Thermal decomposition and fire behavior of glass fiber–reinforced polyester resin composites containing phosphate-based fire-retardant additives

2012 ◽  
Vol 30 (4) ◽  
pp. 318-330 ◽  
Author(s):  
Maria R Ricciardi ◽  
Vincenza Antonucci ◽  
Michele Giordano ◽  
Mauro Zarrelli
Author(s):  
J Vipin Allien ◽  
Hemantha Kumar ◽  
Vijay Desai

The semi-active vibration control of sandwich beams made of chopped strand mat glass fiber reinforced polyester resin polymer matrix composite (PMC) and magnetorheological fluid (MRF) core were experimentally investigated in this study. Two-, four- and six-layered glass fiber reinforced polyester resin polymer matrix composites were prepared using the hand-layup technique. The magnetorheological fluid was prepared in-house with 30% volume of carbonyl iron powder and 70% volume of silicone oil. Nine cantilever sandwich beams of varying thicknesses of the top and bottom layers glass fiber reinforced polyester resin polymer matrix composite beams and middle magnetorheological fluid core were prepared. The magnetorheological fluid core was activated with a non-homogeneous magnetic field using permanent magnets. The first three modes, natural frequencies and damping ratios of the glass fiber reinforced polyester resin polymer matrix composite-magnetorheological fluid core sandwich beams were determined through free vibration analysis using DEWESoft modal analysis software. The amplitude frequency response of the glass fiber reinforced polyester resin polymer matrix composite-magnetorheological fluid core sandwich beams through forced vibration analysis was determined using LabVIEW. The effect of various parameters such as magnetic flux density, thickness of glass fiber reinforced polyester resin polymer matrix composite layers and magnetorheological fluid core layer on the natural frequencies, damping ratio and vibration amplitude suppressions of the glass fiber reinforced polyester resin polymer matrix composite-magnetorheological fluid core sandwich beams was investigated. Based on the results obtained, 2 mm thickness top and bottom layers glass fiber reinforced polyester resin polymer matrix composite and 5 mm thickness magnetorheological fluid core sample have achieved a high shift in increased natural frequency, damping ratio and vibration amplitude suppression under the influence of magnetic flux density.


2019 ◽  
Vol 37 (3) ◽  
pp. 193-212
Author(s):  
Xi Cheng ◽  
Jianming Wu ◽  
Chenguang Yao ◽  
Guisheng Yang

This study compared thermal degradation, pyrolysis behavior, and the fire behavior of flame-retarded glass-fiber-reinforced polyamide 6 with aluminum hypophosphite and aluminum phenylphosphinate (BPA-Al), respectively. We sythesize aluminum phenylphosphinate by benzenephosphinic acid (BPA) and AlCl3.6H2O in water. so we call aluminum phenylphosphinate BPA-Al for short. The dependence of limiting oxygen index on phosphorus content was linear for aluminum hypophosphite and BPA-Al. Thermogravimetric analysis proved aluminum hypophosphite was less stable than BPA-Al. Thermogravimetric-Fourier transform infrared tests showed that aluminum hypophosphite system balanced the charring process and the gas releasing well, and that BPA-Al system enhanced the charring process and decreased the gas releasing. Peak heat release rate and total heat release data proved that aluminum hypophosphite system was superior to BPA-Al system in lowering the heat release. Their differences were caused by different P-H (aluminum hypophosphite) and P-phenyl (BPA-Al) structures. P-H structure did better than P-phenyl structure in balancing the condensed phase effect and the gaseous phase action. So P-H structure (aluminum hypophosphite) was more suitable than P-phenyl structure (BPA-Al) in the flame retardancy of glass-fiber-reinforced polyamide 6.


SpringerPlus ◽  
2016 ◽  
Vol 5 (1) ◽  
Author(s):  
Nannan Hu ◽  
Ke Wang ◽  
Hongming Ma ◽  
Wanjiang Pan ◽  
Qingqing Chen

Sign in / Sign up

Export Citation Format

Share Document