Synthesis and crystal structure of a new ternary intermetallic compound Ce16Ru8 + x In3 − x (0 < x < 1.0)

2011 ◽  
Vol 56 (2) ◽  
pp. 218-222 ◽  
Author(s):  
Zh. M. Kurenbaeva ◽  
A. I. Tursina ◽  
E. V. Murashova ◽  
S. N. Nesterenko ◽  
Yu. D. Seropegin
ChemInform ◽  
2010 ◽  
Vol 33 (51) ◽  
pp. no-no
Author(s):  
O. Ya. Zelinska ◽  
V. V. Pavlyuk ◽  
A. V. Zelinskiy ◽  
V. M. Davydov

2002 ◽  
Vol 343 (1-2) ◽  
pp. 132-134 ◽  
Author(s):  
O.Ya Zelinska ◽  
V.V Pavlyuk ◽  
A.V Zelinskiy ◽  
V.M Davydov

1991 ◽  
Vol 6 (10) ◽  
pp. 2077-2083 ◽  
Author(s):  
Pedro B. Celis ◽  
Eiji Kagawa ◽  
Kozo Ishizaki

The new ternary intermetallic compound Zr3Ti2Si3, with a (Mn5Si3)16H crystal structure, was designed based on the information of the crystal structure of the related binary compounds Zr5Si3 and Ti5Si3 in order to be used in ultra-high temperature structural applications. By x-ray diffraction analysis, we demonstrate the possibility of substituting an entire layer of zirconium atoms with a layer of titanium atoms in the (Zr5Si3)16H. An analysis of atomic neighbor distances in each compound was done. It was found that the Zr–Si relative interatomic distance diminishes while the Ti–Si distance increases. This indicates that Zr–Si bond strength is maintained as in the binary Zr5Si3. The resulting ternary intermetallic compound has a 16H crystal structure and has a lower density than the original compound of zirconium silicide. This new compound, which is stronger than Ti5Si3 and lighter than Zr5Si3, is considered an excellent candidate of the next generation of intermetallic compounds for ultra-high temperature structural applications.


2009 ◽  
Vol 25 ◽  
pp. 123-124 ◽  
Author(s):  
Mosbah JEMMALI ◽  
Siwar WALHA ◽  
Rached BEN HASSEN ◽  
Henri NOËL

1998 ◽  
Vol 552 ◽  
Author(s):  
Yoshinao Mishima ◽  
Keurn-Yeon Hwang ◽  
Fu-Gao Wei

ABSTRACTIntermetallic compound Co3A1Cx, or called ic-phase, has been reported to assume the E21, or Perovskite structure. In the present work its crystal structure is critically reinvestigated in the two-phase alloys containing κ-phase in the Co primary solid solution matrix, α(Co), using conventional electron diffraction. It is shown that the crystal structure of κ-phase is a derivative of E21 being a cubic structure composed of eight E21 sub-unit cells in a half of which the body center sites are not occupied by carbon atoms. As a result, its space group is Fm3m and the chemical formula should be Co3AIC0.5. It is also found that the lattice parameter of the phase is about twice as large as that of α(Co). Orientation relationship of the κ-phase with the matrix α(Co) is found to be similar to the case for the γ' phase with the fcc γmatrix in a Ni-base superalloy since three orthogonal axes of κ-phase are parallel to those of α(Co). Lattice misfit under this orientation relationship between the two phases is found to be about 2.5%.


1994 ◽  
Vol 49 (1) ◽  
pp. 27-30 ◽  
Author(s):  
Klaus-Jürgen Range ◽  
Georg H. Grosch ◽  
Franz Rau ◽  
Ulrich Klement

Abstract The intermetallic compound Rb3Au7 could be synthesized from the elements at 4 kbar, 700 °C in a modified Belt-type apparatus. The structure (Cmmm; a = 5.579(1), b = 13.267(5), c = 7.265(2) Å; Z = 2; R = 0.035, Rw = 0,031) comprises three crystallographically independent Au atoms, arranged in layers along the c-axis. The shortest interatomic distances are Au -Au = 2.633Å, Au -Rb = 3.438Å and Rb -Rb = 3.622Å.


2019 ◽  
Vol 806 ◽  
pp. 58-62
Author(s):  
Takuya Sasaki ◽  
Takashi Kato ◽  
Jun Fukushima ◽  
Yamato Hayashi ◽  
Hirotsugu Takizawa

Author(s):  
C. S. Lin ◽  
W. A. Chiou ◽  
M. Meshii

The galvannealed steel sheets have received ever increased attention because of their excellent post-painting corrosion resistance and good weldability. However, its powdering and flaking tendency during press forming processes strongly impairs its performance. In order to optimize the properties of galvanneal coatings, it is critical to control the reaction rate between solid iron and molten zinc.In commercial galvannealing line, aluminum is added to zinc bath to retard the diffusion rate between iron and zinc by the formation of a thin layer of Al intermetallic compound on the surface of steel at initial hot-dip galvanizing. However, the form of this compound and its transformation are still speculated. In this paper, we report the direct observations of this compound and its transformation.The specimens were prepared in a hot-dip simulator in which the steel was galvanized in the zinc bath containing 0.14 wt% of Al at a temperature of 480 °C for 5 seconds and was quenched by liquid nitrogen.


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