EM shielding, dosimetry control and Xe(135)-Sm(149) Poisoning effect for nuclear waste treatment

Author(s):  
Syed Bahauddin Alam ◽  
Hussain Mohammed Dipu Kabir ◽  
Md. Nazmus Sakib ◽  
Celia Shahnaz ◽  
Shaikh Anowarul Fattah
ChemInform ◽  
2010 ◽  
Vol 27 (9) ◽  
pp. no-no
Author(s):  
J. F. MALONE ◽  
D. J. MARRS ◽  
M. A. MCKERVEY ◽  
P. O'HAGAN ◽  
N. THOMPSON ◽  
...  

2018 ◽  
Vol 189 ◽  
pp. 00014 ◽  
Author(s):  
Bernhard Kienzler ◽  
Horst Geckeis

This paper provides for a summary of facts which are indispensable for nuclear waste disposal. Information is presented on types of radioactive wastes and the origin, the waste treatment procedures and some characteristics of the waste forms. Finally the various host rocks and the international disposal concepts are discussed and the procedures for safety analyses are shortly described.


Author(s):  
Z. Asfari ◽  
B. Pulpoka ◽  
M. Saadioui ◽  
S. Wenger ◽  
M. Nierlich ◽  
...  

Author(s):  
S. R. Biggs ◽  
M. Fairweather ◽  
D. Harbottle ◽  
B. Lin ◽  
J. Peakall

A great deal of existing nuclear waste is stored as a solid-liquid slurry, and the effective transportation of such systems is an essential element in the successful implementation of almost all waste treatment strategies involving particulate wastes within the nuclear industry. A detailed knowledge of turbulent, particle-laden liquid flow behaviour is therefore obviously important. However, systematic and detailed studies of solid-liquid flows by experimental investigation are still limited for pipe flows, contrary to the significant amount of work available for channel flows. Research is therefore required to understand the effects of physical parameters, such as particle shape, size and size distribution, and solids concentration, on the properties of solid-liquid systems, particularly in horizontal pipe flows where particles may settle out of the flow and form solid beds which can potentially lead to pipe blockages. The presence of particles in a turbulent pipe flow also modifies the characteristics of the flow, thereby changing its ability to maintain particles in suspension. The work described concerns pipe flows over a Reynolds number range of 1,000–10,000, with varying levels of solids concentration within the flow. Measurements of the flow and particle characteristics have been gathered using particle image velocimetry (PIV) and, for high solids concentrations, ultrasound Doppler velocity profiling (UDVP) techniques. This work has demonstrated that the intensity of turbulence within such flows can be significantly affected by the presence of solid particles, with small particles generally attenuating turbulence levels, while large particles often augment turbulence levels from the pipe centre-line to the near-wall region. In addition, the coagulation of particles into larger agglomerates is also of importance, with data demonstrating that whilst turbulence levels are influenced and augmented by such agglomerates at low Reynolds numbers, high turbulence levels at high Reynolds numbers can destroy the agglomerates and reduce their effect on the carrier fluid. Work has also been undertaken to examine the effect of particle size and Reynolds number on particle deposition within the flows, and also to establish the minimum transport velocity required to re-suspend particles from solid beds. All these findings are of importance in enhancing our understanding of flows of particles in pipes which in turn is of value in enabling the design of cost effective and efficient waste treatment processes.


2017 ◽  
Vol 201 ◽  
pp. 47-61 ◽  
Author(s):  
Baiyan Li ◽  
Xinglong Dong ◽  
Hao Wang ◽  
Dingxuan Ma ◽  
Kui Tan ◽  
...  

Highly efficient capture of radioactive organic iodides (ROIs) from off-gas mixtures remains a substantial challenge for nuclear waste treatment. Current materials utilized for ROI sequestration suffer from low capacity, high cost (e.g. use of noble metals), and poor recyclability. Recently, we have developed a new strategy to tackle this challenge by functionalizing MOF materials with tertiary amines to create molecular traps for the effective capture and removal of ROIs (e.g. radioactive methyl iodide) from nuclear wastes. To further enhance the uptake capacity and performance of CH3I capture by ROI molecular traps, herein, we carry out a systematic study to investigate the effect of different amine molecules on ROI capture. The results demonstrate a record-high CH3I saturation uptake capacity of 80% for MIL-101–Cr–DMEDA at 150 °C, which is 5.3 times that of Ag0@MOR (15 wt%), a leading adsorbent material for capturing ROIs during nuclear fuel reprocessing. Furthermore, the CH3I decontamination factors (DFs) for MIL-101–Cr–DMEDA are as high as 5000 under simulated reprocessing conditions, largely exceeding that of facility regulatory requirements (DF = 3000). In addition, MIL-101–Cr–DMEDA can be recycled without loss of capacity, illustrating yet another advantage compared to known industrial adsorbents, which are typically of a “single-use” nature. Our analysis also shows that both physisorption and chemisorption of CH3I occur at the three amine-grafted MOFs. While chemisorption takes place at the amine functionalized sites, the amount of physisorption correlates with the MOF porosity. A possible binding site of amine–CH3I interaction has been identified via an in situ IR spectroscopic study. The results suggest that CH3I interacts strongly and directly with the tertiary nitrogen of the amine molecules. The CH3I uptake amount decreases as the amine chain length increases, in trend with the decreasing pore space of the corresponding framework. The strategy to build MOF-based molecular traps developed in this work not only leads to a new record-high performance for ROI capture, but also offers an effective way of systematically tuning the porosity by varying the length of functionalized amine molecules. This study also demonstrates that MOFs represent a promising new platform for selective capture and removal of radioactive nuclear waste.


2006 ◽  
Vol 4 (2) ◽  
pp. 86-89 ◽  
Author(s):  
J. Wochele ◽  
Chr. Ludwig ◽  
H.-J. Lau ◽  
W. Heep

1998 ◽  
Vol 235 (1-2) ◽  
pp. 37-40 ◽  
Author(s):  
S. F. Marsh ◽  
G. D. Jarvinen ◽  
R. A. Bartsch ◽  
J. Nam ◽  
M. E. Barr

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