Fluoro-bridged dimanganese(III) porphyrin dimer: effect of intermacrocyclic interactions in modulating metal spin state

2021 ◽  
Author(s):  
Debangsu Sil ◽  
Sayantani Banerjee ◽  
Sudip Kumar Ghosh ◽  
Sankar Prasad Rath
Keyword(s):  
Spin State ◽  
Porphyrin Dimer

Coordination‐Induced Spin‐State Switching of an Aminyl‐Radical‐Bridged Nickel(II) Porphyrin Dimer between Doublet and Sextet States

2019 ◽  
Vol 131 (15) ◽  
pp. 5077-5081 ◽  
Author(s):  
Daiki Shimizu ◽  
Yuki Ide ◽  
Takahisa Ikeue ◽  
Atsuhiro Osuka
Keyword(s):  
Spin State ◽  
State Switching ◽  
Aminyl Radical ◽  
Porphyrin Dimer

scholarly journals Equatorial ligand plane perturbations lead to a spin-state change in an iron(iii) porphyrin dimer

2019 ◽  
Vol 48 (19) ◽  
pp. 6353-6357 ◽  
Author(s):  
Firoz Shah Tuglak Khan ◽  
Syed Jehanger Shah ◽  
Susovan Bhowmik ◽  
Fabián G. Cantú Reinhard ◽  
Mala A. Sainna ◽  
...  
Keyword(s):  
Spin State ◽  
State Change ◽  
Complete Reversal ◽  
Small Change ◽  
Ethane To Ethene ◽  
Equatorial Ligand ◽  
Porphyrin Dimer

A complete reversal of the spin state of iron(iii) is observed upon a small change to the diporphyrin bridge from ethane to ethene by keeping all other factors intact.

Influence of ligand substituent conformation on the spin state of an iron(ii)/di(pyrazol-1-yl)pyridine complex

2021 ◽  
Vol 50 (10) ◽  
pp. 3464-3467
Author(s):  
Rafal Kulmaczewski ◽  
Mark J. Howard ◽  
Malcolm A. Halcrow
Keyword(s):  
Spin State ◽  
Spin Crossover ◽  
Solution Phase ◽  
Pyridine Complex

The temperature of the solution-phase spin-crossover equilibrium in iron(ii) complexes of 4-alkylsulfanyl-2,6-di{pyrazol-1-yl}pyridine (bppSR) complexes depends strongly on the alkylsulfanyl substituent.

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