Electrochemical Preparation of a Reduced Graphene Oxide/Ruthenium Oxide Modified Electrode and Its Application to the Simultaneous Determination of Serotonin and Melatonin

2015 ◽  
Vol 7 (4) ◽  
pp. 654-662 ◽  
Author(s):  
Balamurugan Devadas ◽  
Rajesh Madhu ◽  
Shen-Ming Chen ◽  
Vediyappan Veeramani ◽  
Muniyandi Rajkumar
2014 ◽  
Vol 2014 ◽  
pp. 1-10 ◽  
Author(s):  
Gen Liu ◽  
Wei Ma ◽  
Yan Luo ◽  
Deng-ming Sun ◽  
Shuang Shao

Poly(methylene blue) and electrochemically reduced graphene oxide composite film modified electrode (PMB-ERGO/GCE) was successfully fabricated by electropolymerization and was used for simultaneous determination of uric acid (UA) and xanthine (Xa). Based on the excellent electrocatalytic activity of PMB-ERGO/GCE, the electrochemical behaviors of UA and Xa were studied by cyclic voltammetry (CV) and square wave voltammetry (SWV). Two anodic sensitive peaks at 0.630 V (versus Ag/AgCl) for UA and 1.006 V (versus Ag/AgCl) for Xa were given by CV in pH 3.0 phosphate buffer. The calibration curves for UA and Xa were obtained in the range of 8.00 × 10−8~4.00 × 10−4 M and 1.00 × 10−7~4.00 × 10−4 M, respectively, by SWV. The detection limits for UA and Xa were3.00×10-8 M and5.00×10-8 M, respectively. Finally, the proposed method was applied to simultaneously determine UA and Xa in human urine with good selectivity and high sensitivity.


2018 ◽  
Vol 30 (11) ◽  
pp. 2620-2627 ◽  
Author(s):  
Miloš Ognjanović ◽  
Dalibor M. Stanković ◽  
Martin Fabián ◽  
Aleksandar Vukadinović ◽  
Željko Prijović ◽  
...  

RSC Advances ◽  
2014 ◽  
Vol 4 (89) ◽  
pp. 48522-48534 ◽  
Author(s):  
A. T. Ezhil Vilian ◽  
Muniyandi Rajkumar ◽  
Shen-Ming Chen ◽  
Chi-Chang Hu ◽  
Shakkthivel Piraman

This paper describes the two-step synthesis of a nitrogen-doped reduced graphene oxide–ZnO (N-doped RGO–ZnO) nanocomposite and its photo electrochemical application.


Author(s):  
Pedro Borges ◽  
Edson Nossol

Reduced graphene oxide/ruthenium oxide hexacyanoferrate (rGO/RuOHCF) modified electrode showed synergic activity between the materials attested by the increase of electrochemical current and stability. The preparation of the nanocomposite was made by a simple two-step electrochemical approach. The material structure was characterized by spectroscopic techniques (Raman, infrared and energy-dispersive X-ray) as well as its morphology by scanning electron microscopy and compared to the analogously prepared reduced graphene oxide (rGO) and ruthenium oxide hexacyanoferrate (RuOHCF) thin films spectra and images. The results suggest that the improvement of the nanocomposite electrochemical activity is generated by the well-distributed RuOHCF nanometric particles over high-surfaced graphene sheets. Ethanol electrochemical oxidation in the rGO/RuOHCF modified electrode was performed in 0.1 mol L-1 NaCl (pH = 1.5) solution and it showed an anodic current peak starting at 0.9 V. Scan rate tests exhibited a diffusioncontrolled process not followed by any coupled chemical reaction. The determination of ethanol by amperometry coupled with batch injection analysis (BIA) system resulted in a wide linear range (20-400 mmol L-1) and good sensitivity (0.150 μA L mmol-1). The nanocomposite also showed application as an electrochemical sensor of ethanol in commercial samples mainly because of its easy preparation comparing to biosensors.


RSC Advances ◽  
2015 ◽  
Vol 5 (28) ◽  
pp. 21659-21669 ◽  
Author(s):  
H. Bagheri ◽  
A. Afkhami ◽  
P. Hashemi ◽  
M. Ghanei

An electrochemical sensor based on a new nanocomposite of graphene/Fe3O4 has been fabricated for simultaneous determination of melatonin and dopamine.


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