Hydrocarbon source rock assessment of the shale and coal bearing horizons of the Early Paleocene Hangu Formation in Kala-Chitta Range, Northwest Pakistan

The present study aims to investigate the origin, type, thermal maturity and hydrocarbon generation potential of organic matter and paleo-depositional environment of the Early Paleocene (Danian) Hangu Formation outcropped in the Kala-Chitta Range of Northwest Pakistan, Eastern Tethys. Organic-rich shale and coal intervals were utilized for geochemical analyses including TOC (total organic carbon) and Rock–Eval pyrolysis coupled with carbon (δ13Corg) and nitrogen (δ15Norg) stable isotopes. The organic geochemical results showed that the kerogen Type II (oil/gas prone) and Type III (gas prone) dominate the investigated rock units. The TOC (wt%) and S2 yield indicate that the rock unit quantifies sufficient organic matter (OM) to act as potential source rock. However, the thermal maturity Tmax°C marks the over maturation of the OM, which may be possibly linked with the effect attained from nearby tectonically active Himalayan Foreland Fold-and-Thrust Belt system and associated metamorphosed sequences. The organic geochemical analyses deciphered indigenous nature of the OM and resultant hydrocarbons. The δ13Corg and δ15Norg stable isotopic signatures illustrated enrichment of the OM from both marine and terrestrial sources accumulated into the Hangu Formation. The Paleo-depositional model established using organic geochemical and stable isotopic data for the formation supports its deposition in a shallow marine proximal inner shelf environment with prevalence of sub-oxic to anoxic conditions, a scenario that could enhance the OM preservation. Overall, the formation holds promising coal and shale intervals in terms of organic richness, but due to relatively over thermal maturation, it cannot act as an effective source rock for liquid hydrocarbon generation and only minor amount of dry gas can be expected. In implication, the results of this study suggest least prospects of liquid hydrocarbon generation potential within Hangu Formation at studied sections.

Cyclostratigraphy of the Middle to Upper Ordovician successions of the Armorican Massif (western France) using portable X-ray fluorescence

To expand traditional cyclostratigraphic numerical methods beyond their common technical limitations and apply them to truly deep-time archives we need to reflect on the development of new approaches to sedimentary archives that traditionally are not targeted for cyclostratigraphic analysis, but that frequently occur in the impoverished deep-time record. Siliciclastic storm-dominated shelf environments are a good example of such records. Our case study focusses on the Middle to Upper Ordovician siliciclastic successions of the Armorican Massif (western France), which are well-studied in terms of sedimentology and sequence stratigraphy. In addition, these sections are protected geological heritage due to the extraordinary quality of the outcrops. We therefore tested the performance of non-destructive high-resolution (cm-scale) portable X-ray fluorescence and natural gamma-ray analyses on outcrop to obtain major and trace element compositions. Despite the challenging outcrop conditions in the tidal beach zone, our geochemical analyses provide useful information regarding general lithology and several specific sedimentary features such as the detection of paleoplacers, or the discrimination between different types of diagenetic concretions such as nodules. Secondly, these new high-resolution data are used to experiment the application of commonly used numerical cyclostratigraphic techniques on this siliciclastic storm-dominated shelf environment, a non-traditional sedimentological setting for cyclostratigraphic analysis. In the lithological relatively homogenous parts of the section spectral power analyses and bandpass filtering hint towards a potential astronomical imprint of some sedimentary cycles, but this needs further confirmation in the absence of more robust independent age constraints.

Biogeochemical Niche of Magnetotactic Cocci Capable of Sequestering Large Polyphosphate Inclusions in the Anoxic Layer of the Lake Pavin Water Column

Magnetotactic bacteria (MTB) are microorganisms thriving mostly at oxic–anoxic boundaries of aquatic habitats. MTB are efficient in biomineralising or sequestering diverse elements intracellularly, which makes them potentially important actors in biogeochemical cycles. Lake Pavin is a unique aqueous system populated by a wide diversity of MTB with two communities harbouring the capability to sequester not only iron under the form of magnetosomes but also phosphorus and magnesium under the form of polyphosphates, or calcium carbonates, respectively. MTB thrive in the water column of Lake Pavin over a few metres along strong redox and chemical gradients representing a series of different microenvironments. In this study, we investigate the relative abundance and the vertical stratification of the diverse populations of MTB in relation to environmental parameters, by using a new method coupling a precise sampling for geochemical analyses, MTB morphotype description, and in situ measurement of the physicochemical parameters. We assess the ultrastructure of MTB as a function of depth using light and electron microscopy. We evidence the biogeochemical niche of magnetotactic cocci, capable of sequestering large PolyP inclusions below the oxic–anoxic transition zone. Our results suggest a tight link between the S and P metabolisms of these bacteria and pave the way to better understand the implication of MTB for the P cycle in stratified environmental conditions.

