Distributions and Fate of Volatile Organic Compounds in Narragansett Bay, Rhode Island

1983 ◽  
Vol 40 (S2) ◽  
pp. s304-s321 ◽  
Author(s):  
S. G. Wakeham ◽  
J. T. Goodwin ◽  
A. C. Davis

A wide range of volatile organic compounds (VOC) were measured in the water column along a north–south transect in Narragansett Bay, Rhode Island, during two summers and two winters. The dominant VOC are chlorinated C2-hydrocarbons, chlorobenzenes, and aromatic hydrocarbons. Major sources for these anthropogenic compounds are municipal and industrial wastewaters discharged into the upper bay. Concentration trends along the transect are variable depending on the compound class and the season of sampling, indicating that different processes control the distributions of different compounds. Volatilization apparently is a major removal process for all VOC. Calculations suggest water column residence times with respect to volatilization of 150–300 h in Narragansett Bay. Biodegradation, particularly in summer, is important for aromatic hydrocarbons, which are degraded in a few days. Sorption onto particulate matter and eventual sedimentation is minor, except for the higher molecular weight alkanes.

2013 ◽  
Vol 13 (12) ◽  
pp. 32649-32701 ◽  
Author(s):  
M. Li ◽  
Q. Zhang ◽  
D. G. Streets ◽  
K. B. He ◽  
Y. F. Cheng ◽  
...  

Abstract. An accurate speciation mapping of non-methane volatile organic compounds (NMVOC) emissions has an important impact on the performance of chemical transport models (CTMs) in simulating ozone mixing ratios and secondary organic aerosols. In this work, we developed an improved speciation framework to generate model-ready anthropogenic Asian NMVOC emissions for various gas-phase chemical mechanisms commonly used in CTMs by using an explicit assignment approach and updated NMVOC profiles, based on the total NMVOC emissions in the INTEX-B Asian inventory for the year 2006. NMVOC profiles were selected and aggregated from a wide range of new measurements and the SPECIATE database. To reduce potential uncertainty from individual measurements, composite profiles were developed by grouping and averaging source profiles from the same category. The fractions of oxygenated volatile organic compounds (OVOC) were corrected during the compositing process for those profiles which used improper sampling and analyzing methods. Emissions of individual species were then lumped into species in different chemical mechanisms used in CTMs by applying mechanism-dependent species mapping tables, which overcomes the weakness of inaccurate mapping in previous studies. Gridded emissions for eight chemical mechanisms are developed at 30 min × 30 min resolution using various spatial proxies and are provided through the website: http://mic.greenresource.cn/intex-b2006. Emission estimates for individual NMVOC species differ between one and three orders of magnitude for some species when different sets of profiles are used, indicating that source profile is the most important source of uncertainties of individual species emissions. However, those differences are diminished in lumped species as a result of the lumping in the chemical mechanisms.


2021 ◽  
Author(s):  
Johan Mattsson ◽  
Lennart Larsson

An emissions barrier was used in premises with indoor air complaints due to emissions from the buildings in question. The emissions comprised chlorophenols/chloroanisoles and polycyclic aromatic hydrocarbons (PAH) from treated wood, and volatile organic compounds (VOC), mainly 2-ethylhexanol, from PVC flooring and the glue used to paste the flooring onto a concrete slab. Attaching the barrier at the surfaces from where the emissions were spread (floor, walls, ceiling) resulted in a fresh and odour-free indoor air. We conclude that using an emissions barrier in buildings made unhealthy by moisture is an efficient way of restoring a pleasant and healthy indoor air.


2019 ◽  
Vol 26 (6) ◽  
pp. 1731-1741 ◽  
Author(s):  
Mohamad M. Ayad ◽  
Nagy L. Torad ◽  
Islam M. Minisy ◽  
Raja Izriq ◽  
El-Zeiny M. Ebeid

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