In this paper, we examine the disappearance of criticality, ignition locus and bifurcation diagrams of temperature against Rayleigh number of a one-dimensional diffusion-convection-reaction model with the assumption of infinite thermal conductivity and zero species diffusivity. The predictions of this model are compared with those of the Semenov model to determine the impact of the species diffusion term. It is shown that for large values of the Rayleigh number (R* ≫ 1), the ignition locus may be expressed in a parametric form
B Ls
=
t
/ln
t
+
t
/(
t
- 1) (1 <
t
≼ 3.4955),
ψ
/
R
* = (
B Ls
)
2
((
t
- 1)/
t
) exp{ -
B Ls
+
B Ls
/
t
} ln
t
, where
B
is the heat of reaction parameter,
ψ
is the Semenov number and
Ls
is a (modified) Lewis number. Criticality is found to disappear at
B Ls
= 4.194. When these results are compared with those of the Semenov model, it is found that neglecting the species diffusion term gives conservative approximations to the ignition locus, and criticality boundary. It is found that the lumped thermal model-I has five different types of bifurcation diagrams of temperature against Rayleigh number (single-valued, isola, inverse
S
, mushroom, inverse
S
+ isola). These diagrams are qualitatively identical to the bifurcation diagrams of temperature against flow rate for the forced convection problem under the assumption of infinite thermal conductivity and zero species diffusivity.
Reaction–diffusion with a time-dependent reaction rate: the single-species diffusion–annihilation process
