CLEAN AND OXYGEN-COVERED Cu3Au(110): A SURFACE STRUCTURE INVESTIGATION WITH STM AND NICISS
Cu 3 Au (110) has been investigated by scanning tunneling microscopy (STM) and 180° low energy ion scattering and detection of neutrals (NICISS). Two different terminations would be possible on the basis of a bulk-truncated surface, a gold-rich or a pure copper surface layer. From the NICISS investigation the gold-rich termination has been found. Two surface modifications could be prepared. Rapid cool-down after annealing at 800 K results in a 2×1 LEED superstructure, but careful preparation and prolonged cooling below 600 K gives a LEED 4×1 superstructure. A new pairing row model has been proposed. Upon oxygen exposure at 330 K on the quenched 2×1 surface and subsequent annealing at 800 K, a 2×1 LEED superstructure presents itself with considerably sharper half order reflexes. NICISS data propose a segregation of Cu atoms to the surface layer forming -Cu-O- rows just above the Cu rows in the Au -rich layer. The 2×1 superstructure formed is in part similar to the well-known added row structure at Cu (110)-(2×1)-O. The structure model has been verified by direct imaging of the added rows with STM.