Mitigating Membrane Degradation: Investigation of Lifetime and Fluoride Emission Rate from Modified Short-Side-Chain and Long-Side-Chain PFSA Membrane Electrode Assemblies during High Temperature Open Circuit Voltage Hold

2020 ◽  
Vol 18 ◽  
pp. 100568
Author(s):  
Mingqun Yang ◽  
Wen Cui ◽  
Xin Song ◽  
Yong Zhao ◽  
Xin Jing ◽  
...  

Fuel Cells ◽  
2016 ◽  
Vol 16 (5) ◽  
pp. 577-583 ◽  
Author(s):  
M. Rau ◽  
A. Niedergesäß ◽  
C. Cremers ◽  
S. Alfaro ◽  
T. Steenberg ◽  
...  

2020 ◽  
Vol 8 (43) ◽  
pp. 15426-15435
Author(s):  
Haijun Bin ◽  
Indunil Angunawela ◽  
Ruijie Ma ◽  
Asritha Nallapaneni ◽  
Chenhui Zhu ◽  
...  

Introduction of chlorine in the conjugated side chains significantly improves open-circuit voltage and power conversion efficiency, benefiting from a lower HOMO energy level, well-balanced charge transport and superior nanoscale morphology.


MRS Advances ◽  
2019 ◽  
Vol 4 (36) ◽  
pp. 2001-2007
Author(s):  
Enfang He ◽  
Hong Zhang ◽  
Yueyue Gao ◽  
Fengyun Guo ◽  
Shiyong Gao ◽  
...  

ABSTRACT:Two benzodifuran (BDF) polymers, PBDF-C and PBDF-S, with alkyl and alkylthio substituted thiophene side-chains and benzodithiophene-4,8-dione (BDD) as the acceptor were designed and synthesized. Their optical, electrochemical properties and photovoltaic performances were systematically investigated. The polymer solar cells (PSCs) with a device structure of ITO/PEDOT:PSS/polymer:PC71BM/Ca/Al were fabricated. The PBDF-C based device showed a power conversion efficiency (PCE) of 3.01% after adding 1 vol% 1,8-diodooctane (DIO) as the solvent additive, and PBDF-S gave an enhanced PCE of 3.48% without any post-treatments. The enhancements were from the higher open-circuit voltage (Voc) and fill factor (FF). The thermal- and solvent-treatment-free processing is more favourable for the large area roll-to-roll manufacturing or printing technology for PSCs.


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