The role of corona discharge in the electrical precipitation process

1952 ◽  
Vol 71 (1) ◽  
pp. 67-73 ◽  
Author(s):  
H. J. White
Author(s):  
David L. Kirchman

Geomicrobiology, the marriage of geology and microbiology, is about the impact of microbes on Earth materials in terrestrial systems and sediments. Many geomicrobiological processes occur over long timescales. Even the slow growth and low activity of microbes, however, have big effects when added up over millennia. After reviewing the basics of bacteria–surface interactions, the chapter moves on to discussing biomineralization, which is the microbially mediated formation of solid minerals from soluble ions. The role of microbes can vary from merely providing passive surfaces for mineral formation, to active control of the entire precipitation process. The formation of carbonate-containing minerals by coccolithophorids and other marine organisms is especially important because of the role of these minerals in the carbon cycle. Iron minerals can be formed by chemolithoautotrophic bacteria, which gain a small amount of energy from iron oxidation. Similarly, manganese-rich minerals are formed during manganese oxidation, although how this reaction benefits microbes is unclear. These minerals and others give geologists and geomicrobiologists clues about early life on Earth. In addition to forming minerals, microbes help to dissolve them, a process called weathering. Microbes contribute to weathering and mineral dissolution through several mechanisms: production of protons (acidity) or hydroxides that dissolve minerals; production of ligands that chelate metals in minerals thereby breaking up the solid phase; and direct reduction of mineral-bound metals to more soluble forms. The chapter ends with some comments about the role of microbes in degrading oil and other fossil fuels.


1976 ◽  
Vol 29 (8) ◽  
pp. 1649 ◽  
Author(s):  
H Farrah ◽  
WF Pickering

The effect of changes in pH and the presence of ligands on the uptake of zinc ions by three types of clay mineral (kaolinite, illite and montmorillonite) has been investigated. In alkaline media the clay suspension acts as a nucleation centre for polymeric hydroxy species, and the major role of many ligands is to mask the precipitation process. Uncharged and negatively charged species are not sorbed to any measurable extent. In acidic media the adsorption capacity of the clays for zinc increases with pH and possible mechanisms are considered. For kaolinite and illite the controlling process appears to be the attachment of hydroxy species to particular sites on the particle edges; with montmorillonite ion exchange at negative lattice sites appears predominant. Of particular interest is the apparent affinity between montmorillonite and species containing nitrogen functional groups.


2009 ◽  
Vol 24 (5) ◽  
pp. 1700-1708 ◽  
Author(s):  
Mei-Keat Liang ◽  
Siddharth V. Patwardhan ◽  
Elena N. Danilovtseva ◽  
Vadim V. Annenkov ◽  
Carole C. Perry

Histidine is an amino acid present in proteins involved in biosilica formation and often found in peptides identified during phage display studies but its role(s) and the extent of its involvement in the silica precipitation process is not fully understood. In this contribution we describe results from an in vitro silicification study conducted using poly-histidine (P-His) and a series of different molecular weight synthetic polymers containing the imidazole functionality (polyvinylimidazole, PVI) for comparison. We show that the presence of imidazole from PVI or P-His is able to catalyze silicic acid condensation; the effect being greater for P-His. The catalytic mechanism is proposed to involve the dual features of the imidazole group—its ability to form hydrogen bonds with silicic acid and electrostatic attraction toward oligomeric silicic acid species.


2021 ◽  
Vol 2100 (1) ◽  
pp. 012016
Author(s):  
A S Dobrovolskaya ◽  
E A Filimonova ◽  
V A Bityurin ◽  
A N Bocharov

Abstract In this paper we present numerical research of pressure waves influence on the end-gas in HCCI engine with discharge activation. It is shown that there is certain promotion of exothermic chemical reactions by pressure waves. That leads to the slight heating of the end-gas, but mainly the end-gas is heated due to the compression in the process of combustion wave propagation.


2021 ◽  
Vol 146 ◽  
pp. 763-769
Author(s):  
Yifan Wang ◽  
Wenchao Gao ◽  
Xuefeng Zhang ◽  
Hao Zhang ◽  
Wenju Liu ◽  
...  

2013 ◽  
Vol 68 (7) ◽  
pp. 1536-1542 ◽  
Author(s):  
S. Preis ◽  
I. C. Panorel ◽  
I. Kornev ◽  
H. Hatakka ◽  
J. Kallas

Ozone and hydroxyl radical are the most active oxidizing species in water treated with gas-phase pulsed corona discharge (PCD). The ratio of the species dependent on the gas phase composition and treated water contact surface was the objective for the experimental research undertaken for aqueous phenol (fast reaction) and oxalic acid (slow reaction) solutions. The experiments were carried out in the reactor, where aqueous solutions showered between electrodes were treated with 100-ns pulses of 20 kV voltage and 400 A current amplitude. The role of ozone increased with increasing oxygen concentration and the oxidation reaction rate. The PCD treatment showed energy efficiency surpassing that of conventional ozonation.


2017 ◽  
Vol 24 (10) ◽  
pp. 103506 ◽  
Author(s):  
H. Y. Sun ◽  
B. X. Lu ◽  
M. Wang ◽  
Q. F. Guo ◽  
Q. K. Feng

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