THEORY OF RESIDUAl POROSITY IN POWDER COMPACTS

1963 ◽  
Vol 6 (12) ◽  
pp. 1-16 ◽  
Author(s):  
G. C. KUCZYNSKI
Author(s):  
J. W. Mellowes ◽  
C. M. Chun ◽  
I. A. Aksay

Mullite (3Al2O32SiO2) can be fabricated by transient viscous sintering using composite particles which consist of inner cores of a-alumina and outer coatings of amorphous silica. Powder compacts prepared with these particles are sintered to almost full density at relatively low temperatures (~1300°C) and converted to dense, fine-grained mullite at higher temperatures (>1500°C) by reaction between the alumina core and the silica coating. In order to achieve complete mullitization, optimal conditions for coating alumina particles with amorphous silica must be achieved. Formation of amorphous silica can occur in solution (homogeneous nucleation) or on the surface of alumina (heterogeneous nucleation) depending on the degree of supersaturation of the solvent in which the particles are immersed. Successful coating of silica on alumina occurs when heterogeneous nucleation is promoted and homogeneous nucleation is suppressed. Therefore, one key to successful coating is an understanding of the factors such as pH and concentration that control silica nucleation in aqueous solutions. In the current work, we use TEM to determine the optimal conditions of this processing.


Author(s):  
Swathi K. Manchili ◽  
Johan Wendel ◽  
Eduard Hryha ◽  
Lars Nyborg
Keyword(s):  

2021 ◽  
pp. 004051752110238
Author(s):  
Oluwafemi P Akinmolayan ◽  
James M Manimala

Silica nanoparticle-impregnated Kevlar (SNK) fabric has better specific ballistic performance in comparison to its neat counterparts. For multifunctional structural applications using lightweight composites, combining this improved ballistic functionality with an acoustic functionality is desirable. In this study, acoustic characterization of neat and SNK samples is conducted using the normal-incidence impedance tube method. Both the absorption coefficient and transmission loss (TL) are measured in the 60–6000 Hz frequency range. The influence of parameters such as number of layers of neat or treated fabric, percentage by weight of nanoparticle addition, spacing between fabric layers, and residual porosity is examined. It is found that while absorption decreases with an increase in nanoparticle addition for frequencies above about 2500 Hz, increasing the number of layers shifts peak absorption to lower frequencies. By introducing an air-gap behind the fabric layer, dominant low-frequency (1000–3000 Hz) absorption peaks are obtained that correlate well with natural modes of mass-equivalent thin plates. Examining the influence of residual porosity by laminating the SNK samples reveals that it contributes to about 30–50% of the total absorption. Above about 1500 Hz, 3–5 dB of TL increase is obtained for SNK samples vis-à-vis the neat samples. TL is found to increase beyond that of the neat sample above a threshold frequency when an air-gap is introduced between two SNK layers. With an increase in the weight of nanoparticle addition, measured TL tends to be closer to mass law predictions. This study demonstrates that SNK fabric could provide improved acoustic performance in addition to its ballistic capabilities, making it suitable for multifunctional applications and could form the basis for the development of simplified models to predict the structural acoustic response of such nanoparticle–fabric composites.


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