Hydrogen–deuterium exchange in tetrahydroborate salts
Keyword(s):
H Nmr
◽
1H nmr spectroscopy has been used to demonstrate hydrogen–deuterium exchange in solutions of NaBH4/NaB2H4 in diglyme and KBH4/KB2H4 in 18-crown-6 ether/chloroform. Earlier observations of such exchange with LiBH4/LiB2H4 in an ethereal solvent were confirmed. Spectra were simplified by broadband decoupling of deuterium, facilitating quantitative measurement of the degree of exchange.
Keyword(s):
2011 ◽
Vol 41
(1)
◽
pp. 41-51
◽
Keyword(s):
Keyword(s):
1979 ◽
Vol 83
(23)
◽
pp. 3020-3023
◽
2018 ◽
Vol 122
(8)
◽
pp. 2368-2378
◽
Quantification of protein backbone hydrogen-deuterium exchange rates by solid state NMR spectroscopy
2010 ◽
Vol 48
(4)
◽
pp. 203-212
◽
1995 ◽
Vol 247
(4)
◽
pp. 682-688
◽