Automated Fluoride Ion Determination

1977 ◽  
Vol 14 (1-6) ◽  
pp. 269-274 ◽  
Author(s):  
David C. Cowell
Keyword(s):  
Continuous Flow ◽  
Ion Concentration ◽  
Fluoride Ion ◽  
Selective Electrode ◽  
Automated Method ◽  
Electrode Response ◽  
Kinetics Of ◽  
Fluoride Ion Selective Electrode ◽  
Flow Techniques

An automated method is described, using standard continuous flow techniques, for the determination of urine fluoride ion concentration using a fluoride ion selective electrode. It is shown that the kinetics of the electrode response to changes in fluoride ion can be used for the accurate measurement of fluoride ion concentration in urine, and that equilibration of the electrode response is not a prerequisite for the measurement of fluoride ion. Recovery experiments are in the range 83 to 90%; in-batch precision is between 0·9 and 1·6% and carryover 2·5% or less.

Automated Fluoride Ion Determination

1977 ◽  
Vol 14 (1-6) ◽  
pp. 275-278 ◽  
Author(s):  
David C. Cowell
Keyword(s):  
Continuous Flow ◽  
Ion Concentration ◽  
Fluoride Ion ◽  
Selective Electrode ◽  
Electrode Response ◽  
Kinetics Of ◽  
Fluoride Ion Selective Electrode ◽  
Automated Determination ◽  
Flow Techniques

A method is described, using standard continuous flow techniques, for the automated determination of serum fluoride ion concentration using a fluoride ion selective electrode. It is shown that the kinetics of the electrode response to changes in fluoride ion can be used for the accurate measurement of fluoride ion concentration in serum, and that equilibration of the electrode response is not a prerequisite for the measurement of fluoride ion. Recovery experiments are in the range 86·6–98·5%, in-batch precision is 1·0–6·1%, between-batch precision 5·5%, with carryover of −2·99%.

Determination of inorganic fluoride in blood with a fluoride ion-selective electrode.

1987 ◽  
Vol 33 (2) ◽  
pp. 253-255 ◽  
Author(s):  
E Kissa
Keyword(s):  
Whole Blood ◽  
Fluoride Concentration ◽  
Ion Selective Electrode ◽  
Fluoride Ion ◽  
Inorganic Fluoride ◽  
Selective Electrode ◽  
Cell Potential ◽  
Novel Method ◽  
Fluoride Ion Selective Electrode

Abstract Inorganic fluoride in whole blood, serum, or plasma has been determined with a fluoride ion-selective electrode by adding the 0.5- to 2.0-mL sample to 20 mL of water containing a buffer and fluoride, 25 micrograms/L. The fluoride concentration in the sample is calculated from the resulting cell potential difference recorded after equilibrating for 10 min. This novel method has the advantages of simplicity, accuracy, and high precision, standard deviations for 5 to 7 replicate determinations of fluoride ranging from +/- 1.7 to +/- 2.4 micrograms/L. For whole blood from donors living in an area with fluorinated drinking water, the F- concentration was 20 to 60 micrograms/L.

Fluoride determination in various matrices relevant to nuclear industry: A review

2007 ◽  
Vol 95 (10) ◽  
Author(s):  
R. M. Sawant ◽  
M. A. Mahajan ◽  
Poonam Verma ◽  
Dipti Shah ◽  
U. K. Thakur ◽  
...  
Keyword(s):  
Nuclear Industry ◽  
Ion Selective Electrode ◽  
Nuclear Technology ◽  
Fluoride Ion ◽  
Selective Electrode ◽  
Experimental Parameters ◽  
Fluoride Determination ◽  
Reactor Materials ◽  
Fluoride Ion Selective Electrode

The determination of fluoride from diverse matrices at front and back end of nuclear technology and some studies from this laboratory on optimizations of different experimental parameters differing with multiple fuels and reactor materials, have been reviewed. The most useful techniques such as fluoride ion selective electrode (F-ISE) and ion-chromatography (IC) widely adopted as routine methods for fluoride determination in nuclear industry have been discussed. The effect of various buffer strengths on the response of the fluoride ion selective electrode has been examined. The ion chromatographic studies on mobile phase concentration, medium of sample, sample injection volume

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