A novel method for woody biomass separation with the mixture of aqueous ethanol and ionic liquid

Author(s):  
Huaming Yu ◽  
Jie Chang ◽  
Jia Hu ◽  
Juan Fan ◽  
Huaming Yu
2005 ◽  
Vol 83 (1) ◽  
pp. 16-20 ◽  
Author(s):  
Xuesen Fan ◽  
Xueyuan Hu ◽  
Xinying Zhang ◽  
Jianji Wang

A green procedure for the synthesis of xanthenedione derivatives (3) through InCl3·4H2O-promoted condensation of aldehydes (1) and 5,5-dimethyl-1,3-cyclohexanedione (2) in ionic liquids is described in this paper. This novel method has such advantages as operational simplicity and environmental benignancy together with enhanced atom utilization. Moreover, the reaction media and the catalyst can be recovered conveniently and reused effectively for at least six times.Key words: ionic liquid, xanthenedione derivatives, indium trichloride, green synthesis.


2018 ◽  
Vol 32 (4) ◽  
pp. 5518-5526 ◽  
Author(s):  
Jinshe Chen ◽  
Lingbin Yang ◽  
Wenbo Zhou ◽  
Lijun Zhu ◽  
Yulu Zhou ◽  
...  

2005 ◽  
Vol 2005 (7) ◽  
pp. 446-448 ◽  
Author(s):  
Lei Wang ◽  
Zhizhen Huang

The condensation reaction of telluronium salts 1 with aldehydes and dibutyl telluride 4, bromide 5 with aldehyde 2 proceeded smoothly in the ionic solvent [bmim][BF4], affording a novel method for the stereoselective synthesis of (E)-α,β-unsaturated compounds 3 in high purity, excellent yields and high stereoselectivity.


2005 ◽  
Vol 103 (1-2) ◽  
pp. 59-62 ◽  
Author(s):  
Jun Huang ◽  
Tao Jiang ◽  
Buxing Han ◽  
Weize Wu ◽  
Zhimin Liu ◽  
...  

2010 ◽  
Vol 25 (7) ◽  
pp. 1264-1271 ◽  
Author(s):  
Dalaver H. Anjum ◽  
Rebecca M. Stiger ◽  
James J. Finley ◽  
James F. Conway

We report a novel method of growing silver nanostructures by cathodic sputtering onto an ionic liquid (IL) and our visualization by transmission cryo-electron microscopy to avoid beam-induced motion of the nanoparticles. By freezing the IL suspension and controlling electron dose, we can assess properties of particle size, morphology, crystallinity, and aggregation in situ and at high detail. We observed round silver nanoparticles with a well-defined diameter of 7.0 ± 1.5 nm that are faceted with crystalline cubic structures and ˜80% of the particles have multiply twinned faults. We also applied cryo-electron tomography to investigate the structure of the nanoparticles and to directly visualize the IL wetting around them. In addition to particles, we observed nanorods that appear to have assembled from individual nanoparticles. Reexamination of the samples after 4–5 days from initial preparation showed significant changes in morphology, and potential mechanisms for this are discussed.


2019 ◽  
Vol 2019 ◽  
pp. 1-6 ◽  
Author(s):  
Jafar Al Hakkak ◽  
Warren J. Grigsby ◽  
Kalyani Kathirgamanathan ◽  
Neil R. Edmonds

A novel method to prepare spherical cellulose nanoparticles has been developed using imidazolium ionic liquid processing and regeneration from controlled acetonitrile nonsolvent addition and drying. Nanoparticles ranging from 100 to 400 nm have been prepared with high uniformity. Minimisation of moisture via solvent exchange drying led to discrete nanoparticles, whereas the presence of ambient moisture during regeneration contributed to aggregated morphologies. Chemical analyses of the spherical cellulose nanoparticles reveal a high-amorphous cellulose content. Furthermore, the range of particle sizes achieved with acetonitrile nonsolvent fractionation and solvent exchange drying suggest the size and uniformity of nanoparticle distributions reflect the fractionated cellulose weight fractions. This ionic liquid method is simple, energy efficient, and likely to have wide applicability across other biopolymers as well as potential to prepare surface functionalized spherical cellulose nanoparticles.


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