Petrogenesis of Silicic Rocks from the Phan Si Pan - Tu Le region of the Emeishan Large Igneous Province, Northwestern Vietnam

2021 ◽  
pp. SP518-2020-253
Author(s):  
Thuy Thanh Pham ◽  
J. Gregory Shellnutt ◽  
Tuan-Anh Tran ◽  
Steven W. Denyszyn ◽  
Yoshiyuki Iizuka
Keyword(s):  
Basaltic Magma ◽  
Red River ◽  
Granitic Rocks ◽  
Large Igneous Province ◽  
Weighted Mean ◽  
Emeishan Large Igneous Province ◽  
Icp Ms ◽  
Igneous Province ◽  
Single Grain ◽  
Host Rocks

AbstractThe Permian silicic rocks in the Phan Si Pan (PSP) uplift area and Tu Le (TL) basin of NW Vietnam (collectively the PSP-TL region) are associated with the Emeishan Large Igneous Province (ELIP). The Permian Muong Hum, Phu Sa Phin, and Nam Xe - Tam Duong granites, and Tu Le rhyolites are alkali ferroan A1-type granitic rocks, which likely formed by fractional crystallization of high-Ti basaltic magma that was contaminated by melts derived from the Neoproterozoic host rocks. Zircon U-Pb LA-ICP-MS geochronology yielded weighted-mean 206Pb/238U ages of 246 ± 3 Ma to 259 ± 3 Ma for granites, and 249 ± 3 Ma and 254 ± 2 Ma for rhyolites. This is contrasted with previously-published high precision U-Pb ages, obtained using CA-ID-TIMS method applied on the same zircon grains, which suggest that the calculated LA-ICP-MS U-Pb ages are variably inaccurate by up to 10 Ma, though at the single-grain level dates generally agree within uncertainty. The similarity of rock texture, whole-rock geochemistry, emplacement ages, and fractionation phases between the PSP-TL region and silicic rocks in the Inner Zone ELIP (i.e., Panzhihua, Binchuan) suggests they were spatially proximal before being sinistrally displaced along the Ailao Shan-Red River shear zone.

scholarly journals Simultaneous Quantification of Forsterite Content and Minor–Trace Elements in Olivine by LA–ICP–MS and Geological Applications in Emeishan Large Igneous Province

Minerals ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 634
Author(s):  
Shitou Wu ◽  
Yadong Wu ◽  
Yueheng Yang ◽  
Hao Wang ◽  
Chao Huang ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Inductively Coupled Plasma ◽  
Large Igneous Province ◽  
Emeishan Large Igneous Province ◽  
Inductively Coupled ◽  
Minor Elements ◽  
Icp Ms ◽  
Igneous Province ◽  
Peridotitic Mantle

Olivine forsterite contents [Fo = 100 × Mg/(Mg + Fe) in mol%] and minor–trace element concentrations can aid our understanding of the Earth’s mantle. Traditionally, these data are obtained by electron probe microanalysis for Fo contents and minor elements, and then by laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) for trace elements. In this study, we demonstrate that LA–ICP–MS, with a simplified 100% quantification approach, allows the calculation of Fo contents simultaneously with minor–trace elements. The approach proceeds as follows: (1) calculation of Fo contents from measured Fe/Mg ratios; (2) according to the olivine stoichiometric formula [(Mg, Fe)2SiO4] and known Fo contents, contents of Mg, Fe and Si can be computed, which are used as internal standards for minor–trace element quantification. The Fo content of the MongOLSh 11-2 olivine reference material is 89.55 ± 0.15 (2 s; N = 120), which agrees with the recommended values of 89.53 ± 0.05 (2 s). For minor–trace elements, the results matched well with the recommended values, apart from P and Zn data. This technique was applied to olivine phenocrysts in the Lijiang picrites from the Emeishan large igneous province. The olivine compositions suggest that the Lijiang picrites have a peridotitic mantle source.

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