Direct observation of Fe-Al-Zn ternary intermetallic compound and its transformation during the early stage of hot-dip galvanizing

1993 ◽  
Vol 51 ◽  
pp. 1116-1117
Author(s):  
C. S. Lin ◽  
W. A. Chiou ◽  
M. Meshii
Keyword(s):  
Intermetallic Compound ◽  
Reaction Rate ◽  
Diffusion Rate ◽  
Early Stage ◽  
Zinc Bath ◽  
Steel Sheets ◽  
Direct Observations ◽  
Solid Iron ◽  
Iron And Zinc ◽  
Ternary Intermetallic Compound

The galvannealed steel sheets have received ever increased attention because of their excellent post-painting corrosion resistance and good weldability. However, its powdering and flaking tendency during press forming processes strongly impairs its performance. In order to optimize the properties of galvanneal coatings, it is critical to control the reaction rate between solid iron and molten zinc.In commercial galvannealing line, aluminum is added to zinc bath to retard the diffusion rate between iron and zinc by the formation of a thin layer of Al intermetallic compound on the surface of steel at initial hot-dip galvanizing. However, the form of this compound and its transformation are still speculated. In this paper, we report the direct observations of this compound and its transformation.The specimens were prepared in a hot-dip simulator in which the steel was galvanized in the zinc bath containing 0.14 wt% of Al at a temperature of 480 °C for 5 seconds and was quenched by liquid nitrogen.

Structural and magnetic properties of a novel ternary intermetallic compound CePd3Sn2

2018 ◽  
Vol 739 ◽  
pp. 518-521 ◽  
Author(s):  
C.L. Yang ◽  
S. Tsuda ◽  
K. Umeo ◽  
T. Onimaru ◽  
W. Paschinger ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Intermetallic Compound ◽  
Structural And Magnetic Properties ◽  
Ternary Intermetallic Compound

scholarly journals Comparing hydrogen absorption kinetics of the samples of intermetallic compound and metal hydride compact on its basis

2021 ◽  
Vol 2057 (1) ◽  
pp. 012043
Author(s):  
I A Romanov ◽  
V I Borzenko ◽  
A N Kazakov
Keyword(s):  
Intermetallic Compound ◽  
Metal Hydride ◽  
Hydrogen Absorption ◽  
Reaction Rate ◽  
Nickel Foam ◽  
High Confidence ◽  
Compact Sample ◽  
Kinetics Of ◽  
Rate Controlling Step ◽  
Absorption Of Hydrogen

Abstract This work is devoted to an experimental study and comparison of the kinetics of hydrogen absorption by an intermetallic compound LaNi4.4Al0.3Fe0.3 in form of pure intermetallic compound free backfill and a compact based on it obtained by cold pressing with a spiral matrix of nickel-foam. To calculate the kinetic parameters of the hydrogen absorption reaction, the initial rates method is used. The PCT absorption isotherms are measured at temperatures of 313, 333, and 353 K. The experimental data are described with quite high confidence by the chosen model, which assumes that the reaction rate controlling step is the dissociative absorption of hydrogen on the surface of the a-phase. The rate of hydrogen absorption increases with increasing pressure drop and temperature. It is shown that the rate of hydrogen absorption by the sample of pure IMC is significantly less dependent on temperature compared to the compact sample. In addition, the reaction rate at temperatures of 313 and 333 K is higher for the free backfill sample, and at 353 K it is higher for the metal hydride compact. The values of the absorption constant and the activation energy of the hydrogen absorption reaction are determined for both samples.

Reaction rate of combustion synthesis of an intermetallic compound

1998 ◽  
Vol 95 (2) ◽  
pp. 175-181 ◽  
Author(s):  
Tomohiro Akiyama ◽  
Hiromichi Isogai ◽  
Jun-ichiro Yagi
Keyword(s):  
Intermetallic Compound ◽  
Combustion Synthesis ◽  
Reaction Rate ◽  
Rate Of Combustion

In Situ Spectroscopic Ellipsometry Study of SiC Oxidation at Low Oxygen-Partial-Pressures

2010 ◽  
Vol 645-648 ◽  
pp. 813-816 ◽  
Author(s):  
Keiko Kouda ◽  
Yasuto Hijikata ◽  
Hiroyuki Yaguchi ◽  
Sadafumi Yoshida
Keyword(s):  
Growth Rate ◽  
Spectroscopic Ellipsometry ◽  
Reaction Rate ◽  
Oxidation Process ◽  
Early Stage ◽  
Oxide Thickness ◽  
Oxide Growth ◽  
Low Oxygen ◽  
Partial Pressures

We have investigated the oxidation process of SiC (000-1) C-face at low oxygen partial pressures using an in-situ spectroscopic ellipsometry. The oxide growth rate decreased steeply at the early stage of oxidation and then slowly decreased with increasing oxide thickness. The initial oxide growth rate was almost proportional to the oxygen　partial　pressure for both the polar directions. This result suggests that the initial interfacial reaction rate is constant regardless of the concentration of oxidants reaching the interface.

Microstructure and Microtexture Evolution during Batch Annealing of Warm-Rolled Ti-IF Steel Sheets

2013 ◽  
Vol 331 ◽  
pp. 443-447 ◽  
Author(s):  
Fu Tao Han ◽  
Zuo Cheng Wang ◽  
Cai Nian Jing ◽  
Xiao Min Liu ◽  
Jie Su ◽  
...  
Keyword(s):  
Recrystallization Texture ◽  
Early Stage ◽  
Fiber Texture ◽  
Nucleation Mechanism ◽  
If Steel ◽  
Steel Sheets ◽  
Leading Role ◽  
Batch Annealing ◽  
Texture Characteristics ◽  
Microstructure And Microtexture

Microstructure and microtexture evolution during batch annealing of warm-rolled Ti-IF steel sheets were investigated in this paper. It was founded that α fiber texture and the relatively weak γ fiber texture were formed in warm-rolled and air-cooled Ti-IF steel sheets. In the early stage of recrystallization, the {111} recrystallization texture was formed from the deformed {111} grains in warm-rolled Ti-IF steels. In the later stage of recrystallization, the α fiber texture was consumed and the γ fiber texture in recrystallized grains was further developed. The main recrystallization texture characteristics of warm-rolled Ti-IF steel sheets had been decided in the early stages of recrystallization, and the oriented nucleation mechanism played a leading role in the formation of recrystallization texture in warm-rolled Ti-IF steel sheets.

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