scholarly journals Fabrication, Characterization, and Optimization of CdS and CdSe Quantum Dot-Sensitized Solar Cells with Quantum Dots Prepared by Successive Ionic Layer Adsorption and Reaction

2014 ◽  
Vol 2014 ◽  
pp. 1-14 ◽  
Author(s):  
H. K. Jun ◽  
M. A. Careem ◽  
A. K. Arof

CdS and CdSe quantum dot-sensitized solar cells (QDSSCs) were used for the study of determining the optimum preparation parameters that could yield the best solar cell performance. The quantum dots (QDs) were coated on the surface of mesoporous TiO2layer deposited on FTO substrate using the successive ionic layer adsorption and reaction (SILAR) method. In this method the QDs are allowed to grow on TiO2by dipping the TiO2electrode successively in two different solutions for predetermined times. This method allows the fabrication of QDs in a facile way. Three preparation parameters that control the QD fabrication were investigated: concentration of precursor solutions, number of dipping cycles (SILAR cycles), and dipping time in each solution. CdS based QDSSC showed optimum performance when the QDs were prepared from precursor solutions having the concentration of 0.10 M using 4 dipping cycles with the dipping time of 5 minutes in each solution. For CdSe QDSSC, the optimum performance was achieved with QDs prepared from 0.03 M precursor solutions using 7 dipping cycles with 30 s dipping time in each solution. The QDs deposited on TiO2surface were characterized using UV-vis absorption spectroscopy, FESEM, and TEM imaging.

Nano Letters ◽  
2009 ◽  
Vol 9 (12) ◽  
pp. 4221-4227 ◽  
Author(s):  
HyoJoong Lee ◽  
Mingkui Wang ◽  
Peter Chen ◽  
Daniel R. Gamelin ◽  
Shaik M. Zakeeruddin ◽  
...  

2015 ◽  
Vol 3 (23) ◽  
pp. 12539-12549 ◽  
Author(s):  
Ru Zhou ◽  
Haihong Niu ◽  
Qifeng Zhang ◽  
Evan Uchaker ◽  
Zhiqiang Guo ◽  
...  

Appreciable influences of deposition strategies on the assembly of QDs and the performance of the resultant QDSCs were highlighted.


2013 ◽  
Vol 873 ◽  
pp. 556-561
Author(s):  
Jian Jun Tian

CdS/CdSe quantum dots co-sensitized solar cells (QDSCs) were prepared by combining the successive ion layer absorption and reaction (SILAR) method and chemical bath deposition (CBD) method for the fabrication of CdS and CdSe quantum dots, respectively. In this work, we designed anisotropic nanostructure ZnO photoelectrodes, such as nanorods/nanosheets and nanorods array, for CdS/CdSe quantum dots co-sensitized solar cells. Our study revealed that the performance of QDSCs could be improved by modifying surface of ZnO to increase the loading of quantum dots and reduce the charge recombination.


2014 ◽  
Vol 2014 ◽  
pp. 1-6 ◽  
Author(s):  
Xiaoping Zou ◽  
Sheng He ◽  
Gongqing Teng ◽  
Chuan Zhao

In order to optimize the charge transfer path in quantum dot sensitized solar cells (QDSCs), we employed successive ionic layer adsorption and reaction method to dope CdSe with Co for fabricating CdS/Co-doped-CdSe QDSCs constructed with CdS/Co-doped-CdSe deposited on mesoscopic TiO2film as photoanode, Pt counter electrode, and sulfide/polysulfide electrolyte. After Co doping, the bandgap of CdSe quantum dot decreases, and the conduction band and valence band all improve, forming a cascade energy level which is more conducive to charge transport inside the solar cell and reducing the recombination of electron-hole thus improving the photocurrent and ultimately improving the power conversion efficiency. This work has not been found in the literature.


2014 ◽  
Vol 10 (3) ◽  
pp. 621-626 ◽  
Author(s):  
Myeong-Soo Jeong ◽  
Min-Kyu Son ◽  
Soo-Kyoung Kim ◽  
Songyi Park ◽  
Kandasamy Prabakar ◽  
...  

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