On Improving the Cycling Stability of P2-Type Na0.67Ni0.33Mn0.67O2 Cathode Material By Ti-Substitution for Na-Ion Batteries

2019 ◽  
Author(s):  
Debanjana Pahari ◽  
Sreeraj Puravankara
Keyword(s):  
Solid State ◽  
Cathode Material ◽  
Discharge Capacity ◽  
Synthesis Method ◽  
Cycling Stability ◽  
Solid State Synthesis ◽  
Initial Discharge Capacity ◽  
Initial Discharge ◽  
Ti Substitution ◽  
Solid State Synthesis Method

A novel cathode material with Ti-substitution on Ni site, P2-type Na0.67Ni0.25Ti0.08Mn0.67O2 has been synthesized via solid-state synthesis method and characterized electrochemically. Na0.67Ni0.25Ti0.08Mn0.67O2 electrodes have been observed tobe highly reversible at higher voltage ranges. The electrodes have an initial discharge capacity of 125 mAhg-1and can retain around 84% of this capacity (105 mAhg-1) even after 50 cycles at 0.1C when cycled at an uppercut-off voltage of 4.3 V. Na0.67Ni0.25Ti0.08Mn0.67O2 electrodes are believed to suppress the irreversible P2-O2 transformation by diverting the charging reaction through a more reversible P2-OP4transition.

On Improving the Cycling Stability of P2-Type Na0.67Ni0.33Mn0.67O2 Cathode Material By Ti-Substitution for Na-Ion Batteries

2019 ◽  
Author(s):  
Debanjana Pahari ◽  
Sreeraj Puravankara
Keyword(s):  
Solid State ◽  
Cathode Material ◽  
Electrode Materials ◽  
Cycling Stability ◽  
Partial Substitution ◽  
Li Ion Batteries ◽  
Initial Discharge Capacity ◽  
Initial Discharge ◽  
Li Ion ◽  
Ti Substitution

The extensive studies over the last decade have established Na-ion batteries (NIBs) as one of the cheaperalternatives to Li-ion batteries. P2-type Na0.67Ni0.33Mn0.67O2 has stood out among layered oxidebased electrode materials providing the best over-all electrochemical performance. The electrodes can exertup to 92.5% of its theoretical capacity (160 mAhg-1) at a voltage higher than 3 V accounted for the Ni2+/Ni4+redox. However, at higher voltages, electrodes suffer irreversibility due to P2-O2 structural transition.Recent studies in suppressing this transition by partial substitution with various metals on either Ni or Mnlattice site have suggested enhancing cycling stability. In this study, a novel cathode material with Ti-substitution on Ni site, P2-type Na0.67Ni0.25Ti0.08Mn0.67O2 has been synthesized via solid-state synthesismethod and characterized electrochemically. Na0.67Ni0.25Ti0.08Mn0.67O2 electrodes have been observed tobe highly reversible at higher voltage ranges. The electrodes have an initial discharge capacity of 125 mAhg-1and can retain around 84% of this capacity (105 mAhg-1) even after 50 cycles at 0.1C when cycled at an uppercut-off voltage of 4.3 V. Na0.67Ni0.25Ti0.08Mn0.67O2 electrodes are believed to suppress the irreversible P2-O2 transformation by diverting the charging reaction through a more reversible P2-OP4transition.

Effect of sulfur doping on structural reversibility and cycling stability of a Li2MnSiO4 cathode material

2018 ◽  
Vol 47 (35) ◽  
pp. 12337-12344 ◽  
Author(s):  
Xia Wu ◽  
Shi-Xi Zhao ◽  
Lü-Qiang Yu ◽  
Jin-Lin Yang ◽  
Ce-Wen Nan
Keyword(s):  
Cathode Material ◽  
Discharge Capacity ◽  
Cycling Stability ◽  
Initial Discharge Capacity ◽  
Sulfur Doping ◽  
Initial Discharge ◽  
Excellent Cycling Stability

Sulfur has been successfully employed into Li2MnSiO4 and results in a high initial discharge capacity and excellent cycling stability.

