Production of low-cost solar-grade silicon by reduction of SiF4 gas with sodium: Technical and industrial developmental status

Author(s):  
Jordi Perez-Mariano ◽  
Lorenza Moro ◽  
Kai Lau ◽  
Marc Hornbostel ◽  
Anoop Nagar ◽  
...  
2014 ◽  
Vol 881-883 ◽  
pp. 1562-1567
Author(s):  
Peng Zou ◽  
Kui Xian Wei ◽  
Wen Hui Ma ◽  
Ke Qiang Xie ◽  
Ji Jun Wu ◽  
...  

In present, refining of metallurgical grade silicon is one of the promising routes to low-cost solar grade silicon for solar cells. Alloying with Ca has shown a great potential as efficient refining method of MG-Si in combination with acid leaching. Compared with Ca metal, Ca-Si alloy is cheaper and more secure. Great removal of impurity depends on microstructure of MG-Si after alloyed with Ca-Si alloy. In the work, the change of impurity phase which was performed by the change of the microstructure of MG-Si before and after alloyed with Ca-Si alloy has been analyzed. It was determined that CaSi2phase contained significant phosphorus content after alloying with Ca-Si alloy, It also investigated the optimal acid leaching condition after leaching, which confirmed that metallurgical grade silicon with Ca-Si alloy addition followed by acid leaching could be a potential route to remove phosphorus from MG-Si.


2016 ◽  
Vol 83 ◽  
pp. 324-328 ◽  
Author(s):  
Marouan Khalifa ◽  
Malek Atyaoui ◽  
Rachid Ouertani ◽  
Messaoud Hajji ◽  
Hatem Ezzaouia

2017 ◽  
Vol 105 (7) ◽  
Author(s):  
Barbara Karches ◽  
Jonas Schön ◽  
Heiko Gerstenberg ◽  
Gabriele Hampel ◽  
Patricia Krenckel ◽  
...  

AbstractIn a series of crystallization experiments, the directional solidification of silicon was investigated as a low cost path for the production of silicon wafers for solar cells. Instrumental neutron activation analysis was employed to measure the influence of different crystallization parameters on the distribution of 3d-metal impurities of the produced ingots. A theoretical model describing the involved diffusion and segregation processes during the solidification and cooling of the ingots could be verified by the experimental results. By successive etching of the samples after the irradiation, it could be shown that a layer of at least 60 μm of the samples has to be removed to get real bulk concentrations.


Silicon ◽  
2020 ◽  
Vol 12 (10) ◽  
pp. 2405-2412 ◽  
Author(s):  
Jing Guo ◽  
Yang Liu ◽  
Lu Liu ◽  
Jia Liu ◽  
Jian Kong ◽  
...  

2021 ◽  
Vol 4 (4) ◽  
pp. 4181-4198
Author(s):  
Avritti Srivastava ◽  
Deepak Sharma ◽  
Premshila Kumari ◽  
Mrinal Dutta ◽  
Sanjay K. Srivastava

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Xingli Zou ◽  
Li Ji ◽  
Jianbang Ge ◽  
Donald R. Sadoway ◽  
Edward T. Yu ◽  
...  

AbstractCrystalline-silicon solar cells have dominated the photovoltaics market for the past several decades. One of the long standing challenges is the large contribution of silicon wafer cost to the overall module cost. Here, we demonstrate a simple process for making high-purity solar-grade silicon films directly from silicon dioxide via a one-step electrodeposition process in molten salt for possible photovoltaic applications. High-purity silicon films can be deposited with tunable film thickness and doping type by varying the electrodeposition conditions. These electrodeposited silicon films show about 40 to 50% of photocurrent density of a commercial silicon wafer by photoelectrochemical measurements and the highest power conversion efficiency is 3.1% as a solar cell. Compared to the conventional manufacturing process for solar grade silicon wafer production, this approach greatly reduces the capital cost and energy consumption, providing a promising strategy for low-cost silicon solar cells production.


Author(s):  
Julio A. Bragagnolo ◽  
Charles E. Bucher ◽  
John R. Mott ◽  
Michael Hayes

Sign in / Sign up

Export Citation Format

Share Document