Photodissociation of mass-selected clusters: solvated metal ions

1992 ◽  
Author(s):  
James M. Farrar ◽  
Stephen G. Donnelly
Keyword(s):  
Metal Ions ◽  
Solvated Metal Ions

Coordination and ligand exchange dynamics of solvated metal ions

2005 ◽  
Vol 249 (24) ◽  
pp. 2993-3006 ◽  
Author(s):  
B.M. Rode ◽  
C.F. Schwenk ◽  
T.S. Hofer ◽  
B.R. Randolf
Keyword(s):  
Metal Ions ◽  
Ligand Exchange ◽  
Solvated Metal Ions

9 Solvated metal ions and ion clusters, and the effect of ligands upon their reactivity

2001 ◽  
pp. 295-324 ◽  
Author(s):  
Vladimir E. Bondybey ◽  
Martin Beyer ◽  
Uwe Achatz ◽  
Brigitte Fox ◽  
Gereon Niedner-Schatteburg
Keyword(s):  
Metal Ions ◽  
Ion Clusters ◽  
Solvated Metal Ions

Photodissociation of mass-selected solvated metal ions: monoaquastrontium(+)

1987 ◽  
Vol 91 (26) ◽  
pp. 6447-6449 ◽  
Author(s):  
M. H. Shen ◽  
J. W. Winniczek ◽  
J. M. Farrar
Keyword(s):  
Metal Ions ◽  
Solvated Metal Ions

scholarly journals On the relationship between the structural and volumetric properties of solvated metal ions inO-donor solvents using new structural data in amide solvents

2018 ◽  
Vol 20 (21) ◽  
pp. 14525-14536 ◽  
Author(s):  
Daniel Lundberg ◽  
Dorota Warmińska ◽  
Anna Fuchs ◽  
Ingmar Persson
Keyword(s):  
Metal Ions ◽  
Chemical Properties ◽  
Structural Data ◽  
Volumetric Properties ◽  
Physico Chemical ◽  
Solvated Metal Ions ◽  
The Relationship

The relationship between the structural and volumetric properties of ions in solvents with different physico-chemical properties has been studied for 19 cations and six anions in six solvents.

scholarly journals Complexes of Bismethyl-imido-triphosphoric-acid-pentakis-dimethyl-amide (TRIPA), a New Tridentate Ligand

1972 ◽  
Vol 27 (11) ◽  
pp. 1324-1329 ◽  
Author(s):  
M. W. G. De Bolster ◽  
J. Den Heijer ◽  
W. L. Groeneveld
Keyword(s):  
Metal Ions ◽  
Geometric Isomer ◽  
Tridentate Ligand ◽  
Nitrate Anion ◽  
Chemical Formula ◽  
Chloride Complexes ◽  
Paramagnetic Resonance ◽  
Physical Measurements ◽  
Solvated Metal Ions ◽  
Electron Paramagnetic

A number of new complexes containing TRIPA, chemical formula [ (CH3) 2N]2 P (O) N (CH3)P (O) [N (CH3) 2] N (CH3) P (O) [N (CH3) 2] 2, is reported The compounds have the general formula M (TRIPA) n (anion) p, where M = Mg, Ca, Mn, Fe, Co, Ni, Cu, Zn, Cd (p = 2) and Al, Fe (p = 3), n=1,2 and anion stands for BF4⁻, [B (C6H5)4]⁻, NO3⁻ and Cl⁻. They are characterized and identified by chemical analysis and physical measurements.It is shown that the bis-compounds contain octahedrally solvated metal ions, the ligand acting as a tridentate phosphoryl donor. Electron paramagnetic resonance measurements show some distortion of the octahedrons. The mono-compounds with the nitrate anion probably possess a fivecoordinated structure whereas the chloride complexes are probably dimeric.The occurrence of more than one geometric isomer for the group [M (TRIPA) 2] P* is discussed. It is concluded that the s-facial and u-facial isomers may occur; a possible connection with the size of the metal ions is indicated. The mer form is rejected because of steric requirements.

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