Magnetically Assembling Nanoscale Metal Network Into Phase Change Material—Percolation Threshold Reduction in Paraffin Using Magnetically Assembly of Nanowires

Author(s):  
Junwei Su ◽  
Iman Mirzaee ◽  
Fan Gao ◽  
Xiao Liu ◽  
Majid Charmchi ◽  
...  

A high throughput manufacturing process to magnetically assembling nanowire (NW) network into paraffin was developed for enhancing conductivity in phase change materials (PCMs) used in energy storage applications. The prefabricated nickel NWs were dispersed in melted paraffin followed by magnetic alignment under a strong magnetic field. Measuring electrical conductivity of the nanocomposite, as well as observing cross section of the sample slice under an optical microscope characterized the alignment of NWs. As a comparison, nickel particles (NPs) based paraffin nanocomposites were also fabricated, and its electrical conductivity with and without applied magnetic field were measured. The effects of aspect ratio of fillers (particles and NWs) and volume concentration on percolation threshold were studied both experimentally and theoretically. It was found that the NW based paraffin nanocomposite has much lower percolation threshold compared to that of particle based paraffin composite. Furthermore, the alignment of particles and NWs under magnetic field significantly reduces the threshold of percolation. This work provides solid foundation for the development of a manufacturing technology for high thermal conductivity PCMs for thermal energy storage applications.

2014 ◽  
Author(s):  
Junwei Su ◽  
Xiao Liu ◽  
Iman Mirzaee ◽  
Fan Gao ◽  
Majid Charmchi ◽  
...  

A high throughput manufacturing process to magnetically assembling nanowire (NW) network into paraffin was developed for enhancing conductivity in phase change materials (PCMs) used in energy storage applications. The prefabricated nickel nanowires were dispersed in melted paraffin followed by magnetic alignment under a strong magnetic field. Measuring electrical conductivity of the nanocomposites, as well as observing cross-section of the sample slice under an optical microscope characterized the alignment of nanowires. As a comparison, nickel particles (NPs) based paraffin nanocomposites were also fabricated and its electrical conductivity with and without applied magnetic field were measured. The effects of aspect ratio of fillers (particles and nanowires) and volume concentration on percolation threshold were studied both experimentally and theoretically. It was found that the nanowire based paraffin nanocomposite has much lower percolation threshold compared to that of particle based paraffin composite. Furthermore, the alignment of particles and nanowires under magnetic field significantly reduce the threshold of percolation. This work provides solid foundation for the development of a manufacturing technology for high thermal conductivity phase change materials (PCM) for thermal energy storage applications.


Energies ◽  
2021 ◽  
Vol 14 (19) ◽  
pp. 6176 ◽  
Author(s):  
Hamidreza Behi ◽  
Mohammadreza Behi ◽  
Ali Ghanbarpour ◽  
Danial Karimi ◽  
Aryan Azad ◽  
...  

Usage of phase change materials’ (PCMs) latent heat has been investigated as a promising method for thermal energy storage applications. However, one of the most common disadvantages of using latent heat thermal energy storage (LHTES) is the low thermal conductivity of PCMs. This issue affects the rate of energy storage (charging/discharging) in PCMs. Many researchers have proposed different methods to cope with this problem in thermal energy storage. In this paper, a tubular heat pipe as a super heat conductor to increase the charging/discharging rate was investigated. The temperature of PCM, liquid fraction observations, and charging and discharging rates are reported. Heat pipe effectiveness was defined and used to quantify the relative performance of heat pipe-assisted PCM storage systems. Both experimental and numerical investigations were performed to determine the efficiency of the system in thermal storage enhancement. The proposed system in the charging/discharging process significantly improved the energy transfer between a water bath and the PCM in the working temperature range of 50 °C to 70 °C.


2015 ◽  
Vol 830-831 ◽  
pp. 505-508 ◽  
Author(s):  
R. Sudheer ◽  
K. Narayan Prabhu

In recent years phase change materials have emerged to be ideal energy storage materials for their higher energy density over sensible heat storing materials. Use of phase change materials (PCM) have been successfully implemented at lower temperature applications with various organic compounds. On the other hand, high temperature applications have been solely dominated by various salts, their eutectics and mixtures as phase change materials. This work discusses the suitability of metals and alloys for thermal energy storage applications as the phase change material. Metals offer superior thermal conductivities with considerable energy density compared to salts. Here, two alloys namely, Sn-0.3Ag-0.7Cu (SAC) solidifying over 212-224°C and ZA8 (Zn-8%Al) solidifying over 378-405°C have been studied. Thermal analysis of PCMs using Computer Aided Cooling Curve Analysis (CA-CCA) and DSC technique were performed to predict the solidification path. In addition to this, Newtonian technique was employed to estimate the latent heat of fusion for these phase change materials. Cooling rate curves and Fraction Solid curves offered a better insight into their ability to receive and discharge heat over the concerned temperature range.


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