An inorganic–organic nanocomposite calix[4]quinone (C4Q)/CMK-3 as a cathode material for high-capacity sodium batteries

2017 ◽  
Vol 4 (11) ◽  
pp. 1806-1812 ◽  
Author(s):  
Shibing Zheng ◽  
Jinyan Hu ◽  
Weiwei Huang
Keyword(s):  
Cathode Material ◽  
Discharge Capacity ◽  
High Capacity ◽  
Initial Discharge Capacity ◽  
Capacity Retention ◽  
Initial Discharge ◽  
Sodium Batteries

A novel high-capacity cathode material C4Q/CMK-3 for SIBs shows an initial discharge capacity of 438 mA h g−1 and a capacity retention of 219.2 mA h g−1 after 50 cycles.

scholarly journals Smart Functional Surfactant Activated Conductive Polymer Coated on Paper with Ultra-Sensitive Humidity Sensing Characteristics

2022 ◽  
Author(s):  
Jonas Mahlknecht ◽  
Günter Wuzella ◽  
Herfried Lammer ◽  
Mohammed Khalifa
Keyword(s):  
Solid State ◽  
Sodium Lauryl Sulfate ◽  
Synthesis Method ◽  
Conductive Polymer ◽  
Solid State Synthesis ◽  
Lauryl Sulfate ◽  
Humidity Sensing ◽  
Sensing Characteristics ◽  
Solid State Synthesis Method ◽  
Surfactant Assisted

Herein, surfactant-assisted PANI nanorods was synthesized via the solid-state synthesis method at different concentrations of sodium lauryl sulfate (SLS). Upon the addition of SLS, the average rod diameter of PANI...

The displacement reaction mechanism of the CuV2O6 nanowire cathode for rechargeable aqueous zinc ion batteries

2020 ◽  
Vol 49 (4) ◽  
pp. 1048-1055 ◽  
Author(s):  
Xin Yu ◽  
Fang Hu ◽  
Fuhan Cui ◽  
Jun Zhao ◽  
Chao Guan ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Cathode Material ◽  
Discharge Capacity ◽  
Current Density ◽  
Zinc Ion ◽  
Cycle Performance ◽  
Displacement Reaction ◽  
Initial Discharge Capacity ◽  
Initial Discharge ◽  
A Current

CuV2O6 nanowires as a cathode material for Zn-ion batteries display an initial discharge capacity of 338 mA h g−1 at a current density of 100 mA g−1 and an excellent cycle performance after 1200 cycles at 5 A g−1.

Fabrication of layered Ti3C2 with an accordion-like structure as a potential cathode material for high performance lithium–sulfur batteries

2015 ◽  
Vol 3 (15) ◽  
pp. 7870-7876 ◽  
Author(s):  
Xiaoqin Zhao ◽  
Min Liu ◽  
Yong Chen ◽  
Bo Hou ◽  
Na Zhang ◽  
...  
Keyword(s):  
Cathode Material ◽  
Discharge Capacity ◽  
High Performance ◽  
Coulombic Efficiency ◽  
Initial Discharge Capacity ◽  
Capacity Retention ◽  
Initial Discharge ◽  
Lithium Sulfur Batteries ◽  
Lithium Sulfur

L-Ti3C2 was prepared by exfoliating Ti3AlC2 in 40% HF. With sulfur-loaded L-Ti3C2 as cathodes, Li–S batteries deliver a high initial discharge capacity of 1291 mA h g−1, an excellent capacity retention of 970 mA h g−1 and coulombic efficiency of 99% after 100 cycles.

scholarly journals A novel low-temperature solid-state route for nanostructured cubic garnet Li7La3Zr2O12 and its application to Li-ion battery

RSC Advances ◽  
2016 ◽  
Vol 6 (67) ◽  
pp. 62656-62667 ◽  
Author(s):  
P. Jeevan Kumar ◽  
K. Nishimura ◽  
M. Senna ◽  
A. Düvel ◽  
P. Heitjans ◽  
...  
Keyword(s):  
Solid State ◽  
Low Temperature ◽  
Discharge Capacity ◽  
Li Ion Battery ◽  
Initial Discharge Capacity ◽  
Solid State Route ◽  
Initial Discharge ◽  
Model Cell ◽  
Li Ion

Garnet Li7La3Zr2O12 nanoparticles with 1 mass% Al were prepared via a solid-state route at 750 °C within 3 h. A model cell sandwiched by Li and LiCoO2 exhibited initial discharge capacity of 64 μA h cm−2 μm−1, being 93% of LiCoO2 theoretical value.

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