scholarly journals DOUBLE-VALUEDNESS OF THE ELECTRON WAVEFUNCTION AND ROTATIONAL ZERO-POINT MOTION OF ELECTRONS IN RINGS

2010 ◽  
Vol 24 (21) ◽  
pp. 2201-2214 ◽  
Author(s):  
J. E. HIRSCH

I propose that the phase of an electron's wavefunction changes by π when the electron goes around a loop maintaining phase coherence. Equivalently, that the minimum orbital angular momentum of an electron in a ring is ℏ/2 rather than zero as generally assumed, hence, that the electron in a ring has azimuthal zero point motion. This proposal implies that a spin current exists in the ground state of aromatic ring molecules and suggests an explanation for the ubiquitousness of persistent currents observed in mesoscopic rings.

Science ◽  
2018 ◽  
Vol 362 (6421) ◽  
pp. eaat7319 ◽  
Author(s):  
Philip C. Bunting ◽  
Mihail Atanasov ◽  
Emil Damgaard-Møller ◽  
Mauro Perfetti ◽  
Iris Crassee ◽  
...  

Orbital angular momentum is a prerequisite for magnetic anisotropy, although in transition metal complexes it is typically quenched by the ligand field. By reducing the basicity of the carbon donor atoms in a pair of alkyl ligands, we synthesized a cobalt(II) dialkyl complex, Co(C(SiMe2ONaph)3)2 (where Me is methyl and Naph is a naphthyl group), wherein the ligand field is sufficiently weak that interelectron repulsion and spin-orbit coupling play a dominant role in determining the electronic ground state. Assignment of a non-Aufbau (dx2–y2, dxy)3(dxz, dyz)3(dz2)1 electron configuration is supported by dc magnetic susceptibility data, experimental charge density maps, and ab initio calculations. Variable-field far-infrared spectroscopy and ac magnetic susceptibility measurements further reveal slow magnetic relaxation via a 450–wave number magnetic excited state.


2011 ◽  
Vol 25 (09) ◽  
pp. 1173-1200 ◽  
Author(s):  
J. E. HIRSCH

Is superconductivity associated with a lowering or an increase of the kinetic energy of the charge carriers? Conventional BCS theory predicts that the kinetic energy of carriers increases in the transition from the normal to the superconducting state. However, substantial experimental evidence obtained in recent years indicates that in at least some superconductors the opposite occurs. Motivated in part by these experiments many novel mechanisms of superconductivity have recently been proposed where the transition to superconductivity is associated with a lowering of the kinetic energy of the carriers. However none of these proposed unconventional mechanisms explores the fundamental reason for kinetic energy lowering nor its wider implications. Here I propose that kinetic energy lowering is at the root of the Meissner effect, the most fundamental property of superconductors. The physics can be understood at the level of a single electron atom: kinetic energy lowering and enhanced diamagnetic susceptibility are intimately connected. We propose that this connection extends to superconductors because they are, in a very real sense, "giant atoms". According to the theory of hole superconductivity, superconductors expel negative charge from their interior driven by kinetic energy lowering and in the process expel any magnetic field lines present in their interior. Associated with this we predict the existence of a macroscopic electric field in the interior of superconductors and the existence of macroscopic quantum zero-point motion in the form of a spin current in the ground state of superconductors (spin Meissner effect). In turn, the understanding of the role of kinetic energy lowering in superconductivity suggests a new way to understand the fundamental origin of kinetic energy lowering in quantum mechanics quite generally. This provides a new understanding of "quantum pressure", the stability of matter and the origin of fermion anticommutation relations, it leads to the prediction that spin currents exist in the ground state of aromatic ring molecules, and that the electron wavefunction is double-valued, requiring a reformulation of conventional quantum mechanics.


2016 ◽  
Vol 18 (3) ◽  
pp. 1570-1577 ◽  
Author(s):  
Masahiro Yamaki ◽  
Yoshiaki Teranishi ◽  
Hiroki Nakamura ◽  
Sheng Hsien Lin ◽  
Yuichi Fujimura

Stationary angular momentum, which is a fundamental quantity of high-symmetry aromatic ring molecules, can be created for low-symmetry ring molecules by applying theoretically designed stationary laser fields.


1989 ◽  
Vol 28 (3) ◽  
pp. D655-D661 ◽  
Author(s):  
M. Sinclair ◽  
D. Moses ◽  
D. McBranch ◽  
A.J. Heeger ◽  
J. Yu ◽  
...  

Topologica ◽  
2009 ◽  
Vol 2 (1) ◽  
pp. 002 ◽  
Author(s):  
K. Helmerson ◽  
M. F. Andersen ◽  
P. Cladé ◽  
V. Natarajan ◽  
W. D. Phillips ◽  
...  

2018 ◽  
Vol 27 (08) ◽  
pp. 1850068 ◽  
Author(s):  
Dashty T. Akrawy ◽  
Ali H. Ahmed

A set of empirical formulae have been proposed to calculate the [Formula: see text]-decay half-lives from ground state to ground state transitions of 356 nuclei classified to different set of e–e, e–o, o–e and o–o isotopes. Within these formulae, modification of the previous set of Royer expressions were done by introducing three different physical terms, including the orbital angular momentum and isobaric asymmetry factors. The predicted [Formula: see text]-decay half-lives compared with those adopted by former proposed models for the depended experimental data, and significant improvements were noticed for all the studied sets of isotopes.


2007 ◽  
Vol 790 (1-4) ◽  
pp. 705c-712c ◽  
Author(s):  
K. Helmerson ◽  
M.F. Andersen ◽  
C. Ryu ◽  
P. Cladé ◽  
V. Natarajan ◽  
...  

2021 ◽  
Vol 9 ◽  
Author(s):  
Hirobumi Mineo ◽  
Ngoc-Loan Phan ◽  
Yuichi Fujimura

Herein we review a theoretical study of unidirectional π-electron rotation in aromatic ring molecules, which originates from two quasi-degenerate electronic excited states created coherently by a linearly polarized ultraviolet/visible laser with a properly designed photon polarization direction. Analytical expressions for coherent π-electron angular momentum, ring current and ring current-induced magnetic field are derived in the quantum chemical molecular orbital (MO) theory. The time evolution of the angular momentum and the ring current are expressed using the density matrix method under Markov approximation or by solving the time-dependent Schrödinger equation. In this review we present the results of the following quantum control scenarios after a fundamental theoretical description of coherent angular momentum, ring current and magnetic field: first, two-dimensional coherent π-electron dynamics in a non-planar (P)-2,2’-biphenol molecule; second, localization of the coherent π-electron ring current to a designated benzene ring in polycyclic aromatic hydrocarbons; third, unidirectional π-electron rotations in low-symmetry aromatic ring molecules based on the dynamic Stark shift of two relevant excited states that form a degenerate state using the non-resonant ultraviolet lasers. The magnetic fields induced by the coherent π-electron ring currents are also estimated, and the position dependence of the magnetic fluxes is demonstrated.


2001 ◽  
Vol 114 (2) ◽  
pp. 725 ◽  
Author(s):  
Tony C. Smith ◽  
Haiyang Li ◽  
David A. Hostutler ◽  
Dennis J. Clouthier ◽  
Anthony J. Merer

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