Kinetics of nonstationary migration-accelerated energy transfer in a solid body doped with rare-earth and transition-metal ions

2014 ◽  
Vol 116 (5) ◽  
pp. 700-705
Author(s):  
N. A. Glushkov
2003 ◽  
Vol 486 (1) ◽  
pp. 1-10 ◽  
Author(s):  
Juan Dı́az-Garcı́a ◽  
José M Costa-Fernández ◽  
Nerea Bordel ◽  
Rosario Pereiro ◽  
Alfredo Sanz-Medel

Author(s):  
Harichandra A Parbat ◽  
D V Prabhu ◽  
Anna Pratima Nikalje

Oxidation of alcohols has industrial importance as it yields several useful products.Toxic and costly metal ions like Os(VIII), Cr(VI), and Ru in different oxidation states are widely used for the oxidation of a variety of organic compounds. We are reporting herein the oxidation of the industrially useful primary alcohols, 2-Chloroethanol, 2-Butoxyethanol and 2-Phenoxyethanol using Ammonium metavanadate in acidic medium. Relatively less toxic and cheaper transition metal ions of the first series are effectively used as homogeneous catalysts for the oxidation of the alcohols to the corresponding aldehydes. 2- Chloroethanol is used as a precursor for ethylene oxide and is useful in the manufacture of crop protection chemicals, and pharmaceuticals.2-Butoxyethanol finds use in the making of paints, varnishes and industrial and household cleaners.


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