Process R&D and Scale-up of Advanced Battery Materials at Argonne's Materials Engineering Research Facility

Author(s):  
P. J. Webster ◽  
Z. Chen ◽  
D. J. Hughes ◽  
A. Steuwer ◽  
B. Malard ◽  
...  

Large Central Scientific Facilities such as the ESRF (the European Synchrotron Radiation Facility) and ILL (the European centre for neutron research), were set up to provide scientists with the advanced facilities they need to exploit neutron and synchrotron X-ray beams for scientific research. Engineers also conduct research at these Facilities, but this is less common as most practicing engineers generally have little or no knowledge of neutron or X-ray scattering, or of their considerable potential for engineering research, model validation, material development and for fatigue and failure analysis. FaME38 is the new joint support Facility for Materials Engineering, located at ILL-ESRF, set up to encourage and to facilitate engineering research by engineers at these facilities. It provides a technical and knowledge centre, a materials support laboratory, and the additional equipment and resources that academic and industrial engineers need for materials engineering research to become practicable, efficient and routine. It enables engineers to add the most advanced scientific diffraction and imaging facilities to their portfolio of diagnostic tools. These include non-destructive internal and through-surface strain scanning, phase analysis, radiography and tomography of engineering components. Synchrotron X-ray and neutron diffraction strain mapping is particularly suited for the rigorous experimental, non-destructive, validation of Finite Element and other computer model codes used to predict residual stress fields that are critical to the performance and lifetimes of engineering components. This paper discusses the FaME38 facility and demonstrates its utility in gaining fundamental insight into mechanical engineering problems through examples, including studies of railway rails, welds and peened surfaces that demonstrate the potential of neutron of synchrotron X-ray strain scanning for the determination of residual stress fields in a variety of engineering materials and critical components.


1986 ◽  
Vol 10 (3P2B) ◽  
pp. 1117-1122 ◽  
Author(s):  
C.E. Wagner ◽  
D. Berwald ◽  
G. Listvinsky

2021 ◽  
Vol 54 (5) ◽  
pp. 1416-1423
Author(s):  
Oles Sendetskyi ◽  
Mark Salomons ◽  
Patricio Mendez ◽  
Michael Fleischauer

In situ and operando techniques play an important role in modern battery materials research and development. As materials characterization and application requirements advance, so too must the in situ/operando test methods and hardware. The effects of temperature, internal mechanical pressure and parasitic reactions due to, for example, cell sealing are critical for commercial scale-up but often overlooked in in situ/operando cell designs. An improved electrochemical operando cell for X-ray diffraction and spectroscopy using ConFlat-style flanges in combination with a beryllium window is presented. The cell is reusable and simple to fabricate and assemble, providing superior sealing, relevant and adjustable cell stack pressure, and reproducible charge/discharge cycling performance for short- and long-term experiments. Cell construction, electrochemical performance, and representative operando X-ray powder diffraction measurements with carbon and aluminium electrodes at temperatures between 303 and 393 K are provided. Operando electrochemical cell testing at high temperatures allows access to temperature-sensitive phase transitions and opens the way for analysis and development of new lithium-based cathode, anode and electrolyte materials for lithium-ion batteries.


1988 ◽  
Author(s):  
Herman C. Miller ◽  
Adele Militello ◽  
Michael W. Leffler ◽  
Jr. Grogg ◽  
Scarborough William E. ◽  
...  

1989 ◽  
Author(s):  
Michael W. Leffler ◽  
Kent K. Hathaway ◽  
Brian L. Scarborough ◽  
Clifford F. Baron ◽  
Herman C. Miller

Author(s):  
Eric McCalla ◽  
Matthew Parmaklis ◽  
Sarish Rehman ◽  
Ethan Anderson ◽  
Shipeng Jia ◽  
...  

In the search for better performing battery materials, researchers have increasingly ventured into complex composition spaces, including numerous pseudo-quaternaries, with numerous further substitutions being either explored experimentally or proposed based on computation. Given the vast composition spaces that need exploring, experimental combinatorial science can play an important role in accelerating the development of advanced battery materials and is arguably the best means to obtain a sufficiently large data set to truly bring a high degree of precision to advanced computational techniques such as machine-learning. Herein, we present a robust high-throughput synthesis platform that is currently being used in the McCalla lab at McGill University to study Li-ion cathodes, anodes and solid electrolytes, as well as Na-ion cathodes. The synthesis methods used are presented in detail, as are the high-throughput characterization techniques we utilize regularly (X-ray diffraction, electrochemical testing and electrochemical impedance spectroscopy). We quantitatively determine the high precision and reproducibility achieved by this combinatorial system and also demonstrate its versatility by presenting for the first time combinatorial data for two high-power anodes for Li-ion batteries (TiNb2O7 and W3-Nb14O44) as well as solid state electrolyte Li7La3Zr2O12. Our methods reproduce accurately the results from the literature for bulk samples, indicating that the high-throughput methodology utilizing small mg-scale samples scale up extremely well to the larger sample sizes typically used in both the literature and industry. The throughput of this combinatorial infrastructure has a current limit of 896 XRD patterns and 896 EIS patterns a week, and 448 cyclic voltammograms running simultaneously.


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