Pd/APN-Mn(BTC) as novel, highly efficient, and recyclable catalyst for Suzuki–Miyaura cross coupling reaction

2020 ◽  
Vol 98 (8) ◽  
pp. 445-452
Author(s):  
Hamid Aliyan ◽  
Razieh Fazaeli
Keyword(s):  
Palladium Nanoparticles ◽  
Metal Organic Framework ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Analytical Techniques ◽  
Mild Conditions ◽  
Cross Coupling Reaction ◽  
Highly Dispersed ◽  
Metal Organic ◽  
Adsorption Desorption

A novel, heterogeneous, and bifunctional metal organic framework containing palladium and manganese, Pd/APN-Mn(BTC), has been prepared and completely characterized using FTIR, XRD, SEM-EDS, N2 adsorption–desorption, TG-DTG, NH3-TPD, and ICP analytical techniques. The APN-Mn(BTC) framework has been shown to be a useful platform for the stabilization and support of palladium nanoparticles (Pd NPs). Very effective catalytic activity has been exhibited by the highly dispersed Pd particles, Pd-NPs/APN-Mn(BTC), in the Suzuki–Miyaura cross-coupling reaction with reasonable to excellent reaction yields under mild conditions in H2O–ethanol solvent.

A robust, catalytic metal–organic framework with open 2,2′-bipyridine sites

2014 ◽  
Vol 50 (37) ◽  
pp. 4810-4812 ◽  
Author(s):  
Honghan Fei ◽  
Seth M. Cohen
Keyword(s):  
Metal Organic Framework ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Cross Coupling Reaction ◽  
Metal Organic ◽  
Catalytic Metal ◽  
Organic Framework

A highly crystalline Zr(iv)-based metal–organic framework (MOF) containing open 2,2′-bipyridine (bpy) chelating sites has been realized using two synthetic strategies, and readily forms complexes with PdCl2 to produce a MOF that exhibits efficient and recyclable catalysis for the Suzuki–Miyaura cross-coupling reaction.

Copper-catalyzed oxidative coupling of arylboronic acids with aryl carboxylic acids: Cu3(BTC)2 MOF as a sustainable catalyst to access aryl esters

2018 ◽  
Vol 5 (15) ◽  
pp. 2322-2331 ◽  
Author(s):  
Nainamalai Devarajan ◽  
Palaniswamy Suresh
Keyword(s):  
Carboxylic Acids ◽  
Oxidative Coupling ◽  
Metal Organic Framework ◽  
Coupling Reaction ◽  
Cross Coupling ◽  
Arylboronic Acids ◽  
Cross Coupling Reaction ◽  
Metal Organic ◽  
Commercially Important ◽  
Organic Framework

A straightforward and sustainable methodology for the synthesis of commercially important aryl esters via a C–O cross-coupling reaction was demonstrated using the Cu3(BTC)2 metal–organic framework.

Sign in / Sign up

Export Citation Format

Share Document