Syntheses and Structure Study on 3,3aλ4,4-Trithia-1-azapentalenes and Their 3-Oxa Analogues
2003 ◽
Vol 68
(7)
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pp. 1243-1263
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Keyword(s):
X Ray
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Reactions of nitrile, amide or ester of 5-amino-3-thioxo-3H-1,2-dithiole-4-carboxylic acid 1 with alkylation and acylation agents were studied. "Ionic" 1,2-dithiole amides 6 were formed in several ways. Treatment with phosphorus pentasulfide afforded the corresponding 3,3aλ4,4-trithia-1-azapentalenes 7. Structures of the synthesized heterocycles were studied using a combination of X-ray analysis, IR spectroscopy, and HF and DFT quantum-chemical calculations.
2002 ◽
pp. 3342
◽
2017 ◽
Vol 11
(1)
◽
pp. 37-48
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Keyword(s):
2008 ◽
Vol 112
(38)
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pp. 9075-9082
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Keyword(s):