Microstructure and Mechanical Properties of Inverse Nanocomposite Made from Polylactide and Hydroxyapatite Nanoparticles

Polymer nanocomposites have been extensively researched for a variety of applications, including medical osteoregenerative implants. However, no satisfactory solution has yet been found for regeneration of big, and so-called critical, bone losses. The requirement is to create a resorbable material which is characterised by optimum porosity, sufficient strength, and elastic modulus matching that of the bone, thus stimulating tissue regrowth. Inverse nanocomposites, where the ceramic content is larger than the polymer content, are a recent development. Due to their high ceramic content, they may offer the required properties for bone implants, currently not met by polymer nanocomposites with a small number of nanoparticles. This paper presents inverse nanocomposites composed of bioresorbable nano crystalline hydroxyapatite (HAP NPs) and polylactide (PLLA), produced by cryomilling and a warm isostatic pressing method. The following compositions were studied: 25%, 50%, and 75% of HAP NPs by volume. The mechanical properties and structure of these composites were examined. It was discovered that 50% volume content was optimal as far as compressive strength and porosity are concerned. The inverse nanocomposite with 50% nanoceramics volume displayed a compressive strength of 99 ± 4 MPa, a contact angle of 50°, and 25% porosity, which make this material a candidate for further studies as a bioresorbable bone implant.

The Regeneration of Large-Sized and Vascularized Adipose Tissue Using a Tailored Elastic Scaffold and dECM Hydrogels

A dome-shaped elastic poly (l-lactide-co-caprolactone) (PLCL) scaffold with a channel and pore structure was fabricated by a combinative method of 3D printing technology and the gel pressing method (13 mm in diameter and 6.5 mm in thickness) for patient-specific regeneration. The PLCL scaffold was combined with adipose decellularized extracellular matrix (adECM) and heart decellularized extracellular matrix (hdECM) hydrogels and human adipose-derived stem cells (hADSCs) to promote adipogenesis and angiogenesis. These scaffolds had mechanical properties similar to those of native adipose tissue for improved tissue regeneration. The results of the in vitro real-time PCR showed that the dECM hydrogel mixture induces adipogenesis. In addition, the in vivo study at 12 weeks demonstrated that the tissue-engineered PLCL scaffolds containing the hydrogel mixture (hdECM/adECM (80:20)) and hADSCs promoted angiogenesis and adipose tissue formation, and suppressed apoptosis. Therefore, we expect that our constructs will be clinically applicable as material for the regeneration of patient-specific large-sized adipose tissue.

Thickness Improvement and Calibration Pressure Reduction of Stepped Tubular Components Using Axial Hydro-pressing Method

A new tube axial hydro-pressing method was proposed to solve the problems of high forming pressure and severely uneven wall thickness distribution of traditional tube hydroforming methods to form stepped tubular components. The forming pressure of the traditional hydroforming and the tube axial hydro-pressing method is studied theoretically, the mechanical model of the fillet area is established, and the forming pressure calculation formula is given. Based on this, an investigation of the tube axial hydro-pressing method is carried out by numerical simulation and experimental methods, and compared with the traditional tube hydroforming method. The key to the tube axial hydro-pressing method is to precisely control the relationship between the protrusion height and the axial feed, which is achieved by precisely controlling the feeding pressure and the axial displacement. Therefore, the constant pressure device in the experiment was used to eliminate the influence of the pressure rise caused by the volume compression on its cooperation relationship, to achieve accurate control of the loading path, eliminate wrinkles and flash defects. A qualified workpiece is successfully manufactured when the internal pressure is 18.0 MPa and the feed on each side is 15.0 mm. The forming pressure is reduced by 88.0%, and the feed is increased by 6.5%, which reduces the wall thickness reduction by 9.0%. The wall thickness difference of the workpiece can be controlled within 7.0%. The tube axial hydro-pressing method is suitable for forming stepped tubular components, which can achieve more replenishment at lower pressures, thereby effectively improving the uniformity of wall thickness and significantly reducing the forming pressure.

Optimisation of Healthy-Lipid Content and Oxidative Stability during Oil Extraction from Squid (Illex argentinus) Viscera by Green Processing

Green extraction was applied to Argentinean shortfin squid (Illex argentinus) viscera, consisting of a wet pressing method including a drying step, mechanic pressing, centrifugation of the resulting slurry, and oil collection. To maximise the oil yield and ω3 fatty acid content and to minimise the oil damage degree, a response surface methodology (RSM) design was developed focused on the drying temperature (45–85 °C) and time (30–90 min). In general, an increase of the drying time and temperature provided an increase in the lipid yield recovery from the viscera. The strongest drying conditions showed a higher recovery than 50% when compared with the traditional chemical method. The docosahexaenoic and eicosapentaenoic acid contents in the extracted oil revealed scarce dependence on drying conditions, showing valuable ranges (149.2–166.5 and 88.7–102.4 g·kg−1 oil, respectively). Furthermore, the values of free fatty acids, peroxides, conjugated dienes, and ω3/ω6 ratio did not show extensive differences by comparing oils obtained from the different drying conditions. Contrary, a polyene index (PI) decrease was detected with increasing drying time and temperature. The RSM analysis indicated that optimised drying time (41.3 min) and temperature (85 °C) conditions would lead to 74.73 g·kg−1 (oil yield), 1.87 (PI), and 6.72 (peroxide value) scores, with a 0.67 desirability value.

