Basalt-derived krasnozems are generally well-structured soils; however, there
is a concern that intensive agricultural practices may result in an adverse
decline in soil organic carbon, organic matter chemistry, and structural
quality over time. A study was conducted on loam to silty clay loam krasnozems
(Ferrosols) near Ballarat in south-western Victoria to assess changes in soil
C, soil structural stability, and C chemistry, at the 0–10 cm soil
depth, under 3 paired sites consisting of adjacent long-term forest (Monterey
pine or eucalyptus) v. 30 year cropping [3 year
pasture–2 year crops (potato and a root crop or grain)]. Soil
structural stability was also characterised in the A and B horizons under
long-term eucalyptus and several cropped sites. Organic C levels in the A
horizons for all the soils were relatively high, ranging from 46 to 89
g/kg. A lower organic C (30%), associated mainly with loss of the
sand-sized (>53 m) macro-C fraction, and a decrease in exchangeable Ca and
Mg was found in the agricultural soils, compared with forest soils. Physically
protected C in the <53 m fraction, as indicated by UV photo-oxidation, was
similar among soils. Wet sieving indicated a decline of both C and N
concentration in water-stable aggregates and the degree of macro-aggregation
under agricultural soils, compared with the forest soils. However, soil
structural changes under cropping were mainly related to a decline in the
>5 mm sized aggregates, with no deleterious increase in the proportion of
0.10 mm aggregates. Solid state 13C NMR spectroscopy
indicated a decrease in O-alkyl and alkyl C under pasture and cropping
compared with forest soils, which was in agreement with the decline in the
macro-C fraction. Characterisation of C chemistry following UV photo-oxidation
showed that charcoal C (dominant presence of aryl C) accounted for 30%
of the total soil organic C, while other functional groups (polysaccharides
and alkyl C) were probably protected within micro-aggregates. Based on soil
organic C and aggregate stability determinations alone, the implications for
soil physical quality, soil loss, and diffuse pollution appear minimal.
macroorganic carbon, soil aggregation, charcoal, photo-oxidation, potato
rotation, CP/MAS 13C NMR spectroscopy.