Fabrication of 3D scaffolds based on fully biobased unsaturated polyester resins by microstereo-lithography

Additive Manufacturing (AM) technologies are an effective route to fabricate tailor made scaffolds for tissue engineering (TE) and regenerative medicine with microstereo-lithography (µSLA) being one of the most promising techniques to produce high quality 3D structures. Here, we report the crosslinking studies of fully biobased unsaturated polyesters (UPs) with 2-hydroxyethyl methacrylate (HEMA) as the unsaturated monomer (UM), using thermal and µSLA crosslinking processes. The resulting resins were fully characterized in terms of their thermal and mechanical properties. Determination of gel content, water contact angle (WCA), topography and morphology analysis by atomic force microscopy (AFM) and scanning electron microscopy (SEM) were also performed. The results show that the developed unsaturated polyester resins (UPRs) have promising properties for µSLA. In vitro cytotoxicity assays performed with 3T3-L1 cell lines showed that the untreated scaffolds exhibited a maximum cellular viability around 60 %, which was attributed to the acidic nature of the UPRs. The treatment of the UPRs and scaffolds with ethanol (EtOH) improved the cellular viability to 100%. The data presented in this manuscript contribute to improve the performance of biobased unsaturated polyesters in additive manufacturing.

Mechanical and Thermomechanical Properties of Clay-Cowpea (Vigna Unguiculata Walp.) Husks Polyester Bio-Composite for Building Applications

This study investigates the feasibility of creating a clay polymer-based composite using cowpea husk (CPH) as filler for production of roof tiles. Polymeric composites were fabricated by mixing unsaturated polyester (UPT) resin with cowpea husk at different filler weights and curing. A hybrid composite was produced with the addition of 3 wt.% clay and all samples produced were subjected to flexural, hardness and dynamic mechanical analysis (DMA) tests. The effect of clay addition on the mechanical and thermo-mechanical behaviour of formulated composites was investigated. The morphological analysis of the mono and hybrid system shows a rough and coarse inhomogeneous surface with voids created due to the addition of CPH filler for the mono reinforced and clay uniformly filling the voids that were created by the CPH in the hybrid composite. It is observed that hardness, tensile modulus and flexural modulus of hybrid composites increase with an increase in the CPH contents, while the strength and flexural strength all decrease with filler content. The optimal composition was obtained using Grey relational analysis (GRA) at 18% CPH for both mono and hybrid composite. The results imply that the composite combination can be used in making rooftiles and/or also in applications where low strength is required.

On the Mechanism of the Steady-State Gamma Radiolysis-Induced Scissions of the Phenyl-Vinyl Polyester-Based Resins

The major societal problem of polymeric waste necessitates new approaches to break down especially challenging discarded waste streams. Gamma radiation was utilized in conjunction with varying solvent environments in an attempt to discern the efficacy of radiolysis as a tool for the deliberate degradation of model network polyesters. Our EPR results demonstrated that gamma radiolysis of neat resin and in the presence of four widely used solvents induces glycosidic scissions on the backbone of the polyester chains. EPR results clearly show the formation of alkoxy radicals and C-centered radicals as primary intermediate radiolytic products. Despite the protective role of the phenyl groups on the backbone of the radiation-induced polyester chains, the radiolytic-glycosidic scissions predominate. Among the following three solvents used in this study (water, isopropyl alcohol, and dichloromethane), the highest radiolytic yield of glycosidic scission was achieved using water. The •OH radicals produced in the radiolysis of phenyl unsaturated polyester aqueous suspensions very rapidly abstract H atoms from the methylene group, which is followed by a very rapid glycosidic scission. The lowest glycosidic yield was found in the dichloromethane solutions of these polyester resins due to scavenging by the fast electron capture reactions.

Effect of Water Absorption on Flexural Properties of Kenaf/Glass Fibres Reinforced Unsaturated Polyester Hybrid Composites Rod

