FIRST ORDER PHASE TRANSITIONS, WHEN AND FROM WHERE DO THEY EMERGE? —THE CASE OF GELS

1995 ◽  
Vol 09 (07) ◽  
pp. 737-749 ◽  
Author(s):  
KEN SEKIMOTO

We briefly review the recent theoretical understanding of the first order phase transition undergone by gels with an emphasis on physical concepts, deliberately excluding details of modeling and analytic methods. The density of a gel changes discontinuously at the transition point. A variety of features of the transition result from the basic fact that the inhomogeneity of the density of the gel inevitably causes shear deformation. This deformation, on the one hand, reflects the geometry of the sample and, on the other hand, may alter the transition temperature.

RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37476-37484 ◽  
Author(s):  
Hong-Hui Wu ◽  
Jiaming Zhu ◽  
Tong-Yi Zhang

The proposed Pseudo-First-Order Phase Transition in a ferroelectric nanoparticle occurs at a temperature lower than its paraelectric/ferroelectric transition Curie temperature and is associated with an ultrahigh electrocaloric effect.


2012 ◽  
Vol 27 (21) ◽  
pp. 1250116 ◽  
Author(s):  
M. BORDAG ◽  
V. DEMCHIK ◽  
A. GULOV ◽  
V. SKALOZUB

The temperature induced phase transition is investigated in the one-component scalar field ϕ4 model on the lattice. Using the GPU cluster a huge amount of Monte Carlo simulation data is collected for a wide interval of coupling values. This gives a possibility to determine the low bound on the coupling constant λ0 when the transition happens and investigate its type. We found that for the values of λ close to this bound a weak-first-order phase transition takes place. It converts into a second-order one with the increase of λ. A comparison with the results obtained in analytic and numeric calculations by other authors is given.


2016 ◽  
Vol 94 (1) ◽  
Author(s):  
Mizuki Shirogane ◽  
Shinji Ejiri ◽  
Ryo Iwami ◽  
Kazuyuki Kanaya ◽  
Masakiyo Kitazawa ◽  
...  

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