scholarly journals Potentiometric Studies on Transition Metal Complexes of Substituted Derivative of Coumarin-Part 1

2009 ◽  
Vol 6 (4) ◽  
pp. 1121-1124
Author(s):  
K. B. Vyas ◽  
G. R. Jani ◽  
M. V. Hathi
Keyword(s):  
Ionic Strength ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Sodium Nitrate ◽  
Formation Constants ◽  
Potentiometric Studies ◽  
Factors Influencing ◽  
Binary Complexes

The formation constants of binary complexes of d10metal ions Cu(II), Ni(II), Co(II) and Mn(II) with 3-[{3-(3’-chloro phenyl}-prop-2-enoyl]-4-hydroxy-6-methyl-2H-chromen-2-one have been studied by using Irving-Rossoti method at constant temperature 30±1°C and ionic strength μ=0.1 M dM-3was held constant using sodium nitrate as an electrolyte. The factors influencing formation and stabilities of binary complexes have been discussed.

Synthesis, Characterization and in vitro Biological Evaluation of a New Schiff Base Derived from Drug and its Complexes with Transition Metal Ions

2018 ◽  
Vol 69 (7) ◽  
pp. 1678-1681
Author(s):  
Amina Mumtaz ◽  
Tariq Mahmud ◽  
M. R. J. Elsegood ◽  
G. W. Weaver
Keyword(s):  
Schiff Base ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Free Ligand ◽  
Transition Metal Ions ◽  
Biological Evaluation ◽  
Pyridoxal Hydrochloride

New series of copper (II), cobalt (II), zinc (II), nickel (II), manganese (II), iron (II) complexes of a novel Schiff base were prepared by the condensation of sulphadizine and pyridoxal hydrochloride. The ligand and metal complexes were characterized by utilizing different instrumental procedures like microanalysis, thermogravimetric examination and spectroscopy. The integrated ligand and transition metal complexes were screened against various bacteria and fungus. The studies demonstrated the enhanced activity of metal complexes against reported microbes when compared with free ligand.

scholarly journals The proton and metal complexes of adenyl-5′-yl imidodiphosphate

1976 ◽  
Vol 159 (1) ◽  
pp. 169-171 ◽  
Author(s):  
L D Pettit ◽  
K F Siddiqui
Keyword(s):  
Complex Formation ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Ions ◽  
Formation Constants ◽  
Enthalpy Change ◽  
Two Temperatures ◽  
Bivalent Transition Metal

The formation constants of the complexes of adenyl-5′-yl imidodiphosphate with H+ Mg2+, Ca2+ and a number of bivalent transition-metal ions were measured potentionmetrically. The complexes are generally a little more stable than the analogous complexes of ATP. By measuring the formation constants at two temperatures, this increase in stability was shown to result from an increased enthalpy change on complex-formation.

Studies on complexes of VO(II), Mn(II), Cu(II), Ni(II), Co(II), Zn(II), Fe(III), and UO2(II) with hydrazone β-diketone ligands

1990 ◽  
Vol 68 (5) ◽  
pp. 774-781 ◽  
Author(s):  
Mohamed S. Abdel-Moez ◽  
Shaker L. Stefan ◽  
Mostafa M. El-Behairy ◽  
Mohamed M. Mashely ◽  
Basheir A. El-Shetary
Keyword(s):  
Magnetic Susceptibility ◽  
Transition Metal ◽  
Ir Spectra ◽  
Metal Ions ◽  
Metal Complexes ◽  
Stability Constants ◽  
Transition Metal Complexes ◽  
Elemental Analysis ◽  
Water Solvent ◽  
Uv Visible

The stepwise stability constants of VO(II), Mn(II), Cu(II), Ni (II), Co(II), Zn(II), Fe(III), and UO2(II) metal ions with 2-(2-acetylphenylhydrazone)-5,5-dimethyl-1,3-cyclohexane dione (2-APHDm), 3-(2-acetylphenylhydrazone)pentane-2,4-dione (2-APHA), 2-(2-acetylphenylhydrazone)-1-phenyl-1,3-butane dione (2-APHB), 2-(2-acetylphenylhydrazone)-1,3-diphenyl-1,3-propane dione (2-APHDB), and 3-(2-acetylphenylhydrazone)-1,1,1-trifluoropentane-2,4-dione (2-APHTA) were determined at 30 °C by pH titrations in 75% (v/v) dioxane–water solvent. In addition, metal complexes of three related β-diketones, 2-APHA, 2-APHB, and 2-APHDB have been synthesized and characterized by elemental analysis, uv–visible, ir spectra, and conductance in DMF and magnetic susceptibility measurements. The structure of the complexes have been proposed. Keywords: transition metal complexes of hydrazone-β-diketone ligands.

Structural, photophysical and magnetic properties of transition metal complexes based on the dipicolylamino-chloro-1,2,4,5-tetrazine ligand

2015 ◽  
Vol 44 (19) ◽  
pp. 8855-8866 ◽  
Author(s):  
Iuliia Nazarenko ◽  
Flavia Pop ◽  
Qinchao Sun ◽  
Andreas Hauser ◽  
Francesc Lloret ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Transition Metal ◽  
Metal Ions ◽  
Metal Complexes ◽  
Transition Metal Complexes

Tuning structural, luminescence and magnetic properties of the complexes of a chloro-tetrazine-dipicolylamine ligand by coordination to four different metal ions.

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