Experimental study on supersonic all gas-phase iodine laser driven by NF3/D2/DCl/CF3I combustion

Flowing afterglow measurements are reported which provide rate constants and product identifications at 298 ± 2 K for the gas-phase reactions of OH− with CH3OH, C2H5OH, CH3OCH3, CH2O, CH3CHO, CH3COCH3, CH2CO, HCOOH, HCOOCH3, CH2=C=CH2, CH3—C≡CH, and C6H5CH3. The main channels observed were proton transfer and solvation of the OH−. Hydration with one molecule of H2O was observed either to reduce the rate slightly and lead to products which are the hydrated analogues of the "nude" reaction, or to stop the reaction completely, k ≤ 10−12 cm3 molecule−1 s−1. The reaction of OH−•H2O with CH3—C≡CH showed an uncertain intermediate behaviour.

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First accurate experimental study of Mu reactivity from a state-selected reactant in the gas phase: the Mu + H2{1} reaction rate at 300 K

Journal of Physics B Atomic Molecular and Optical Physics ◽

10.1088/0953-4075/48/4/045204 ◽

2015 ◽

Vol 48 (4) ◽

pp. 045204 ◽

Cited By ~ 2

Author(s):

Pavel Bakule ◽

Oleksandr Sukhorukov ◽

Katsuhiko Ishida ◽

Francis Pratt ◽

Donald Fleming ◽

...

Keyword(s):

Experimental Study ◽

Gas Phase ◽

Reaction Rate

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A study on an all gas-phase iodine laser based on NCl 3 reaction system

10.1117/12.762084 ◽

2008 ◽

Cited By ~ 1

Author(s):

Taizo Masuda ◽

Tomonari Nakamura ◽

Masamori Endo ◽

Taro Uchiyama

Keyword(s):

Gas Phase ◽

Reaction System ◽

Iodine Laser

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A multiwatt all gas-phase iodine laser (AGIL)

10.1117/12.548614 ◽

2004 ◽

Cited By ~ 1

Author(s):

Gerald C. Manke II ◽

Chris B. Cooper ◽

Shiv C. Dass ◽

Timothy J. Madden ◽

Gordon D. Hager

Keyword(s):

Gas Phase ◽

Iodine Laser

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An experimental study of the gas-phase kinetics of reactions with hydrated hydronium(1+) ions(n = 1-3) at 298 K

Journal of the American Chemical Society ◽

10.1021/ja00508a003 ◽

1979 ◽

Vol 101 (14) ◽

pp. 3724-3730 ◽

Cited By ~ 56

Author(s):

D. K. Bohme ◽

G. I. Mackay ◽

S. D. Tanner

Keyword(s):

Experimental Study ◽

Gas Phase ◽

Gas Phase Kinetics ◽

Kinetics Of

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Experimental investigation of slag/matte/metal/ tridymite equilibria in the Cu–Fe–O–S–Si system at 1473 K (1200°C), 1523 K (1250°C) and 1573 K (1300°C)

International Journal of Materials Research (formerly Zeitschrift fuer Metallkunde) ◽

10.1515/ijmr-2020-1110502 ◽

2020 ◽

Vol 111 (5) ◽

pp. 365-372

Author(s):

Svetlana Sineva ◽

Jeff Chen ◽

Taufiq Hidayat ◽

Maksym Shevchenko ◽

Peter C. Hayes ◽

...

Keyword(s):

Experimental Study ◽

Experimental Investigation ◽

High Temperature ◽

Gas Phase ◽

Closed System ◽

Electron Probe ◽

Quantitative Measurement ◽

Experimental Information ◽

X Ray ◽

Fast Quenching

Abstract Laboratory experimental study was undertaken to characterise the four-phase slag/matte/metal/tridymite equilibria of the Cu-Fe-O-S-Si system at 1473 K [1200°C], 1523 K [1250° C] and 1573 [1300°C] in a "closed" system without interaction with gas phase. The research methodology involved high temperature equilibration, ultra-fast quenching of the equilibrated samples followed by quantitative measurement of the equilibrated phases by electron probe X-ray microanalysis. Attainment of chemical equilibrium was carefully checked by the 4-points test approach. The results obtained in the present study provide reliable fundamental experimental information, which is crucial for the development and optimisation of the multicomponent thermodynamic database for copper-containing systems.

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