A preliminary treatment of solute and solvent interactions in the diffuse part of the electric double layer
1981 ◽
Vol 59
(13)
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pp. 1854-1859
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Keyword(s):
The Mean
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The electrolyte in the diffuse layer is modelled by a system of charged hard spheres and dipolar hard spheres. Poisson's equation and integral equations for the mean electrostatic potential are derived and the implications worked out for a mean field approximation.