Ab initiomolecular orbital characterization of dimethyl group-III azides as sources for photolytic production of free radical beams

2002 ◽  
Vol 20 (3) ◽  
pp. 995-998 ◽  
Author(s):  
Keiji Hayashi ◽  
Takuo Kanayama ◽  
Toyohiro Shimizu ◽  
Yasunori Kawamura ◽  
Kenji Kameko ◽  
...  
Keyword(s):  
Author(s):  
Marcelo Daniel Sciorra ◽  
Elisa Fantino ◽  
Cecilia Eugenia María Grossi ◽  
Rita María Ulloa
Keyword(s):  

2009 ◽  
Vol 114 (1) ◽  
pp. 276-281 ◽  
Author(s):  
Ilkay Orhan ◽  
Murat Kartal ◽  
Mahmoud Abu-Asaker ◽  
F. Sezer Şenol ◽  
Gülderen Yilmaz ◽  
...  

1998 ◽  
Vol 189-190 ◽  
pp. 435-438 ◽  
Author(s):  
Hiroshi Harima ◽  
Toshiaki Inoue ◽  
Shin-ichi Nakashima ◽  
Hajime Okumura ◽  
Yuuki Ishida ◽  
...  

2007 ◽  
Vol 60 (3) ◽  
pp. 173 ◽  
Author(s):  
Petre Ionita ◽  
Floriana Tuna ◽  
Marius Andruh ◽  
Titus Constantinescu ◽  
Alexandru T. Balaban

Starting from the well known stable free radical 2,2-diphenyl-1-picrylhydrazyl (DPPH; 2a) and its congener 2,2-diphenyl-1-(4-cyano-2,6-dinitrophenyl)hydrazyl 2b, or from their reduced hydrazine counterparts 1a,b, it was possible to obtain the p-quinonoid compounds 4a,b by oxidation with ceric (Ce4+) sulfate, which by reduction gave the corresponding hydroxyl derivatives 2-phenyl-2-(4-hydroxyphenyl)-1-picrylhydrazine 5a or 2-phenyl-2-(4-hydroxyphenyl)-1-(4-cyano-2,6-dinitrophenyl)hydrazine 5b. These hydroxyl derivatives (5a,b) react with 4-carboxy-TEMPO or 2,2-diphenyl-1-(4-carboxy-2,6-dinitrophenyl)hydrazine to form the corresponding esters 6a,b or 8a,b. These esters (6a,b and 8a,b) lead to the hybrid hetero diradicals (nitroxide–hydrazyl type) 7a,b or homo biradicals (hydrazyl–hydrazyl type) 9a,b by oxidation with lead dioxide or potassium permanganate. The new compounds were characterized by UV-vis, NMR, EPR, and MS analysis, and their magnetic behaviour was investigated.


RSC Advances ◽  
2016 ◽  
Vol 6 (45) ◽  
pp. 39522-39529 ◽  
Author(s):  
Wanfen Pu ◽  
Daijun Du ◽  
Rui Liu ◽  
Jiongyi Gu ◽  
Kewei Li ◽  
...  

HDPAM was synthesized by water free-radical copolymerization based on functional hyperbranched polyamide-modified ultrafine silica as functional monomer.


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