Poly (ether ether ketone) composites reinforced by graphene oxide and silicon dioxide nanoparticles

2017 ◽  
Vol 30 (4) ◽  
pp. 406-417 ◽  
Author(s):  
Xiaochen Hou ◽  
Ying Hu ◽  
Xiyu Hu ◽  
Dong Jiang

Wear-resistant composites with excellent tribological performances and good mechanical/thermal properties were developed by blending the modification of nano-silicon dioxide (m-SiO2) and the modification of graphene oxide (m-GO) with a poly (ether ether ketone) (PEEK) matrix by twin-screw extrusion compounding and subsequently injection molding. The tribological behaviors and the mechanical/thermal properties of the composites were carefully investigated. Compared with pure PEEK, PEEK/m-GO, and PEEK/m-SiO2 composites, the PEEK/m-GO/m-SiO2 composites exhibited considerable enhancements in those performances. These were attributed to m-GO and m-SiO2 that carried the majority of the load during a sliding process and prevented severe wear of the matrix.

2013 ◽  
Vol 129 (5) ◽  
pp. 2527-2535 ◽  
Author(s):  
Matthieu Guehenec ◽  
Victoria Tishkova ◽  
Sylvie Dagreou ◽  
Frederic Leonardi ◽  
Christophe Derail ◽  
...  

2021 ◽  
Vol 4 (9) ◽  
pp. 9664-9672
Author(s):  
Yuan Yuan Cai ◽  
Jia Jun Wang ◽  
Zhi Hong Cai ◽  
Qiu Gen Zhang ◽  
Ai Mei Zhu ◽  
...  

2020 ◽  
Vol 10 (21) ◽  
pp. 7536
Author(s):  
Yutao Yan ◽  
Cheng Jiang ◽  
Yuqiu Huo ◽  
Chaofeng Li

Poly-ether-ether ketone (PEEK) is a great potential thermoplastic in industry and medical treatment and health. In this work, PEEK/graphene oxide (GO) and PEEK/MoS2 composites were prepared by a novel hot isostatic pressing method. The addition of GO alters the tribological behaviors mechanism; fatigue wear mechanism is predominant to PEEK/GO composites. However, the combination of abrasive and adhesive wear mechanisms is observed for PEEK/MoS2 composites and PEEK. The reason for this is that the hardness and tensile strength of composites are increased with the appropriate addition of GO. The response time to stable friction state of PEEK/GO and PEEK/MoS2 composites is reduced in comparison with PEEK, which is conducive to shorten running-in time, reduce the energy consumption, and improve the tribological performances of composites. The addition of GO and MoS2 can effectively decrease the friction coefficient and wear rate, and the optimal content of GO and MoS2 was 0.7 wt.% and 15 wt.%, respectively. The results indicate that PEEK/GO and PEEK/MoS2 are impressive composites that possess super tribological properties.


2020 ◽  
Vol 20 (8) ◽  
pp. 4714-4721 ◽  
Author(s):  
Jiaye Ye ◽  
Chun Wu ◽  
Wei Qin ◽  
Fangfang Zhong ◽  
Mei Ding

The purpose of this study was to improve the repulsion ability of sulfonated poly(ether ether ketone) (SPEEK) membrane for the vanadium ions crossover. For this purpose graphene oxide (GO) nanosheet and titanium dioxide (TiO2) nanoparticles were employed into the polymer matrix to prepare SPEEK/GO/TiO2 hybrid membrane via solution-casting method for vanadium redox flow battery (VRFB). The morphology, permeability of vanadium ions and device performance of asprepared membrane were investigated and discussed. It was observed that with the barrier block effect by the filler, the VRFB single cell with the optimized SPEEK/GO/TiO2 hybrid membrane exhibited high coulombic efficiency (~99%), excellent energy efficiency (~85%) and vigorous cyclability (~97.2% capacity retention after 100 cycles). Moreover, the VRFB cell with this blend membrane showed lower vanadium ions permeability than Nafion 212 or pure SPEEK membranes. These results demonstrated that the comprehensive properties of hybrid membrane have been remarkably improved comparing to pristine SPEEK which suggested that the hybrid membrane was applicable for VRFB energy storage system.


RSC Advances ◽  
2018 ◽  
Vol 8 (14) ◽  
pp. 7753-7760 ◽  
Author(s):  
Handong Sun ◽  
Yunxia Lv ◽  
Chongyang Zhang ◽  
Xiaodan Zuo ◽  
Mengzhu Li ◽  
...  

Introducing long carbon–fluorine bonds into the polymer chain produced comb-shaped PEEK possessing a low dielectric constant (2.73) and low dielectric loss (3.00 × 10−3).


RSC Advances ◽  
2020 ◽  
Vol 10 (43) ◽  
pp. 25685-25695
Author(s):  
Cheng Yang ◽  
Jing Xu ◽  
Yue Xing ◽  
Sijia Hao ◽  
Zhidong Ren

A polymer “bridge” was designed to connect graphene oxide and poly(ether ether ketone), making stronger and tougher composites.


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