Rapid response petrology for the opening eruptive phase of the 2021 Cumbre Vieja eruption, La Palma, Canary Islands

How and why magmatic systems reactivate and evolve is a critical question for monitoring and hazard mitigation efforts during initial response and ongoing volcanic crisis management. Here we report the first integrated petrological results and interpretation provided to monitoring authorities during the ongoing eruption of Cumbre Vieja, La Palma, Canary Islands, Spain. The first eruptive products comprised simultaneous Strombolian fountain-fed lava flows and tephra fall from near-continuous eruption plumes. From combined field, petrographic and geochemical analyses conducted in the 10 days following sample collection, we infer low percentage mantle melts with a variably equilibrated multimineralic crystal-cargo and compositional fractionation by winnowing during eruptive processes. Hence ‘rapid response’ petrology can untangle complex magmatic and volcanic processes for this eruption, which combined with further study and methodological improvement can increasingly assist in active decision making.

Multi-Level Sensing Technologies in Landslide Research—Hrvatska Kostajnica Case Study, Croatia

In March 2018, a landslide in Hrvatska Kostajnica completely destroyed multiple households. The damage was extensive, and lives were endangered. The question remains: Can it happen again? To enhance the knowledge and understanding of the soil and rock behaviour before, during, and after this geo-hazard event, multi-level sensing technologies in landslide research were applied. Day after the event field mapping and unmanned aerial vehicle (UAV) data were collected with the inspection of available orthophoto and “geo” data. For the landslide, a new geological column was developed with mineralogical and geochemical analyses. The application of differential interferometric synthetic aperture radar (DInSAR) for detecting ground surface displacement was undertaken in order to determine pre-failure behaviour and to give indications about post-failure deformations. In 2020, electrical resistivity tomography (ERT) in the landslide body was undertaken to determine the depth of the landslide surface, and in 2021 ERT measurements in the vicinity of the landslide area were performed to obtain undisturbed material properties. Moreover, in 2021, detailed light detection and ranging (LIDAR) data were acquired for the area. All these different level data sets are being analyzed in order to develop a reliable landslide model as a first step towards answering the aforementioned question. Based on applied multi-level sensing technologies and acquired data, the landslide model is taking shape. However, further detailed research is still recommended.

Genesis of the Eastern Adamello Plutons (Northern Italy): Inferences for the Alpine Geodynamics

The Corno Alto–Monte Ospedale magmatic complex crops out at the eastern border of the Adamello batholith, west of the South Giudicarie Fault (NE Italy). This complex includes tonalites, trondhjemites, granodiorites, granites and diorites exhibiting an unfoliated structure suggesting passive intrusion under extensional-to-transtensional conditions. Major, minor elements, REE and isotopic analyses and geochemical and thermodynamic modelling have been performed to reconstruct the genesis of this complex. Geochemical analyses unravel a marked heterogeneity with a lack of intermediate terms. Samples from different crust sections were considered as possible contaminants of a parental melt, with the European crust of the Serre basement delivering the best fit. The results of the thermodynamic modelling show that crustal melts were produced in the lower crust. Results of the geochemical modelling display how Corno Alto felsic rocks are not reproduced by fractional crystallization nor by partial melting alone: their compositions are intermediate between anatectic melts and melts produced by fractional crystallization. The tectonic scenario which favored the intrusion of this complex was characterized by extensional faults, active in the Southalpine domain during Eocene. This extensional scenario is related to the subduction of the Alpine Tethys in the Eastern Alps starting at Late Cretaceous time.

Integrated petrographic and geochemical analysis of the Langobard age pottery of Szólád, Western Hungary

This study presents the results of the petrographic and geochemical analyses of the entire pottery assemblage discovered at the sixth-century (AD) cemetery of Szólád, Western Hungary, associated with the Langobard era in the territory of the former Roman province of Pannonia. Szólád is one of the most prominent archaeological sites of this period, where prior studies have shown that the cemetery was used for ca. one or two generations by a migrating group of diverse genetic background. The present work is the first integrated typological and archaeological science pottery analysis from the early migration period (fifth to sixth century) Hungary. We applied polarising light optical microscopy (OM), prompt gamma activation analysis (PGAA), and neutron activation analysis (NAA) on all samples and, additionally, scanning electron microscopy equipped with energy dispersive spectrometry (SEM–EDS) on one selected sample. One main fabric group with three subgroups were defined by OM, to which the majority of the samples belong. This fabric group was characterised by aplastic inclusions derived from a carbonate-cemented sandstone typical of the environs of Szólád; therefore, the vessels of this fabric group appear to have been produced locally. The remaining four samples display a variety of unique, ungrouped, fabrics (loners) indicative of different recipes and/or the presence of pottery originating from outside of the region. Our study concludes that the community associated with the cemetery favoured burying pots with the deceased that stylistically resembled archaic “Elbe Germanic” traditions, but which were in fact made locally. However, in some cases, relationships with more distant territories and cultural traditions are also represented.

