Crystallographic and spectroscopic studies of adducts of indium (III) iodide with two cyclic ketones
Keyword(s):
Indium(III) iodide forms a 1:1 adduct with 9-xanthenone, of quasi-tetrahedral structure; triclinic, a = 10.805(4), b = 11.494(4), c = 7.493 (2) Å, α = 104.12(3), β = 106.35(3), γ = 91.165(3)°, V = 860.8(5) Å3, Z = 2, space group P1-. With 9-fluorenone, the adduct has 1:2 stoichiometry, and approximately D3h symmetry in the InI3O2 kernel; the structure is triclinic, a =11.212(2), b = 16.504(3), c = 7.537(2) Å, α = 94.57(2), β = 109.05(1), γ = 91.165(15)°, V = 1312.6(4) Å3, Z = 2, space group P1-. The solid structures, and the solution chemistry, are compared with those of related neutral derivatives of indium(III) halides.Key words: Indium(III) iodide, solution chemistry, crystal structures, adducts.
2009 ◽
Vol 2009
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pp. 5227-5232
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2012 ◽
Vol 68
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pp. o408-o412
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2012 ◽
Vol 68
(11)
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pp. o459-o464
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2013 ◽
Vol 640
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pp. 357-362
2010 ◽
Vol 636
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pp. 1183-1189
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2006 ◽
Vol 61
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pp. 979-982
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