ISOTOPE SHIFT OF THE NITROGEN ABSORPTION BANDS IN THE VACUUM ULTRAVIOLET REGION

1964 ◽  
Vol 42 (9) ◽  
pp. 1716-1729 ◽  
Author(s):  
M. Ogawa ◽  
Y. Tanaka ◽  
A. S. Jursa
Keyword(s):  
Isotope Shift ◽  
Vacuum Ultraviolet ◽  
Electronic States ◽  
Normal Incidence ◽  
Ultraviolet Region ◽  
Nitrogen Absorption ◽  
Absorption Bands ◽  
Quantum Numbers ◽  
Vibrational Levels ◽  
Vacuum Ultraviolet Region

The vibrational isotope shift of the nitrogen absorption bands has been studied in the 830–1000 Å region. A 3-meter normal-incidence vacuum spectrograph was used with the helium continuum as background.According to our analysis, the vibrational quantum numbers assigned to the lowest observed vibrational levels for the various electronic states of N214 are as follows: [Formula: see text], 100 824 cm−1, ν = 0; (b 1Πu), 101 455 cm−1, ν = 1; (l 1Πu), 104 146 cm−1, ν = 5; [Formula: see text], 104 366 cm−1, ν = 0; (m 1Πu), 105 350 cm−1, ν = 5 ~ 7; (o 1Πu), 105 703 cm−1, ν = 0; [Formula: see text], 106 649 cm−1, ν = 4; (p 1Πu), 108 373 cm−1, ν = 9 ~ 10; [Formula: see text], 109 833 cm−1, ν = 11 ~ 12; [Formula: see text] 110 944 cm−1, ν = 10; (s ?), 116 688 cm−1, ν > 20; and (t ?), 118 486 cm−1,[Formula: see text]. The observed isotope shift for the bands [Formula: see text], 106 381 cm−1; [Formula: see text], 108 549 cm−1; (f ?), 110 196 cm−1; [Formula: see text] 110 664 cm−1; [Formula: see text], 112 777 cm−1; (h′ ?), 114 841 cm−1; (h″ ?), 116 820 cm−1; and [Formula: see text], 118 778 cm−1 increases in this order and shows that none of these bands corresponds to a (0, 0) band.

Rotational analysis of the forbidden d3 Δi ← X1Σ+ absorption bands of carbon monoxide

1970 ◽  
Vol 48 (24) ◽  
pp. 3004-3015 ◽  
Author(s):  
G. Herzberg ◽  
T. J. Hugo ◽  
S. G. Tilford ◽  
J. D. Simmons
Keyword(s):  
Carbon Monoxide ◽  
High Resolution ◽  
Intensity Distribution ◽  
Vacuum Ultraviolet ◽  
Ultraviolet Region ◽  
Rotational Analysis ◽  
Absorption Bands ◽  
Local Perturbations ◽  
Vacuum Ultraviolet Region ◽  
Π State

The forbidden d3Δi–X1Σ+ transition of CO has been observed in absorption at high resolution in the vacuum ultraviolet region. The intensity distribution in the rotational structure of the observed bands is in conformity with the assumption that the transition occurs on account of the interaction between the d3Δ state and a 1Π state, presumably the A1Π state. Thirteen bands of the d–X system have been analyzed yielding more extensive rotational data for the d3Δi state than were previously known. A discussion of the local perturbations in the d state by the A1Π and a3Π states is included.

The electronic spectra of HCl and HF

1979 ◽  
Vol 57 (10) ◽  
pp. 1650-1661 ◽  
Author(s):  
A. E. Douglas ◽  
F. R. Greening
Keyword(s):  
Absorption Spectra ◽  
Electronic Spectra ◽  
Vacuum Ultraviolet ◽  
Rydberg States ◽  
Spectral Lines ◽  
High Dispersion ◽  
Ultraviolet Region ◽  
Vibrational Levels ◽  
Vacuum Ultraviolet Region ◽  
Ionization Limit

The absorption spectra of HCl and HF have been photographed at high dispersion in the vacuum ultraviolet region. In the HCl spectrum, many new band systems have been identified and 18 vibrational levels of the ionic B1Σ state have been observed. The B1Σ state is found to interact strongly with the Rydberg states. Although many bands have been analysed, much of the HCl spectrum remains unassigned. Analyses of bands associated with the lowest discrete 1Π and 3Π states of HF are presented together with the analyses of two 1Π–X1Σ band systems which lie between the first and second ionization limit. The spectrum of HF is very complex and little of it has been analysed even though the spectral lines are sharp and well resolved. The theoretical problems in understanding the spectra of HCl and HF are discussed.

THE FORBIDDEN I1Σ−–X1Σ+ ABSORPTION BANDS OF CARBON MONOXIDE

1966 ◽  
Vol 44 (12) ◽  
pp. 3039-3045 ◽  
Author(s):  
G. Herzberg ◽  
J. D. Simmons ◽  
A. M. Bass ◽  
S. G. Tilford
Keyword(s):  
Carbon Monoxide ◽  
Selection Rule ◽  
Vacuum Ultraviolet ◽  
Ultraviolet Region ◽  
Absorption Bands ◽  
Coriolis Interaction ◽  
Dipole Radiation ◽  
Vacuum Ultraviolet Region ◽  
Vibrational Constants ◽  
Π State

The forbidden I1Σ−–X1Σ+ transition of CO has been observed in absorption at high resolution in the vacuum ultraviolet region. As expected for a 1Σ−–1Σ+ transition, the bands consist of single Q branches, in which the lines of lowest J are either missing or very weak. Although the selection rule prohibiting Σ−–Σ+ transitions is rigorous for dipole radiation at zero rotation, the I1Σ−–X1Σ+ transition can occur for higher rotational levels because of Coriolis interaction with the A1Π state, which lies very close to the I1Σ− state.Eight bands of the I–X system have been analyzed and from them the rotational and vibrational constants of the I1Σ− state have been determined. Previous information on this state was based entirely on the study of perturbations in the A1Π state. The corresponding perturbations in the I1Σ− state have now been observed. In addition, small "vibrational" perturbations in the ν = 4 and 5 levels (probably caused by interactions with the a3Π state) are found.

Luminescence Properties of Nd 3+ ‐Doped AlF 3 ‐Based Fluoride Glass in the Vacuum Ultraviolet Region

2020 ◽  
Vol 257 (8) ◽  
pp. 1900475
Author(s):  
Kohei Yamanoi ◽  
Yuki Minami ◽  
Toshihiko Shimizu ◽  
Nobuhiko Sarukura ◽  
Takahiro Murata ◽  
...  
Keyword(s):  
Vacuum Ultraviolet ◽  
Fluoride Glass ◽  
Luminescence Properties ◽  
Ultraviolet Region ◽  
Vacuum Ultraviolet Region

Anisotropic Optical Spectra of YAlO3(YAP) Single Crystals in the Vacuum Ultraviolet Region. III. Spectra of Optical Constants

1994 ◽  
Vol 63 (6) ◽  
pp. 2269-2289 ◽  
Author(s):  
Tetsuhiko Tomiki ◽  
Yoshiiku Ganaha ◽  
Tomoyoshi Futemma ◽  
Tohru Shikenbaru ◽  
Hiroo Kato ◽  
...  
Keyword(s):  
Single Crystals ◽  
Optical Constants ◽  
Vacuum Ultraviolet ◽  
Optical Spectra ◽  
Ultraviolet Region ◽  
Vacuum Ultraviolet Region
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