Synthesis and vibrational spectra of some lead(II) halide adducts with O-, S-, and N-donor atom ligands

1976 ◽  
Vol 54 (21) ◽  
pp. 3430-3438 ◽  
Author(s):  
Ivor Wharf ◽  
Thor Gramstad ◽  
Ramesh Makhija ◽  
Mario Onyszchuk
Keyword(s):  
Raman Spectra ◽  
Vibrational Spectra ◽  
Vibrational Frequencies ◽  
Infrared And Raman Spectra ◽  
Donor Atom ◽  
Bidentate Ligands ◽  
Experimental Conditions ◽  
Monodentate Ligands

Lead(II) halides (PbX2 where X = Cl, Br, and I) formed five types of adducts with monodentate (L) and bidentate (LL) ligands: PbX2•L, PbX2•2L, 2PbX2•L, PbX2•LL, and PbX2•2LL, but not all halides and ligands produced each type. Monodentate ligands were dimethylsulphoxide, N,N-dimethylacetamide, N,N-dimethylthioacetamide, thioacetamide, 2,6-dimethyl-γ-pyrone, N-methyl-2-pyridone, N-methyl-2-pyrollidinone, thiourea, pyridine, piperidine, and aniline, while bidentate ligands were ethylenediamine, tetramethylethylenediamine, 1,10-phenanthroline, and 2,2′-bipyridine. Infrared and Raman spectra are reported together with ligand vibrational frequencies shifted by coordination. Under similar experimental conditions qualitative trends in acceptor and donor abilities appeared to be PbI2 > PbBr2 > PbCl2 and S-donors > O-donors, respectively.

Vibrational Spectra of the Hexacarbonyl Manganese(I) Cation

1974 ◽  
Vol 52 (2) ◽  
pp. 213-215 ◽  
Author(s):  
R. A. N. McLean
Keyword(s):  
Force Constant ◽  
Raman Spectra ◽  
Vibrational Spectra ◽  
Vibrational Frequencies ◽  
Force Constants ◽  
Infrared And Raman Spectra

The infrared and Raman spectra of the hexacarbonylmanganese cation as Mn(CO)6+ PF6− were assigned by comparison with other hexacarbonyl species. The CO stretching force constants for Mn(CO)6+ and Re(CO)6+ as indicated by the CO stretching vibrational frequencies are not significantly different. However, the Mn—C force constant in Mn(CO)6+ is likely to be considerably less than the Cr—C force constant in Cr(CO)6, whereas Re(CO)6+ and W(CO)6 have similar values. It is postulated that, although Mn(CO)6+ has equal metal–carbon σ bonding to Re(CO)6+, the metal-carbon σ bonding is less for Mn(CO)6+.

Schwingungsspektren von Ag3PS4 und Cu3PS4 / Vibrational Spectra of Ag3PS4 and Cu3PS4

1983 ◽  
Vol 38 (1) ◽  
pp. 27-30 ◽  
Keyword(s):  
Crystal Field ◽  
Raman Spectra ◽  
Vibrational Spectra ◽  
Far Infrared ◽  
Infrared Region ◽  
Vibrational Frequencies ◽  
Infrared And Raman Spectra

Abstract The infrared and Raman spectra of silver thiophosphate Ag3PS4 have been recorded. The observed frequencies are assigned on the basis of tetrahedral units by considering a splitting of the F2 modes by the crystal field. The vibrational frequencies of copper thiophosphate Cu3PS4 are completed for the far infrared region. For both title compounds DTA-data have been determined and interpreted.

Synthesis and vibrational spectra of lead(II) thiocyanate complexes

1976 ◽  
Vol 54 (8) ◽  
pp. 1189-1196 ◽  
Author(s):  
Anthony D. Baranyi ◽  
Ramesh Makhija ◽  
Mario Onyszchuk
Keyword(s):  
Raman Spectra ◽  
Vibrational Spectra ◽  
Infrared And Raman Spectra ◽  
Bidentate Ligands ◽  
Thiocyanate Complexes ◽  
Vibrational Bands ◽  
Thiocyanate Group

The preparation, properties, and vibrational spectra are reported for the following complexes of lead(II) thiocyanate with mono- and bidentate ligands: Pb(NCS)2•2py, Pb(NCS)2•phen, Pb(NCS)2•2phen, Pb(NCS)2•tmen, Pb(NCS)2•en, Pb(NCS)2•2en, Pb(NCS)2•2dmso, and Pb(NCS)2•2dma. Assignments are made for the ν(CN), ν(CS), and δ(NCS) vibrational bands of the thiocyanate group and the results are discussed in terms of the type of coordination of NCS with lead(II). Values are consistent with bridge-bonded and/or N-bonded thiocyanate. Infrared and Raman spectra of the complexes Pb(NCS)2•bipy and Pb(NCS)2•4tu are reexamined and new assignments are made which support bridge-bonded and/or N-bonded NCS contrary to previous reports of S-bonded NCS.