This study investigates the effect of water absorption on the flexural strength of kenaf/ glass/unsaturated polyester (UPE) hybrid composite solid round rods used for insulating material applications. Three volume fractions of kenaf/glass fibre 20:80 (KGPE20), 30:70 (KGPE30), and 40:60 (KGPE40) with three different fibre arrangement profiles of kenaf fibres were fabricated by using the pultrusion technique and were aimed at studying the effect of kenaf fibres arrangement profile and its content in hybrid composites. The fibre/ resin volume fraction was maintained constant at 60:40. The dispersion morphologies of tested specimens were observed using the scanning electron microscope (SEM). The findings were compared with pure glass fibre-reinforced UPE (control) composite. The water absorption results showed a clear indication of how it influenced the flexural strength of the hybrid and non-hybrid composites. The least affected sample was observed in the 30KGPE composite type, wherein the kenaf fibre was concentrated at the centre of a cross-section of the composite rod. The water absorption reduced the flexural strength by 7%, 40%, 24%, and 38% of glass/UPE (control), 20KGPE, 30KGPE, and 40KGPE composites, respectively. In randomly distributed composite types, the water absorption is directly proportional to the volume fraction of kenaf fibre. At the same time, flexural properties were inversely proportional to the volume fraction of kenaf fibres. Although the influence of water absorption on flexural strength is low, the flexural strength of pultruded hybrid composites was more influenced by the arrangement of kenaf fibre in each composite type than its fibre loading.

Mechanics of Materials Natural Fibers Technology on Thermal Properties of Polymer

The thermal characteristics of polymathic methacrylate combined with unsaturated polyester were determined by numerical and experimental research. Models for numerically investigating the parameters of thermal conductivity, specific heat capacity, and thermal diffusivity were developed using COMSOL Multiphysics. The numerical data were then compared to experimental results for the same material using the same measurements to ensure that they were correct. By comparing the thermal conductivity data to two sets of theoretical data, the results were confirmed. The COMSOL models were quite close to the experimental data, with just minor differences between the three models. One set of theoretical data coincided with the mean of the other data, while the second set revealed a significant departure below the other data.

Effects of drilling parameters on delamination of kenaf-glass fibre reinforced unsaturated polyester composites

Drilling is a secondary material removal and usually carried out to facilitate fastening of parts together. Drilling of composite materials is not usually a problem-free process. Issues related to delamination composite laminates need to be addressed because it introduces the stress concentration point on the composite. This study focussed on the influence of process parameters such as spindle speed, feed rate, type of drill bits and geometry on the extend of delamination experienced by the composite during the drilling process of kenaf-glass fibre-reinforced unsaturated polyester composite, and the delamination measurements were taken under a microscope. Taguchi methods and analysis of variance were employed to find the optimal parameters. From the results, the most significant parameter was the feed rate. The minimum delamination was achieved when the feed rate was 0.05 mm/rev and spindle speed was 700r/min using both types of drill bits. The quality of the drill hole using the twist drill bit has been proven to be better than the brad drill bit.

The Effect of Wear Rate on Polymeric Composites Reinforced Nanoclays

This research aims to study the addition of nanoclays on unsaturated polyester (UP) and epoxy resin (EP) as filling and by weight percentage (2%, 4% and 6%) to this mixture and then study the extent of the effect of this addition on wear rate of the composites’ material where three loads were adopted (10, 15 and 20[Formula: see text]N), respectively, on the iron hard disk (269 HB) and copper hard disk of 111[Formula: see text]HB for the resin before and after adding the clays, where the approved sliding velocities were 4.1887, 3.1415 and 2.0943[Formula: see text]m/sec, respectively, and the test duration was 10 min on the test disc. Immersion of samples in the water for 2, 4, 6 and 8 weeks showed a clear improvement in the wear rate and tear values of dry and submerged conditions in a water under different conditions of load change, slipping speed, time and temperature stability after adding the nanoclays to the polymer.

Pengaruh Fraksi Volume Serat Jerami Terhadap Kekuatan Material Komposit Aplikasi Kayu Lapis

Polymer Matrix Composite (PMC) is a composite material that uses a polymer matrix most widely used in industry, transportation, and everyday life. Plywood is one of the current industrial needs that is growing rapidly and is becoming a leading export. However, besides that, the availability of raw materials is decreasing along with deforestation. Resulting in the need for alternative raw materials. Straw is one of the largest wastes that is not utilized optimally. It can be used as straw as a reinforcing material for environmentally friendly composite materials. Composite material was made using the hand lay up method, with straw fiber purchased with 4% NaOH treatment using Yukalac 157 BQTN-EX unsaturated polyester resin and MEPOXE A hardener. Then, tensile testing was carried out with volume fractions of straw fiber 5%, 10% 20% and 30 % This shows that the volume fraction of straw fiber affects the strength of the composite material. The tensile strength value of the straw fiber composite meets the minimum standard for tensile strength in plywood. Judging from the surface structure of the composite material, there are voids or air bubbles. However, the most visible in the sample with fractions of 10% and 20%. Further research needs to be done with other tests such as hit test, sandpaper test to meet the requirements for SNI standard plywood.