Electrophysical Properties of Composites Based on Polyethylene Modified with Multi-Walled Carbon Nanotubes with High Content of Fe–Co-Catalyst

2020 ◽  
Vol 93 (4) ◽  
pp. 586-594
Author(s):  
S. I. Moseenkov ◽  
V. L. Kuznetsov ◽  
A. V. Zavorin ◽  
G. V. Golubtsov ◽  
E. Yu. Korovin ◽  
...  
2020 ◽  
Vol 10 ◽  
pp. 56-68
Author(s):  
A. A. Leonov ◽  
◽  
E. V. Abdulmenova ◽  
M. P. Kalashnikov ◽  
◽  
...  

In this work, composites based on yttria-stabilized zirconia (3Y-TZP), with additives of 1, 5 and 10 wt. % multi-walled carbon nanotubes (MWCNTs) were investigated. Samples were obtained by spark plasma sintering at a temperature of 1500 °C. It was found that MWCNTs retain their structure after high-temperature sintering, they are located along the grain boundaries of ZrO2, forming a network structure. Found that the addition of 1 wt. % MWCNTs increase the relative density of the composite from 98.3 % to 99.0 %. It is noted that nanotubes can significantly affect the phase composition of composites. Additive 5 wt. % MWCNT partially limits the monoclinic-tetragonal phase transition of ZrO2, and the addition of 10 wt. % MWCNTs leads to the formation of a cubic phase of zirconium carbide. It was found that the fracture toughness of the composite with 10 wt. % MWCNTs increases from 4.0 to 5.7 MPa·m1/2.


This work is devoted to the study of the effect of carbon nanotubes functionalization on the electrical conductivity of composite materials based on them. Carbon nanotubes were functionalized by treatment in nitric acid and isopropyl alcohol. Changes in the morphology of multi-walled carbon nanotubes during liquid-phase functionalization were investigated using Auger-electron microscopy. Samples of composite material on the basis of initial and functionalized carbon nanotubes and epoxy resin were prepared and the concentration dependence of electrical conductivity using the four-probe method was studied. The study reveals the effect of functionalization in various solutions on the electrophysical properties of the obtained carbon nanotubes/epoxy composites.


2010 ◽  
Vol 447-448 ◽  
pp. 634-638 ◽  
Author(s):  
Henry Kuo Feng Cheng ◽  
Nanda Gopal Sahoo ◽  
Lin Li ◽  
Siew Hwa Chan ◽  
Jian Hong Zhao

Multi-walled carbon nanotubes (MWCNTs) were functionalized with a carboxyl group (-COOH) to improve their dispersion in a nylon6 (PA6) matrix, a liquid crystal polymer (LCP) and their blend. This functionalized MWCNTs also achieved better interfacial adhesions with both polymer matrices and with both phases in the blend. The dispersion of MWCNT-COOH in the polymer matrices and their interfacial interactions with polymer molecules were found to be the most important factors affecting the properties of composites. Moreover, studies on morphological, rheological, and mechanical properties confirmed that a better miscibility between PA6 and LCP had been constituted in the presence of MWCNT-COOH. Therefore, it is observed that the functionalized MWCNTs not only played the traditional role as reinforcing fillers in the polymer matrices, but also performed a novel role as compatibilizers for their blend.


2012 ◽  
Vol 556 (1) ◽  
pp. 158-167
Author(s):  
V. Kažukauskas ◽  
V. Kalendra ◽  
N. Vainorius ◽  
C. W. Bumby ◽  
B. M. Ludbrook ◽  
...  

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