The vibrational spectra of ClF2SbF6, BrF2SbF6, and ClO2SbF6

1970 ◽  
Vol 48 (21) ◽  
pp. 3456-3459 ◽  
Author(s):  
H. A. Carter ◽  
F. Aubke
Keyword(s):  
Strong Coupling ◽  
Raman Spectra ◽  
Vibrational Spectra ◽  
Vibrational Frequencies ◽  
Vibrational Modes ◽  
Infrared And Raman Spectra

Infrared and Raman spectra of ClF2SbF6, BrF2SbF6, and ClO2SbF6 are reported. Vibrational frequencies for the BrF2+ cation are assigned. In all compounds various degrees of anion–cation interaction are found. The symmetry of the anion is reduced but no internal similarity between the three spectra is recognizable. In addition, strong coupling of vibrational modes for BrF2SbF6 is observed.

scholarly journals Analytic calculations of anharmonic infrared and Raman vibrational spectra

2016 ◽  
Vol 18 (5) ◽  
pp. 4201-4215 ◽  
Author(s):  
Yann Cornaton ◽  
Magnus Ringholm ◽  
Orian Louant ◽  
Kenneth Ruud
Keyword(s):  
Raman Spectra ◽  
Vibrational Spectra ◽  
Vibrational Frequencies ◽  
High Order ◽  
Molecular Properties ◽  
Infrared And Raman Spectra ◽  
Recursive Scheme ◽  
Raman Intensities ◽  
Derivatives Of ◽  
Ir And Raman

Using a recent recursive scheme for the calculation of high-order geometric derivatives of molecular properties, we present the first analytic calculations of infrared and Raman spectra including anharmonicity both in the vibrational frequencies and in the IR and Raman intensities.

Vibrational spectra of aquadioxotetra; peroxodivanadates(V) M2[V2O2(O2)4(H2O)]·xH2O (M = N(CH3)4, Cs)

1990 ◽  
Vol 55 (6) ◽  
pp. 1485-1490 ◽  
Author(s):  
Peter Schwendt ◽  
Milan Sýkora
Keyword(s):  
Raman Spectra ◽  
Vibrational Spectra ◽  
Normal Coordinate Analysis ◽  
Force Constants ◽  
Infrared And Raman Spectra ◽  
Empirical Correlations ◽  
Normal Coordinate ◽  
Bond Lengths ◽  
Stretching Vibrations

The infrared and Raman spectra of M2[V2O2(O2)4(H2O)]·xH2O and M2[V2O2(O2)4(D2O)]·xD2O (M = N(CH3)4, Cs) were measured. In the region of the vanadium-oxygen stretching vibrations, the spectra were interpreted based on normal coordinate analysis, employing empirical correlations between the bond lengths and force constants.

Synthesis, crystal and molecular structure, and vibrational spectra of the complex (COOH)2•2H2O•18-crown-6

1986 ◽  
Vol 64 (1) ◽  
pp. 142-147 ◽  
Author(s):  
Suzanne Deguire ◽  
François Brisse ◽  
Jacques Ouellet ◽  
Rodrigue Savoie
Keyword(s):  
Molecular Structure ◽  
Hydrogen Bonds ◽  
Oxalic Acid ◽  
Raman Spectra ◽  
Vibrational Spectra ◽  
Crystal And Molecular Structure ◽  
Unit Cell ◽  
Infrared And Raman Spectra ◽  
O 18 ◽  
Stoichiometric Complex

A stoichiometric complex of formula (COOH)2•2H2O•18-crown-6 has been obtained from oxalic acid and the macrocyclic polyether 18-crown-6. The crystals of the complex have a monoclinic unit cell and belong to the P21/c space group. The components in the adduct are linked through hydrogen bonds in a polymer-like fashion: -crown–H2O–HOOCCOOH–OH2–crown–, where the oxalic acid molecules are present in two distinct disordered orientations. The infrared and Raman spectra of the complex are also reported and interpreted.

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