The decay of 185Wm has been investigated using a high-resolution Ge(Li) X-ray spectrometer and a Ge(Li)–NaI(Tl) coincidence system. The energies and relative intensities (given in parentheses) of the observed gamma rays associated with the decay of the 185Wm (T1,2 = 1.68 min) are: 23.54 (3.3), 42.29 (1.1), 65.857 (100), 93.30 (0.5), 94.59 (2.2), 107.850 (6.8), 122.05 (1.5), 131.554 (84.0), 164.334 (11), 173.675(61.5),and 187.879(15.4) keV. The energy of the isomeric level has been deduced to be 197.41 keV and decays to the ground state through levels at 187.88, 173.68, 93.29, 65.86, and 23.54 keV. In addition, it was deduced experimentally from measured internal-conversion coefficients that the multipolarity of the 131.55 keV transition is E3 while the 65.86 keV transition is an M1 + E2 mixture with a 30 ± 7.5% M1 component.