Preparation and Characterization of Sulfated TiO2/Zeolite Composite Catalysts with Enhanced Photocatalytic Activity

NANO ◽  
2018 ◽  
Vol 13 (10) ◽  
pp. 1850117
Author(s):  
Yuan Zhao ◽  
JingXiu Li ◽  
Ling Wang ◽  
Yanan Hao ◽  
Lin Yang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Calcination Temperature ◽  
Composite Catalysts ◽  
Crystallization Surface ◽  
Composite Photocatalysts ◽  
Sulfated Tio2 ◽  
Loading Amount ◽  
Zeolite Composite

Sulfated TiO2 nanoparticles were successfully immobilized on zeolite through improving hydrolysis-deposition method. Microstructure, crystallization, surface state and surface area of composite catalysts were characterized by SEM, XRD, FTIR spectra, XPS and BET and the photocatalytic activity was evaluated by degradation of methyl orange under UV irradiation. We optimized these factors (SO[Formula: see text] ions, calcination temperature and loading amount of sulfated TiO[Formula: see text] on photocatalytic activity and crystallization of composite photocatalysts. The results indicated that the SO[Formula: see text] ions are successfully immobilized on the surface of TiO2, and sulfated TiO2/zeolite show the highest photocatalytic activity for methyl orange at the [SO[Formula: see text]]/[Ti[Formula: see text]] molar rate of 1:1, calcination temperature of 600[Formula: see text]C for 2[Formula: see text]h, and sulfated TiO2 loading amount of 40%, respectively.

scholarly journals Synthesis and Characterization of Ag@C-TiO2 Nanocomposite for Degradation of Sasirangan Textile Wastewater

2019 ◽  
Vol 22 (6) ◽  
pp. 299-304
Author(s):  
Heny Puspita Dewi ◽  
Joko Santoso ◽  
Nur Firda Trianda ◽  
Rodiansono Rodiansono
Keyword(s):  
Methylene Blue ◽  
Photocatalytic Activity ◽  
Photocatalytic Degradation ◽  
Textile Wastewater ◽  
Band Gap Energy ◽  
Tio2 Photocatalyst ◽  
Composite Photocatalysts ◽  
Xrd Patterns ◽  
Brookite Phase

Carbon-titanium oxide nanocomposite (denoted as @C-TiO2) was successfully synthesized via hydrothermal method at 150°C for 24 h. The C-TiO2 nanocomposite was furtherly modified by adding an Ag metal dopant (denoted as Ag@C-TiO2) to improve and applied to the photocatalytic degradation of Sasirangan textile wastewater. The composite photocatalysts were characterized by XRD and UV–Vis DRS spectroscopies. XRD patterns showed that TiO2 in @C-TiO2 mainly consisted of a brookite phase, as indicated by a series sharp diffraction peak at 2θ = 27.2° (111), 31.5° (121) and 55.9° (241). The calculated band gap energy (Eg) derived from UV-Vis DRS spectra for TiO2, @C-TiO2, and Ag@C-TiO2 were 2.95 eV, 2.54 eV, and 2.74 eV, respectively. Ag@C-TiO2 photocatalyst was found to be active for the photocatalytic degradation of Sasirangan textile wastewater, as indicated by the change of wastewater color from dark to clear. The quantitative photocatalytic activity of Ag@C-TiO2 was evaluated in the degradation of methylene blue, whereas the conversion of methylene blue was 41.3%. The addition of Ag to @C-TiO2 is believed to play an essential role in the enhancement of photocatalytic activity.

scholarly journals Enhanced Photocatalytic Activity for Degradation of Methyl Orange over Silica-Titania

2011 ◽  
Vol 2011 ◽  
pp. 1-9 ◽  
Author(s):  
Yaping Guo ◽  
Shaogui Yang ◽  
Xuefei Zhou ◽  
Chunmian Lin ◽  
Yajun Wang ◽  
...  
Keyword(s):  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Specific Surface ◽  
Surface Area ◽  
Calcination Temperature ◽  
Specific Surface Area ◽  
Photoelectron Spectroscopy ◽  
Anatase Phase ◽  
Solution Treatment ◽  
X Ray

