimensional arrangement. In addition, the 4,4-di-tert-butyl-2,2′-bipyridine ligand exhibits π–π stacking interactions [centroid–centroid distances = 3.8741 (15) and 3.8353 (15) Å]. The DMSO solvent is disordered and was refined with an occupancy ratio of 0.866 (3):0.134 (3).

scholarly journals (2R,3R,4S,5R)-2-(4-Amino-5-iodo-7H-pyrrolo[2,3-d]pyrimidin-7-yl)-5-methyltetrahydrofuran-3,4-diol

2013 ◽  
Vol 69 (11) ◽  
pp. o1646-o1647
Author(s):  
Ulrich Flörke ◽  
Birte Drewes
Keyword(s):  
Molecular Structure ◽  
Hydrogen Bond ◽  
Hydrogen Bonds ◽  
Bond Length ◽  
Aromatic Ring ◽  
Torsion Angle ◽  
Title Compound ◽  
Three Dimensional ◽  
Amino Group ◽  
Compound C

The molecular structure of the title compound, C11H13IN4O3, shows a ribofuranosyl–pyrrolo O—C—N—C torsion angle of 59.1 (3)°, with the central C—N bond length being 1.446 (3) Å. The C—I bond length is 2.072 (2) Å. The amino group is coplanar with the attached aromatic ring [C—N—C—N torsion angle = −178.8 (2)°] and forms an intramolecular N—H...I hydrogen bond. In the crystal, O—H...N and N—H...O hydrogen bonds link the molecules into puckered layers parallel to (001). These layers are bound to each other by secondary I...O interactions [3.2250 (17) Å], forming a three-dimensional framework.

scholarly journals Diaqua(5,10,15,20-tetraphenylporphyrinato-κ4N)magnesium–18-crown-6 (1/1)

2013 ◽  
Vol 69 (2) ◽  
pp. m114-m115 ◽  
Author(s):  
Khaireddine Ezzayani ◽  
Soumaya Nasri ◽  
Mohamed Salah Belkhiria ◽  
Jean-Claude Daran ◽  
Habib Nasri
Keyword(s):  
Hydrogen Bonds ◽  
Bond Length ◽  
Title Compound ◽  
Supramolecular Structure ◽  
Crystal Packing ◽  
Water Molecules ◽  
Supramolecular Architecture ◽  
Inversion Center ◽  
Asymmetric Unit ◽  
One Dimensional

In the title compound, [Mg(C44H28N4)(H2O)2]·C12H24O6, the MgIIcation lies on an inversion center and is octahedrally coordinated by the four N atoms of the deprotonated tetraphenylporphyrin (TPP) ligand and by two water molecules. The asymmetric unit contains one half of the [Mg(TPP)(H2O)2] complex and one half of an 18-crown-6 molecule. The average equatorial magnesium–pyrrole N atom distance (Mg—Np) is 2.071 (1) Å and the axial Mg—O(H2O) bond length is 2.213 (1) Å. The crystal packing is stabilized by two O—H...O hydrogen bonds between coordinating water molecules and adjacent 18-crown-6 molecules, and exhibits a one-dimensional supramolecular structure along theaaxis. The supramolecular architecture is futher stabilized by weak C—H...π interactions. The 18-crown-6 molecule is disordered over two sets of sites with an occupancy ratio of 0.8:0.2.

A new one-dimensional CdII coordination polymer incorporating 2,2′-(1,2-phenylene)bis(1H-imidazole-4,5-dicarboxylate)

2018 ◽  
Vol 74 (10) ◽  
pp. 1128-1132 ◽  
Author(s):  
Yan-Ju Liu ◽  
Di Cheng ◽  
Ya-Xue Li ◽  
Jun-Di Zhang ◽  
Huai-Xia Yang
Keyword(s):  
Coordination Polymer ◽  
Hydrogen Bonds ◽  
Dicarboxylic Acid ◽  
Three Dimensional ◽  
Dimensional Structure ◽  
Water Molecules ◽  
Coordination Geometry ◽  
One Dimensional ◽  
Distorted Octahedral ◽  
The One