The Effect of High Power Laser on Organic-Rich Shales

The objective of this work is to characterize the effect of a high power laser (HPL) on organic-rich shales. The analysis combines machine learning with advanced characterizations to reveal the geochemical and mechanical transformations induced by high power laser in source rocks. Lab results showed that HPL improves permeability, increases porosity, modifies the mechanical structure of the rock, and may positively affect the maturity of source rocks. A high power laser was used in the lab to perforate and heat different types of source rocks with varying organic content. The process was characterized in real time using near-infrared spectroscopy and mid-IR thermography. The pre- and post-characterization process draws on different tools to evaluate the chemical and structural transformations induced by the HPL processes. This step included several spectroscopy techniques (e.g., FTIR, UV/VIS/NIR), Rock-Eval, and differential thermal analysis (DTA). The analysis leverages on clustering techniques to reveal the distinct effects of HPL on source rocks. The spectroscopy and geochemical analyses revealed that that HPL modifies the molecular structure of the rock. Yet, the fundamental structure of the rock remains intact. The changes are revealed by clustering analysis of the FTIR data before and after laser heating. The analysis show the formation of clusters after the process, which correspond to the maturation of the organic content. The success of the lab work proved that high power laser could enhance the properties of source rocks. The effects include permeability improvement, enhanced porosity, and changes in the molecular distribution of the organic content. The results of the analyses suggest that the laser can drive forward the maturity of the source rock. This work also illustrates how machine learning and multiphysics characterization can reveal the dynamics of the HPL processes and their effects. Ultimately, the outcome of this study will contribute to the development of novel HPL applications.

Supergene Copper and the Ancient Mining Landscapes of the Atacama Desert: Refining the Protocol for the Study of Archaeological Copper Minerals through the Case Study of Pukara de Turi

Northern Chile is home to the world’s largest copper ore deposits, which have been exploited for thousands of years by different groups, at varying scales and for different purposes. In this context, it is important to develop new protocols to characterise the mineralogical variability of archaeological copper ores. A comprehensive and representative methodology in the analysis of minerals, the application of non-destructive analytical techniques, and the combination of insights from geological, archaeological and local knowledge are key to developing a copper mineral repository of the Atacama Desert area. Geochemical analyses were applied to the study of 568 samples from the archaeological site Pukara de Turi, with different techniques such as micro-XRF, XRD, QEMSCAN, Raman spectroscopy and technological studies. This exhaustive analysis allowed for the recognition of two mineralogical associations: atacamite/brochantite (99%) and azurite/chrysocolla (1%). The study of various minerals allows data to be interpreted more reliably and to trace the likely geological sources of these minerals. The azurite/chrysocolla samples appear to belong to the same mineral association found in the Cerro Verde district, which is probably the source of these samples. The atacamite/brochantite samples appear to come from more than one geological source, including, but not limited to, Chuquicamata-Radomiro Tomic and El Abra-Conchi.

Shale Oil/Gas: A New Opportunity for New Zealand?

<p>Within New Zealand the East Coast Basin encompasses the primary shale oil and gás (unconventional) play areas in which both the Waipawa and Whangai formations are widespread. These formations are oil and gas prone and prevalent throughout a large area of the East Coast Basin. To characterise these two formations and evaluate their shale oil and gas potential, existing analytical results were supplemented by a set of new sample analyses of organic and inorganic geochemistry, and rock properties. Thus, some 242 samples from the Whangai Formation have organic geochemical analyses and 40 have inorganic geochemical analyses; for the Waipawa Formation there are 149 organic and 9 inorganic geochemical analyses. In addition, downhole logs from three exploration wells have been used to calculate the brittleness index of the Whangai Formation. All these data have been grouped by structural block and used to determine where the sweet spots are in each formation. Both basic and more robust statistical analysis (machine-learning) is applied to identify the best prospective area. The Rakauroa Member (Whangai Formation) and the Waipawa Formation have the best rock characteristics as unconventional reservoirs, based on quantity and quality. Maturation appears to be an issue for these formations, although there are some localised areas where the Whangai Formation has better maturity. The brittleness index is calculated only for the Rakauroa Member, given the lack of data available for other members of the Whangai Formation and the Waipawa Formation, and yielded promising results. The Motu block appears to be the best area in which to explore for unconventional oil and gas. The prospective resource volumes for the best case scenario for the Whangai (Rakauroa Member) and Waipawa formations combined in the Motu Block are 17% higher (713MMbbl) than the 2P (proved + probable) reserves of New Zealand for oil and condensate (588MMbbl) and 26% (2.1TCF) of the 2P (proved + probable) reserves of natural gas (7.8 TCF). Economic analysis shows feasibility to explore these unconventional reservoirs for both shale oil or shale gas with an oil price of US$60 for both methodologies tested. However, the methodology applied using standard shale oil and gas assessments shows feasibility only for shale oil. Shale gas would not be economic, unless a higher oil prices, lower costs or a technology was developed to improve the recovery factor of these reservoirs. These results indicate a minimum economic field size of 4.5 km² for this area.</p>