A Combination of N2 and CO2 Adsorption to Characterize Nanopore Structure of Organic-Rich Lower Silurian Shale in the Upper Yangtze Platform, South China: Implications for Shale Gas Sorption Capacity

2017 ◽  
Vol 91 (4) ◽  
pp. 1380-1394 ◽  
Author(s):  
Lei CHEN ◽  
Zhenxue JIANG ◽  
Keyu LIU ◽  
Fenglin GAO ◽  
Pengfei WANG
Fuel ◽  
2014 ◽  
Vol 129 ◽  
pp. 204-218 ◽  
Author(s):  
Jingqiang Tan ◽  
Philipp Weniger ◽  
Bernhard Krooss ◽  
Alexej Merkel ◽  
Brian Horsfield ◽  
...  

Author(s):  
Zhazha Hu ◽  
Garri Gaus ◽  
Timo Seemann ◽  
Qian Zhang ◽  
Ralf Littke ◽  
...  

Abstract The shale gas potential of Ediacaran and Lower Silurian shales from the Upper Yangtze platform is assessed in this study with a focus on the contributions of clay minerals and organic matter to sorption capacity. For this purpose, a multidisciplinary assessment was carried out using petrophysical, mineralogical, petrographic and geochemical methods. In terms of TOC contents (4.2%), brittle mineral contents (68.6%) and maximum gas storage capacities (0.054–0.251 mmol/g) Ediacaran shales from this study show comparable properties to other producing shale gas systems although the thermal maturity is extremely high (VRr = 3.6%). When compared to lower Silurian shales from the same region, it is evident that (1) deeper maximum burial and (2) a lack of silica-associated preservation of the pores resulted in a relatively lower mesopore volume, higher micropore volume fraction and lower overall porosity (Ediacaran shales: 1.4–4.6%; Silurian shales: 6.2–7.4%). Gas production is therefore retarded by poor interconnectivity of the pore system, which was qualitatively demonstrated by comparing experimental gas uptake kinetics. TOC content exhibits a prominent control on sorption capacity and micropore volume for both shales. However, different contributions of clay minerals to sorption capacity were identified. This can partly be attributed to different clay types but is likely also related to burial-induced recrystallisation and different origins of illite. Additionally, it was shown that variations in sorption capacity due to incorrect estimates of clay mineral contribution are in the same range as variations due to differences in thermal maturity. Article highlights Pore structure and gas storage characteristics are evaluated for the first time for Ediacaran Shales from the Upper Yangtze platform Due to a lower free gas storage capacity and diffusivity, the Ediacaran shale can be regarded as a less favorable shale gas prospect when compared to the Silurian shale Clay mineral contribution to sorption capacity is evaluated taking clay mineralogy into consideration Maturity-related changes of organic matter sorption capacity have been discussed on the basis of a compiled data set


2016 ◽  
Vol 121 (2) ◽  
pp. 491-505 ◽  
Author(s):  
Yong Zhang ◽  
Dong Jia ◽  
Hongwei Yin ◽  
Mancang Liu ◽  
Wuren Xie ◽  
...  

2015 ◽  
Vol 3 (2) ◽  
pp. SJ1-SJ13 ◽  
Author(s):  
Shu Jiang ◽  
Jinchuan Zhang ◽  
Zhiqiang Jiang ◽  
Zhengyu Xu ◽  
Dongsheng Cai ◽  
...  

This paper describes the geology of organic-rich shales in China, their resource potentials, and properties of emerging and potential China shale gas and shale oil plays. Marine, lacustrine, and coastal swamp transitional shales were estimated to have the largest technically recoverable shale gas resource (25.08 trillion cubic meters or 886 trillion cubic feet) and 25 to 50 billion barrels of technically recoverable shale oil resource. The Precambrian Sinian Doushantuo Formation to Silurian Longmaxi black marine shales mainly accumulated in the intrashelf low to slope environments in the Yangtze Platform in South China and in the Tarim Platform in northwest China. The marine shales in the Yangtze Platform have high maturity (Ro of 1.3%–5%), high total organic carbon (mainly [Formula: see text]), high brittle-mineral content, and have been identified as emerging shale gas plays. The Lower Paleozoic marine shales in the Upper Yangtze area have the largest shale gas potential and currently top the list as exploration targets. The Carboniferous to Permian shales associated with coal and sandstones were mainly formed in transitional depositional settings in north China, northwest China, and the Yangtze Platform in south China. These transitional shales are generally rich in clay with a medium level of shale gas potential. The Middle Permian to Cenozoic organic-rich lacustrine shales interbedded with thin sandstone and carbonate beds are sporadically distributed in rifted basins across China. Their main potentials are as hybrid plays (tight and shale oil). China shales are heterogeneous across time and space, and high-quality shale reservoirs are usually positioned within transgressive systems tract to early highstand systems tract intervals that were deposited in an anoxic depositional setting. For China’s shale plays, tectonic movements have affected and disrupted the early oil and gas accumulation, making tectonically stable areas more favorable prospects for the exploration and development of shale plays.


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