Silica-modified titania (SMT) powders with different atomic ratios of silica to titanium (Rx) were successfully synthesized by a simple ultrasonic irradiation technique. The prepared samples were characterized by X-ray diffraction (XRD), FT-IR spectroscopy, transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and ultraviolet visible spectroscopy. The specific surface area was measured according to BET theory. Results indicate that the addition of silica to titania can suppress the crystalline size growth and the transformation of anatase phase to rutile phase of titania, enlarge specific surface area of the titania particles, and result in a blue shift of absorption edge compared to pure titania. The photocatalytic activity of the SMT samples was evaluated by decolorizing methyl orange aqueous solutions under UV-visible light irradiation. It was found in our study that this activity was affected by silica content, calcination temperature, H2SO4, and oxidants such as KIO4, (NH4)2S2O8and H2O2. The results reveal that the photocatalytic activity of 0.1-SMT catalyst is the best among all samples calcined at550°C for 1 h and it is 1.56 times higher than that of Degussa P-25 titania, which is a widely used commercial TiO2made by Germany Degussa company and has been most widely used in industry as photocatalyst, antiultraviolet product, and thermal stabilizer. The optimal calcination temperature for preparation was550°C. The photocatalytic activity of SMT samples is significantly enhanced by H2SO4solution treatment and oxidants.

Fabrication and characterization of CdS doped TiO2 nanotube composite and its photocatalytic activity for the degradation of methyl orange

2015 ◽  
Vol 72 (8) ◽  
pp. 1341-1347
Author(s):  
Jinwook Chung ◽  
Seu-Run Kim ◽  
Jong-Oh Kim
Keyword(s):  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Uv Light ◽  
Pure Tio2 ◽  
Tio2 Nanotube ◽  
Doped Tio2 ◽  
Photodegradation Efficiency ◽  
Uv Light Irradiation ◽  
Fabrication And Characterization

CdS doped TiO2 nanotube composite was fabricated by chemical bath deposition, and was characterized by the structural, spectral and photoelectrochemical properties. The results of the structural and spectral properties showed that CdS particles were successfully deposited onto the surface of TiO2 nanotube. It is demonstrated that CdS doped TiO2 nanotube composite improved the light harvesting ability. Power conversion efficiency of about 0.32% was observed. This value is about 2.9 times higher than that of pure TiO2 nanotube. The CdS doped TiO2 nanotube composite possesses relatively higher photocatalytic activity and photodegradation efficiency than that of pure TiO2 nanotube under UV light irradiation, and the degradation efficiency of methyl orange was about 42% at UV intensity of 32 W.

Synthesis of Novel g-C3N4/Bi2WO6 Composite with High Visible Light Photocatalytic Activity

2012 ◽  
Vol 557-559 ◽  
pp. 957-960 ◽  
Author(s):  
Lei Ge ◽  
Chang Cun Han ◽  
Jing Liu
Keyword(s):  
Photocatalytic Activity ◽  
Methyl Orange ◽  
Visible Light ◽  
Doping Amount ◽  
Visible Light Photocatalytic Activity ◽  
Composite Photocatalysts ◽  
Degradation Of Methyl Orange ◽  
Visible Light Photocatalytic ◽  
Composite Samples ◽  
Efficient Transfer

The synthesis of g-C3N4/Bi2WO6composite materials with varying the g-C3N4content was reported in this investigation. The composite samples were characterized by various techniques. The photocatalytic activity of the g-C3N4/Bi2WO6products has been investigated by the degradation of methyl orange dye under visible light irradiation. The UV-vis absorption spectra show that the absorption edge of the composite sample shifts to longer wavelengths with increasing the doping amount of g-C3N4. It is revealed that the g-C3N4/Bi2WO6composite photocatalysts exhibit remarkably enhanced photocatalytic performance for the degradation of methyl orange. The high visible light photocatalytic activity of g-C3N4/Bi2WO6can be attributed to the efficient transfer and separation of charge carriers in the interface between g-C3N4and Bi2WO6particles.

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