Structure of solvated metal ions in nitrate and chloride solutions of erbium(III) and yttrium(III) in dimethyl sulfoxide

1991 ◽  
Vol 20 (9) ◽  
pp. 859-874 ◽  
Author(s):  
Georg Johansson ◽  
Haruhiko Yokoyama ◽  
Hitoshi Ohtaki
Keyword(s):  
Metal Ions ◽  
Dimethyl Sulfoxide ◽  
Chloride Solutions ◽  
Solvated Metal Ions

Coordination and ligand exchange dynamics of solvated metal ions

2005 ◽  
Vol 249 (24) ◽  
pp. 2993-3006 ◽  
Author(s):  
B.M. Rode ◽  
C.F. Schwenk ◽  
T.S. Hofer ◽  
B.R. Randolf
Keyword(s):  
Metal Ions ◽  
Ligand Exchange ◽  
Solvated Metal Ions

9 Solvated metal ions and ion clusters, and the effect of ligands upon their reactivity

2001 ◽  
pp. 295-324 ◽  
Author(s):  
Vladimir E. Bondybey ◽  
Martin Beyer ◽  
Uwe Achatz ◽  
Brigitte Fox ◽  
Gereon Niedner-Schatteburg
Keyword(s):  
Metal Ions ◽  
Ion Clusters ◽  
Solvated Metal Ions

Photodissociation of mass-selected solvated metal ions: monoaquastrontium(+)

1987 ◽  
Vol 91 (26) ◽  
pp. 6447-6449 ◽  
Author(s):  
M. H. Shen ◽  
J. W. Winniczek ◽  
J. M. Farrar
Keyword(s):  
Metal Ions ◽  
Solvated Metal Ions

scholarly journals Separation Studies of Pd(II) from Acidic Chloride Solutions of Pt(IV), Ni(II) and Rh(III) by Using 4-Aroyl-3-Phenyl-5-Isoxazolones

2012 ◽  
Vol 9 (2) ◽  
pp. 756-765
Author(s):  
Koduru Janardhan Reddy ◽  
Kap Duk Lee
Keyword(s):  
Metal Ions ◽  
Water Samples ◽  
Liquid Extraction ◽  
Selective Separation ◽  
Extraction Mechanism ◽  
Chloride Solutions ◽  
Liquid Liquid Extraction ◽  
Separation Factors ◽  
Acidic Chloride ◽  
Synthetic Water

This study examined the effect influence of various factors on the extraction of Pd(II) to develop a new liquid-liquid extraction mechanism for the selective separation of palladium(II) from its acidic chloride solutions using 4-aroyl-3-phenyl-5-isoxazolones (HA), such as 3-phenyl-4-(4-fluorobenzoyl)-5- isoxazolone (HFBPI), 3-phenyl-4-benzoyl-5-isoxazolone (HPBI) and 3-phenyl-4- (4-toluoyl)-5-isoxazolone (HTPI). The extraction strength of Pd(II) with HA were in the following order: HFBPI > HPBI > HTPI, which is opposite to that observed with their pKavalues. HPBI was used to separate Pd(II) from Pt(IV), Ni(II) and Rh(III) metal ions and calculated their separation factors (S.F.) were followed in the order: Pd/Ni (40±0.4) > Pd/Pt (25±0.2) > Pd/Rh (15±0.3 > Rh/Ni (2.7±0.3) > Pt/Ni ≈ Rh/Pt (1.7±0.2). The loading and striping of Pd(II) (1.12×10-4mol L-1) were also examined using 1.0×10-3mol L-1HPBI in CHCl3and 1.0 mol L-1HCl, respectively. The results demonstrated that the maximum (97.5%) extraction and desorption (89%) of metal required at least 3.0 cycles. The developed method was applied successfully to the separation of palladium from synthetic water samples.

scholarly journals On the relationship between the structural and volumetric properties of solvated metal ions inO-donor solvents using new structural data in amide solvents

2018 ◽  
Vol 20 (21) ◽  
pp. 14525-14536 ◽  
Author(s):  
Daniel Lundberg ◽  
Dorota Warmińska ◽  
Anna Fuchs ◽  
Ingmar Persson
Keyword(s):  
Metal Ions ◽  
Chemical Properties ◽  
Structural Data ◽  
Volumetric Properties ◽  
Physico Chemical ◽  
Solvated Metal Ions ◽  
The Relationship

The relationship between the structural and volumetric properties of ions in solvents with different physico-chemical properties has been studied for 19 cations and six anions in six solvents.

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