Mechanical Properties of Hot-Pressed B4C-TiB2 Composites Synthesized from B4C-TiO2 and B4C-TiC

In this study, B4C-TiB2 ceramic composites were manufactured by hot pressing method. The raw materials for the in-situ synthesis of TiB2 were TiO2 and TiC. After being sintered at 1900°C for 60min under a pressure of 30MPa, compact composites samples with a TiB2 volume fraction range from 0 to 11.05% were prepared. The relative density, fracture toughness and flexural strength of different sample were tested. Microstructures on the fracture surface were studied by SEM. The result shows that B4C-TiB2 ceramic composites sintered from B4C-TiC had a better mechanical property than the one sintered from B4C-TiO2. When the content of TiB2 (reacted from TiC) was 11.05vol.%, the strength and toughness of B4C-TiB2 ceramics can reach 598MPa and 6.45MPa·m1/2. The toughening mechanisms of B4C-TiB2 composites include micro-crack toughening and energy consumption by the pulling out process of second phase.

Excellent Thermally Conducting Ni Plating Graphite Nanoplatelets/Poly(phenylene sulfone) Composites for High-Performance Electromagnetic Interference Shielding Effectiveness

First, nickel particles were deposited on the surface of graphite nanoplatelets to fabricate highly conductive GnPs@Ni core-shell structure hybrid fillers via electroplating. The modified GnPs were blended with polyphenylene sulfone via the solution blending method, followed by the hot-pressing method to achieve high thermally conducting GnPs@Ni/PPSU composites for high performance electromagnetic interference effectiveness. The results showed that in-plane and through-plane thermal conductivity of the composite at the 40 wt% filler loading could reach 2.6 Wm−1K−1 and 3.7 Wm−1K−1, respectively, which were 9.4 and 20 times higher than that of pure PPSU resin. The orientation degree of fillers was discussed by XRD and SEM. Then, heat conduction data were fitted and analyzed by the Agari model, and the heat conduction mechanism was further explored. The testing results also demonstrated that the material exhibited good conductivity, electromagnetic shielding effectiveness and superior thermal stability. Overall, the GnPs@Ni/PPSU composites had high thermal conductivity and were effective electromagnetic shielding materials at high temperatures.

The Effect of Catalysts Addition to Silicone Rubber as Pressure Transmitting Medium in the Pebble Fuel Production Process

Pebble Fuel is a spherical fuel for high temperature gas-cooled reactors (HTGR). This fuel must have a homogeneous density distribution. Hyperelastic material is used as a pressure transmitting medium (PTM) material in making Pebble fuel using the cold quasi-isostatic pressing method. PTM material properties and characteristics were predicted using the finite element analysis method. The problem is the type of material used and its suitable composition to make a pressure-transmitting medium that has the properties and characteristics of the material as predicted. This research discusses the manufacture of tensile specimens for pressure-emitting media using RTV-586 silicone rubber. The composition comprises three different variants with two major ingredients, namely RTV-586 silicone rubber and catalyst. The test results are then analyzed using the finite element method to determine the material composition that is appropriate or close to the predicted properties and characteristics of the PTM material. This initial study used the Mooney-Rivlin hyperelastic model. The Mooney-Rivlin model shows good similarity to the test result data. In future studies, it will make comparisons with other hyperelastic models to get a suitable PTM material constant.

COPPER-CONTAINING NANOCOMPOSITES ON THE BASIS OF ISOTACTIC POLYPROPYLENE AND BUTADIENE-NITRILE RUBBER

The influence of additives of nanofillers containing nanoparticles of copper oxides stabilized by a polymer matrix of maleinized high-pressure polyethylene obtained by the mechano-chemical method on the structure and properties features of metal-containing nanocomposites based on isotactic polypropylene and butadiene-nitrile rubber by x-ray phase and differential thermal analyses is studied. The improvement of strength, deformation and rheological parameters, as well as thermal-oxidative stability of the obtained nanocomposites was revealed, that is probably due to the synergistic effect of interaction of copper-containing nanoparticles with maleic groups of maleinated high-pressure polyethylene. It is shown that nanocomposites based on isotactic polypropylene and butadiene-nitrile rubber can be processed both by pressing method and by injection molding and extrusion methods that expands the scope of its application