Methods for the comparison of fulvic acid samples: the effects of origin and concentration on acidic properties

1978 ◽  
Vol 56 (9) ◽  
pp. 1196-1201 ◽  
Author(s):  
R. Douglas Burch ◽  
Cooper H. Langford ◽  
Donald S. Gamble

The principles according to which the acidic properties of fulvic acid solutions should be compared are demonstrated. An equilibrium function defined and measured for any mixture, including fulvic acid functional groups, will be a weighted average. A concentration change will generally affect this average by changing the relative values of the statistical weights. Concentration corrections are therefore required for the comparison of two fulvic acid solutions. A Chernozem Ah fulvic acid and the previously described Armadale fulvic acid Batch FA1 were examined in this way. They were found to have the same general chemical characteristics, but with somewhat different numerical values. The implications of these results for the definition of fulvic acid are considered.

1985 ◽  
Vol 65 (3) ◽  
pp. 435-443 ◽  
Author(s):  
DONALD S. GAMBLE ◽  
SHAHAMAT U. KHAN

The catalysis of atrazine hydrolysis at 25.0 °C by the types of acidic functional groups found in humic materials has been investigated. No evidence of catalysis by carboxylate ions was observed. From a knowledge of the types and numbers of acid functional groups in a quantitatively characterized fulvic acid, and the distributions of their KA values it was found that hydrogen ions and undissociated carboxyl groups were the only catalytic agents. The carboxyl groups have a second-order kAH of 7.88 days −1∙M−1. Weakly acidic functional groups having [Formula: see text]showed no catalysis. A predictive equation has been produced for the half-life of atrazine in fulvic acid solutions at 25.0 °C. It represents a general class of equations which should permit the practical prediction of atrazine persistence in soil solutions and other natural waters. Key words: Atrazine hydrolysis, atrazine persistence, fulvic acid, fulvic acid carboxyls, acid catalysis, carboxyl catalysis


The Analyst ◽  
1993 ◽  
Vol 118 (1) ◽  
pp. 71 ◽  
Author(s):  
Yuefeng Xie ◽  
David A. Reckhow
Keyword(s):  

1992 ◽  
Vol 260 ◽  
Author(s):  
ZS. J. Horváth

ABSTRACTThe change of the doping concentration (including type) near the metal-semiconductor interface influences the Schottky barrier height (BH). In many cases this phenomenon is apparently spontaneous, or it is a side effect of the technology. The goal of this paper is to summarize the effect of the near-interface concentration change on the apparent and real Schottky BHs, and to demonstrate its importance with experimental results obtained in GaAs Schottky contacts. The question of the definition of the real BH for some of these structures is also treated.


2017 ◽  
Vol 5 (1) ◽  
pp. SB57-SB67 ◽  
Author(s):  
Nattavadee Srisutthiyakorn ◽  
Gerald M. Mavko

Hydraulic tortuosity is an important parameter in characterizing fluid-flow heterogeneity in porous media. The most basic definition of tortuosity is the ratio of the average flow path length to the sample length. Although this definition seems straightforward, the lack of understanding and the lack of proper ways to measure tortuosity make it one of the most abused parameters in rock physics. Hydraulic tortuosity is often treated merely as a fitting factor, or worse, it is neglected by being combined with a geometric factor in the Kozeny-Carman (KC) equation. Often, the tortuosity is obtained from laboratory measurements of porosity, permeability, and specific surface area by inverting the KC equation. This approach has a major pitfall because it treats tortuosity as a fitting factor, and the inverted tortuosity is often unphysically high. In contrast, we obtained the tortuosity from 3D segmented binary images of porous media using streamlines extracted from a local flux, the output from the lattice Boltzmann method (LBM) flow simulation. After obtaining streamlines from each sample, we calculated the distribution of tortuosities and flux-weighted average tortuosity. With the tortuosity measurement from streamlines, every parameter in the KC equation can be measured accurately from 3D segmented binary images. We found, however, that the KC equation is still missing some important geometric information needed to predict permeability. With known parameters and without a fitting factor, the KC equation predicts permeability higher by one to two orders of magnitude than that predicted by the LBM. We searched for a missing parameter by exploring various concepts such as connected pore space and pore throat distribution. We found that the connected pore space does not contribute to the difference between the KC permeability and LBM permeability, whereas, as we learn with sinusoidal pipe examples, the pore throat distribution captures what is missing from the KC equation.


Talanta ◽  
2004 ◽  
Vol 62 (1) ◽  
pp. 103-108 ◽  
Author(s):  
Jeremy Riggle ◽  
Ray von Wandruszka

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