Improving Fire Safety of Epoxy Resin with Alkyl Glycoside Modified CuAl-Layered Double Hydroxide

In this work, sandwich-like structured CoAl-LDH@ZIF-67 hybrids were constructed by in situ growth of nanosized ZIF-67 crystallites on CoAl-LDH nanoplates.

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Flame-retardant effect of a phenethyl-bridged DOPO derivative and layered double hydroxides for epoxy resin

RSC Advances ◽

10.1039/c7ra08173a ◽

2017 ◽

Vol 7 (73) ◽

pp. 46236-46245 ◽

Cited By ~ 14

Author(s):

Wei Yan ◽

Jie Yu ◽

Mingqiu Zhang ◽

Shuhao Qin ◽

Tao Wang ◽

...

Keyword(s):

Flame Retardant ◽

Epoxy Resin ◽

Layered Double Hydroxide ◽

Layered Double Hydroxides ◽

Double Hydroxide ◽

Double Hydroxides

Flame-retardant epoxy resin (EP) composites were prepared by the incorporation of a phenethyl-bridged DOPO derivative (DiDOPO) and modified layered double hydroxide (OLDH).

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Synthesis and characterization of functional eugenol derivative based layered double hydroxide and its use as a nanoflame-retardant in epoxy resin

Journal of Materials Chemistry A ◽

10.1039/c4ta05740f ◽

2015 ◽

Vol 3 (7) ◽

pp. 3471-3479 ◽

Cited By ~ 69

Author(s):

Cheng Li ◽

Jintao Wan ◽

Ehsan Naderi Kalali ◽

Hong Fan ◽

De-Yi Wang

Keyword(s):

Flame Retardant ◽

Epoxy Resin ◽

Layered Double Hydroxide ◽

Epoxy Resins ◽

Synthesis And Characterization ◽

Double Hydroxide

Aiming to develop a multi-functional flame retardant for epoxy resins, a novel bio-based eugenol derivative (SIEPDP) was synthesized, and was used to modify Mg–Al layered double hydroxide (SIEPDP-LDH). This modified SIEPDP-LDH was used as a novel nanoflame-retardant for bisphenol epoxy resins and compared with unmodified pristine LDH.

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Improving Flame Retardancy of Epoxy Resin Nanocomposites by Carbon Nanotubes Grafted CuAl-Layered Double Hydroxide Hybrid

Journal of Nanoscience and Nanotechnology ◽

10.1166/jnn.2020.18120 ◽

2020 ◽

Vol 20 (10) ◽

pp. 6406-6412 ◽

Cited By ~ 1

Author(s):

Huiyu Cai ◽

Fangchao Peng ◽

Yixi Wang ◽

Junyan Yi ◽

Xingwei Cai ◽

...

Keyword(s):

Carbon Nanotubes ◽

Flame Retardant ◽

Epoxy Resin ◽

Layered Double Hydroxide ◽

Sodium Dodecyl ◽

3D Structure ◽

Fire Retardant ◽

Limit Oxygen Index ◽

Ep Matrix ◽

Double Hydroxide

To solve the issues of the poor dispersion performance of the inorganic flame retardant filler in epoxy resin (EP) matrix, the three-dimensional (3D) hybrid carbon nanotubes-copper aluminum (sodium dodecyl sulfate)-layered double hydroxide (CNTs-OLDH) is designed and synthesized by co-precipitation. The results indicate that the CNTs-OLDH hybrid with 3D-structure is successfully fabricated and well dispersed in EP matrix. The thermostability of EP/CNTs-OLDH nanocomposites is raised and the residue is obviously increased. When the amount of CNTs-OLDH is only 4 wt%, limit oxygen index value of EP/CNTs-OLDH nanocomposites reaches 28.5. Compared with pure EP, the heat release, smoke and gas of EP/FePP nanocomposites are inhibited by CNTs-OLDH hybrid, and the PHRR, THR and SPR values of EP/4CNTs-OLDH nanocomposites decrease by 41.7%, 27.8% and 31.7%. The improved fire retardant performances and thermal stability are attributed to the excellent homogeneous dispersion, the network structure formed by the 3D hybrid in the matrix and the outstanding flame retardant effect of CNTs and OLDH.

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