Unified theory for light-induced halide segregation in mixed halide perovskites

Mixed halide perovskites that are thermodynamically stable in the dark demix under illumination. This is problematic for their application in solar cells. We present a unified thermodynamic theory for this light-induced halide segregation that is based on a free energy lowering of photocarriers funnelling to a nucleated phase with different halide composition and lower band gap than the parent phase. We apply the theory to a sequence of mixed iodine-bromine perovskites. The spinodals separating metastable and unstable regions in the composition-temperature phase diagrams only slightly change under illumination, while light-induced binodals separating stable and metastable regions appear signalling the nucleation of a low-band gap iodine-rich phase. We find that the threshold photocarrier density for halide segregation is governed by the band gap difference of the parent and iodine-rich phase. Partial replacement of organic cations by cesium reduces this difference and therefore has a stabilizing effect.

Unified theory for light-induced halide segregation in mixed halide perovskites

Mixed halide perovskites that are thermodynamically stable in the dark demix under illumination. This is problematic for their application in solar cells. We present a unified thermodynamic theory for this light-induced halide segregation that is based on a free energy lowering of photocarriers funnelling to a nucleated phase with different halide composition and lower band gap than the parent phase. We apply the theory to a sequence of mixed iodine-bromine perovskites. The spinodals separating metastable and unstable regions in the composition-temperature phase diagrams only slightly change under illumination, while light-induced binodals separating stable and metastable regions appear signalling the nucleation of a low-band gap iodine-rich phase. We find that the threshold photocarrier density for halide segregation is governed by the band gap difference of the parent and iodine-rich phase. Partial replacement of organic cations by cesium reduces this difference and therefore has a stabilizing effect.

Small Hydro Power Schemes: Technical Aspects

<p>Small hydro systems play a major role in meeting power requirements of remote, isolated, hilly areas in a decentralized manner by tapping water streams, rivulets and canals of small discharge. Small hydroelectric system captures the energy in flowing water and converts it to electricity.</p>Of all the non-conventional renewable energy sources, small hydro stands first as it is more resourceful, reduces system losses, environment friendly, non-consumptive and source is renewable due to their enormous advantages over large hydro and other power plants, lot of small hydro-power plants have come up across the world to meet the ever increasing demand of electrical energy. Lowering the high initial cost of the small hydro-power plants and its popularization is today’s challenges. This paper describes basic techniques design of the small hydro-power development.

Effect of Stacking Fault Energy on the Mechanical Properties of Cold-Rolling Cu and Cu-Al-Zn Alloys

Sacking fault energy (SFE) plays a significant role for metals or alloys to getting high strength and expected ductility simultaneously. Here the effect of SFE variation on mechanical properties has been studied in cold-rolling Cu and Cu-Al-Zn alloys. Tensile testing results show that the strength and ductility of the materials increase simultaneously with decreasing SFE. X-ray diffraction measurements indicate the peak broadening for the crystallite size decreasing and the lattice strain increasing with the stacking fault energy lowering . The relationship between the microstructure and mechanical properties of the materials is briefly discussed in this paper.

KINETIC ENERGY DRIVEN SUPERCONDUCTIVITY, THE ORIGIN OF THE MEISSNER EFFECT, AND THE REDUCTIONIST FRONTIER

Is superconductivity associated with a lowering or an increase of the kinetic energy of the charge carriers? Conventional BCS theory predicts that the kinetic energy of carriers increases in the transition from the normal to the superconducting state. However, substantial experimental evidence obtained in recent years indicates that in at least some superconductors the opposite occurs. Motivated in part by these experiments many novel mechanisms of superconductivity have recently been proposed where the transition to superconductivity is associated with a lowering of the kinetic energy of the carriers. However none of these proposed unconventional mechanisms explores the fundamental reason for kinetic energy lowering nor its wider implications. Here I propose that kinetic energy lowering is at the root of the Meissner effect, the most fundamental property of superconductors. The physics can be understood at the level of a single electron atom: kinetic energy lowering and enhanced diamagnetic susceptibility are intimately connected. We propose that this connection extends to superconductors because they are, in a very real sense, "giant atoms". According to the theory of hole superconductivity, superconductors expel negative charge from their interior driven by kinetic energy lowering and in the process expel any magnetic field lines present in their interior. Associated with this we predict the existence of a macroscopic electric field in the interior of superconductors and the existence of macroscopic quantum zero-point motion in the form of a spin current in the ground state of superconductors (spin Meissner effect). In turn, the understanding of the role of kinetic energy lowering in superconductivity suggests a new way to understand the fundamental origin of kinetic energy lowering in quantum mechanics quite generally. This provides a new understanding of "quantum pressure", the stability of matter and the origin of fermion anticommutation relations, it leads to the prediction that spin currents exist in the ground state of aromatic ring molecules, and that the electron wavefunction is double-valued, requiring a reformulation of conventional quantum mechanics.

RESONANCES FOR A HYDROGENIC SYSTEM OR A HARMONIC OSCILLATOR STRONGLY COUPLED TO A FIELD

We calculate resonances which are formed by a particle in a potential which is either Coulombian or quadratic when the particle is strongly coupled to a massless boson, taking only two energy levels into consideration. From these calculations we derive how the moving away of the particle from its attraction center goes together with the energy lowering of hybrid states that this particle forms with the field. We study the width of these states and we show that stable states may also appear in the coupling.