Imidazole-4,5-dicarboxylic acid (H3IDC) and its derivatives are widely used in the preparation of new coordination polymers owing to their versatile bridging coordination modes and potential hydrogen-bonding donors and acceptors. A new one-dimensional coordination polymer, namely catena-poly[[diaquacadmium(II)]-μ3-2,2′-(1,2-phenylene)bis(1H-imidazole-4,5-dicarboxylato)], [Cd(C16H6N4O8)0.5(H2O)2] n or [Cd(H2Phbidc)1/2(H2O)2] n , has been synthesized by the reaction of Cd(OAc)2·2H2O (OAc is acetate) with 2,2′-(1,2-phenylene)bis(1H-imidazole-4,5-dicarboxylic acid) (H6Phbidc) under solvothermal conditions. In the polymer, one type of Cd ion (Cd1) is six-coordinated by two N atoms and two O atoms from one H2Phbidc4− ligand and by two O atoms from two water molecules, forming a significantly distorted octahedral CdN2O4 coordination geometry. In contrast, the other type of Cd ion (Cd2) is six-coordinated by two N atoms and two O atoms from two symmetry-related H2Phbidc4− ligands and by two O atoms from two symmetry-related water molecules, leading to a more regular octahedral coordination geometry. The Cd1 and Cd2 ions are linked by H2Phbidc4− ligands into a one-dimensional chain which runs parallel to the b axis. In the crystal, the one-dimensional chains are connected through hydrogen bonds, generating a two-dimensional layered structure parallel to the ab plane. Adjacent layers are further linked by hydrogen bonds, forming a three-dimensional structure in the solid state.

scholarly journals cis-Tetraaquabis{5-[4-(1H-imidazol-1-yl-κN3)phenyl]tetrazolido}manganese(II) dihydrate

2012 ◽  
Vol 68 (4) ◽  
pp. m433-m434 ◽  
Author(s):  
Shao-Wei Tong ◽  
Wen-Dong Song ◽  
Dong-Liang Miao ◽  
Shi-Jie Li ◽  
Jing-Bo An
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Rotation Axis ◽  
Three Dimensional ◽  
Water Molecules ◽  
Stacking Interactions ◽  
Complex Molecules ◽  
Benzene Rings ◽  
Coordinated Water ◽  
Ring Centroid

In the title compound, [Mn(C10H7N6)2(H2O)4]·2H2O, the Mn2+lies on a twofold rotation axis and is six-coordinated by two N atoms from thecis-related monodentate 5-[4-(imidazol-1-yl)phenyl]tetrazolide ligands and four O atoms from the coordinated water molecules. The complex molecules are connectedviawater O—H...O and O—H...N hydrogen bonds and weak π–π stacking interactions between the benzene rings [minimum ring centroid separation = 3.750 (6) Å] into a three-dimensional polymeric structure. The imidazolyl group of the ligand is partially disordered over two sets of sites with refined occupancies of 0.531 (7):0.469 (7).

scholarly journals Crystal structure of diaqua[5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinato-κ4N]iron(III) diaqua(18-crown-6)potassium bis(trifluoromethanesulfonate)–18-crown-6 (1/2)

2015 ◽  
Vol 71 (12) ◽  
pp. m215-m216
Author(s):  
Leila Ben Haj Hassen ◽  
Zouhour Denden ◽  
Yoann Rousselin ◽  
Habib Nasri
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Bond Length ◽  
High Spin ◽  
Title Compound ◽  
Crystal Packing ◽  
Water Molecules ◽  
Supramolecular Architecture ◽  
One Dimensional ◽  
Phenyl Rings

In the title compound, [FeIII(C48H36N4O2)(H2O)2][K(C12H24O6)(H2O)2](SO3CF3)2·2C12H24O6, the FeIIIatom is situated on an inversion centre and is octahedrally coordinated by four pyrrole N atoms of the deprotenated 5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinate ligand and two water molecules. The average equatorial Fe—N(pyrrole) bond length [2.043 (6) Å] is consistent with a high-spin (S= 5/2) iron(III) metalloporphyrin derivative. The K+cation, which also lies on an inversion centre, is chelated by the six O atoms of one 18-crown-6 molecule and is additionally coordinated by two water molecules in a distorted hexagonal–bipyramidal geometry. In the crystal, the cations, anions and one non-coordinating 18-crown-6 molecule are linked by classical O—H...O hydrogen bonds and non-conventional C—H...O hydrogen bonds, leading to a one-dimensional supramolecular architecture along [10-1]. The crystal packing is further stabilized by weak C—H...π interactions involving pyrrole and phenyl rings of the porphyrins, as well as weak C—H...F contacts involving the (SO3CF3)−counter-ion and the 18-crown-6 molecules.

Sign in / Sign up

Export Citation Format

Share Document